Bermuda is a reef atoll along the northern edge of Caribbean coral province. Although investigated by seismic and some shallow drilling, the Pleistocene marine depositional geohistory is poorly constrained. Islands along the southern rim are built by tropical calcareous aeolianites that range in age from Holocene to early Pleistocene (ca 880 kyr). These dunes are composed of particles that were derived from adjacent Pleistocene marine environments at the time of formation. Thus, the aeolianites should contain a record of marine deposition through the Early to Late Pleistocene. Carbonate grains from all aeolian deposits can, via Ward cluster analysis, be separated into two distinct groups: (i) a Halimeda‐rich group; and (ii) a crustose coralline‐rich group. Distribution of these two groups is interpreted to broadly reflect low‐energy (lagoonal) and high‐energy marginal reef (coralline algae and cup‐reef) environments, respectively. Unlike the beach sources, coral particles are perplexingly absent in the aeolianites. This conundrum is interpreted to partly reflect the domal nature of Bermudan corals, which are not incorporated into aeolian deposits due to their relatively large size. Aeolianites from Marine Isotope Stages 7, 9 and 11 record sediments produced in adjacent shallow marine settings that were similar to those present today. The spatially consistent sediment trends are not, however, present in aeolianites from Marine Isotope Stage 5E, where the aeolian bioclastic components are uniformly rich in Halimeda along both southern and northern shores. Such a distribution, where coralline‐rich sediments would be expected, suggests an extrinsic oceanographic control, interpreted herein to be elevated seawater temperature brought in by the Gulf Stream. This interpretation is consistent with palaeozoological studies of Bermuda, as well as North America, the Mediterranean, Japan and Western Australia. 相似文献
Halogens show a range from moderate (F) to highly (Cl, Br, I) volatile and incompatible behavior, which makes them excellent tracers for volatile transport processes in the Earth’s mantle. Experimentally determined fluorine and chlorine partitioning data between mantle minerals and silicate melt enable us to estimate Mid Ocean Ridge Basalt (MORB) and Ocean Island Basalt (OIB) source region concentrations for these elements. This study investigates the effect of varying small amounts of water on the fluorine and chlorine partitioning behavior at 1280?°C and 0.3 GPa between olivine and silicate melt in the Fe-free CMAS+F–Cl–Br–I–H2O model system. Results show that, within the uncertainty of the analyses, water has no effect on the chlorine partitioning behavior for bulk water contents ranging from 0.03 (2) wt% H2O (DClol/melt = 1.6?±?0.9 × 10?4) to 0.33 (6) wt% H2O (DClol/melt = 2.2?±?1.1 × 10?4). Consequently, with the effect of pressure being negligible in the uppermost mantle (Joachim et al. Chem Geol 416:65–78, 2015), temperature is the only parameter that needs to be considered for the determination of chlorine partition coefficients between olivine and melt at least in the simplified iron-free CMAS+F–Cl–Br–I–H2O system. In contrast, the fluorine partition coefficient increases linearly in this range and may be described at 1280?°C and 0.3 GPa with (R2?=?0.99): \(D_{F}^{\text{ol/melt}}\ =\ 3.6\pm 0.4\ \times \ {{10}^{-3}}\ \times \ {{X}_{{{\text{H}}_{\text{2}}}\text{O}}}\left( \text{wt }\!\!\%\!\!\text{ } \right)\ +\ 6\ \pm \ 0.4\times \,{{10}^{-4}}\). The observed fluorine partitioning behavior supports the theory suggested by Crépisson et al. (Earth Planet Sci Lett 390:287–295, 2014) that fluorine and water are incorporated as clumped OH/F defects in the olivine structure. Results of this study further suggest that fluorine concentration estimates in OIB source regions are at least 10% lower than previously expected (Joachim et al. Chem Geol 416:65–78, 2015), implying that consideration of the effect of water on the fluorine partitioning behavior between Earth’s mantle minerals and silicate melt is vital for a correct estimation of fluorine abundances in OIB source regions. Estimates for MORB source fluorine concentrations as well as chlorine abundances in both mantle source regions are within uncertainty not affected by the presence of water. 相似文献
Extreme meteorological conditions favor the development of severe storms and tornadoes that may have largely impacts on the population despite its relatively short life. Tornadic severe storms have been documented around the World. In Mexico (MEX), the study of the occurrence of tornadoes and severe storms is relatively new. In this research, we have selected an event of severe tornadic storm in Ciudad Acuña, Mexico. The storm was driven by a frontal system moving southward from USA converging with a warmer moist air flux from the Gulf of Mexico. The tornado strikes on the Northeast of Mexico, in Coahuila State, on May 25, 2015. Imagery of infrared channel from GOES 13 satellite and the presence of a hook echo in radar data of May 25, 2015, indicate a supercell structure. The maximum values of radial velocity were about ?20 and 15 m s?1. In this study, the WRF model was used in order to simulate the mesoscale meteorological conditions of the tornado. Model simulations capture atmospheric features observed in Doppler radar. The simulated storm-relative helicity values were between 400 and 500 m2 s?2. The simulated convective available potential energy values were of 3000 J kg?1. These values were higher than values for convective storms, located over the region of Ciudad Acuña in Mexico and Del Rio in USA. The supercell was a result of high humidity and temperature gradients, conditioned by frontal activity and moisture flux intensifications from the Gulf of Mexico.
Tourmaline synthesised in an experiment with low boron excess was analysed in situ by secondary ion mass spectrometry. It
revealed significant B isotope zonation with 11B/10B ratios increasing in the growth direction of the crystals. Trend, magnitude and absolute values strongly support results
from high-B-excess isotope fractionation experiments. Furthermore, the closed system B-isotopic evolution of the experimental
fluid was modelled by Rayleigh fractionation. The model results are in excellent agreement with the measured B-isotope composition
of the run-product fluid. Consequently, low-element-excess experiments are proposed as an ideal approach to determine fluid-solid
isotope fractionation factors for systems that are characterised by Rayleigh fractionation. 相似文献
For many geophysical and astrophysical applications the relationship between physical bulk properties and porosity is needed. As part of the preparation for the 'Rosetta' comet rendezvous mission, a simple model for the porosity dependence of the elastic properties of granular media, i.e. the elastic moduli and the propagation velocities of elastic waves, has been developed based on textural properties and the contact stiffness of the constituent particles. It is shown that the derived relationships fit very well with sandstone data. The model is also consistent with data for snow and ice and is in agreement with the transformation mechanisms from snow to ice. A short review shows the relevance to another physical bulk property, the thermal conductivity. 相似文献
During the twentieth century sea surface temperatures in the Atlantic Ocean exhibited prominent multidecadal variations. The source of such variations has yet to be rigorously established—but the question of their impact on climate can be investigated. Here we report on a set of multimodel experiments to examine the impact of patterns of warming in the North Atlantic, and cooling in the South Atlantic, derived from observations, that is characteristic of the positive phase of the Atlantic Multidecadal Oscillation (AMO). The experiments were carried out with six atmospheric General Circulation Models (including two versions of one model), and a major goal was to assess the extent to which key climate impacts are consistent between the different models. The major climate impacts are found over North and South America, with the strongest impacts over land found over the United States and northern parts of South America. These responses appear to be driven by a combination of an off-equatorial Gill response to diabatic heating over the Caribbean due to increased rainfall within the region and a Northward shift in the Inter Tropical Convergence Zone (ITCZ) due to the anomalous cross-equatorial SST gradient. The majority of the models show warmer US land temperatures and reduced Mean Sea Level Pressure during summer (JJA) in response to a warmer North Atlantic and a cooler South Atlantic, in line with observations. However the majority of models show no significant impact on US rainfall during summer. Over northern South America, all models show reduced rainfall in southern hemisphere winter (JJA), whilst in Summer (DJF) there is a generally an increase in rainfall. However, there is a large spread amongst the models in the magnitude of the rainfall anomalies over land. Away from the Americas, there are no consistent significant modelled responses. In particular there are no significant changes in the North Atlantic Oscillation (NAO) over the North Atlantic and Europe in Winter (DJF). Additionally, the observed Sahel drying signal in African rainfall is not seen in the modelled responses. Suggesting that, in contrast to some studies, the Atlantic Multidecadal Oscillation was not the primary driver of recent reductions in Sahel rainfall. 相似文献
Atlantic Multidecadal Variability (AMV) is investigated in a millennial control simulation with the Kiel Climate Model (KCM), a coupled atmosphere–ocean–sea ice model. An oscillatory mode with approximately 60 years period and characteristics similar to observations is identified with the aid of three-dimensional temperature and salinity joint empirical orthogonal function analysis. The mode explains 30 % of variability on centennial and shorter timescales in the upper 2,000 m of the North Atlantic. It is associated with changes in the Atlantic Meridional Overturning Circulation (AMOC) of ±1–2 Sv and Atlantic Sea Surface Temperature (SST) of ±0.2 °C. AMV in KCM results from an out-of-phase interaction between horizontal and vertical ocean circulation, coupled through Irminger Sea convection. Wintertime convection in this region is mainly controlled by salinity anomalies transported by the Subpolar Gyre (SPG). Increased (decreased) dense water formation in this region leads to a stronger (weaker) AMOC after 15 years, and this in turn leads to a weaker (stronger) SPG after another 15 years. The key role of salinity variations in the subpolar North Atlantic for AMV is confirmed in a 1,000 year long simulation with salinity restored to model climatology: No low frequency variations in convection are simulated, and the 60 year mode of variability is absent. 相似文献
Secondary reactions occurring in pyrite-containing sediments from open cut coal mines are complex and not fully understood. In this study, the changes in seepage water composition in a column experiment with a sediment containing pyrite (5.6 g kg−1) were evaluated using a chemical equilibrium model. A column experiment with artificial irrigation (730 mm water yr−1) was carried out for 2 yr with a sediment from the open pit mine Garzweiler, Germany, at the Institute of Applied Geology. Tracer (LiCl) was added to the sediment. Seepage water composition at 52 cm depth was sampled weekly. Redox potential and the water potential were also recorded weekly. Sulphate and Fe(II) were the dominant ions in the seepage water with concentration maxima of 500 and 350 mmol l−1 after 50 days (0.7 pore volumes (PV)). Minimum pH values were around 0.8 after 100 days (1.4 PV), but increased subsequently and reached 2.4 after 700 days (9.5 PV). Ion activity product calculations indicated the intermediate formation of gypsum (19th–480th day of the experiment). Solutions were undersaturated with respect to alunite, jarosite, jurbanite, schwertmannite, melanterite, gibbsite and goethite during the whole experiment. The model of coupled equilibria which included inorganic complexation, precipitation/dissolution of gypsum and multiple cation exchange was tested. Pyrite oxidation and pH-dependent silicate weathering were considered using simple input functions. Transport was modelled using a field capacity cascade submodel. Model results showed satisfactory agreement with measured values for pH and concentrations of SO4, Fe, Mg, Ca and Al. Correlation coefficients lay between 0.7 and 0.9 and linear regression coefficients (modelled against measured) were 1.5 (Ca), 1.0 (Fe, SO4), 0.8 (Mg), 0.7 (pH) and 0.6 (Al). The results showed that the protons produced during pyrite oxidation (94 mmolc H+ kg−1) were mainly released into seepage water (as HSO4− and H+). Cation exchange reactions buffered 20 mmolc of H+ kg−1 sediment, and Al released by silicate weathering accounted for 3.6 mmolc H+ kg−1. Modelling was useful to further understand the significance of different pH buffer reactions. 相似文献
One thousand and fifty-two aurorae boreales and 554 aurorae australes recorded during the nineteenth century at medium latitudes 55° N or 55° S are compared statistically with the known hemispherical asymmetry of the sums of the areas of sunspots. According to the present study, the solar hemispherical asymmetry may be accompanied by an analogous pattern of the hemispherical frequency of auroral days. For the number of auroral days in each hemisphere beyond the two auroral ovals, a remarkable degree of phase equality with the sunspot areas during the second Gleissberg cycle can be demonstrated. 相似文献