Reaction-induced grain boundary cracking and anisotropic fluid flow during prograde devolatilization reactions within subduction zones

Devolatilization reactions during prograde metamorphism are a key control on the fluid distribution within subduction zones. Garnets in Mn-rich quartz schist within the Sanbagawa metamorphic belt of Japan are characterized by skeletal structures containing abundant quartz inclusions. Each quartz inclusion was angular-shaped, and showed random crystallographic orientations, suggesting that these quartz inclusions were trapped via grain boundary cracking during garnet growth. Such skeletal garnet within the quartz schist formed related to decarbonation reactions with a positive total volume change (?V _t > 0), whereas the euhedral garnet within the pelitic schists formed as a result of dehydration reaction with negative ?V _t values. Coupled hydrological–chemical–mechanical processes during metamorphic devolatilization reactions were investigated by a distinct element method (DEM) numerical simulation on a foliated rock that contained reactive minerals and non-reactive matrix minerals. Negative ?V _t reactions cause a decrease in fluid pressure and do not produce fractures within the matrix. In contrast, a fluid pressure increase by positive ?V _t reactions results in hydrofracturing of the matrix. This fracturing preferentially occurs along grain boundaries and causes episodic fluid pulses associated with the development of the fracture network. The precipitation of garnet within grain boundary fractures could explain the formation of the skeletal garnet. Our DEM model also suggests a strong influence of reaction-induced fracturing on anisotropic fluid flow, meaning that dominant fluid flow directions could easily change in response to changes in stress configuration and the magnitude of differential stress during prograde metamorphism within a subduction zone.     

A new algorithm for distance cartogram construction

A distance cartogram is a diagram that visualizes the proximity indices between points in a network, such as time–distances between cities. The Euclidean distances between the points on the distance cartogram represent the given proximity indices. This is a useful visualization tool for the level of service of transport, e.g. difference in the level of service between regions or points in a network and its improvement in the course of time. The two previously proposed methods—multidimensional scaling (MDS) and network time–space mapping—have certain advantages and disadvantages. However, we observe that these methods are essentially the same, and the merits of both these methods can be combined to formulate a generalized solution. In this study, we first formulate the time–space mapping problem, which includes the key features of both of the above stated methods, and propose a generalized solution. We then apply this solution to the time–distances of Japan's railway networks to confirm its applicability.     

The Hinode Spectro-Polarimeter

The joint Japan/US/UK Hinode mission includes the first large-aperture visible-light solar telescope flown in space. One component of the Focal Plane Package of that telescope is a precision spectro-polarimeter designed to measure full Stokes spectra with the intent of using those spectra to infer the magnetic-field vector at high precision in the solar photosphere. This article describes the characteristics of the flight hardware of the Hinode Spectro-Polarimeter, and summarizes its in-flight performance.     

Near-infrared and Visible Light Microthermometry of Fluid Inclusions in Sphalerite from a Possible Southeast Extension of the Toyoha Polymetallic Deposit, Japan

Abstract. Near-infrared (NIR) and visible light microthermometry was applied to the fluid inclusions in sphalerite from a possible southeast extension of the Toyoha polymetallic deposit. Sphalerite occurs as euhedral-subhedral crystals or collo-form aggregates with a variety of color, which contain a well-developed growth banding. Combined with morphological observations, fluid inclusions in dark-colored sphalerite were examined using a near-infrared light microscopic technique, whereas those in light-colored sphalerite and quartz were examined by a conventional visible light microscopy.
Salinities of fluid inclusions in dark-colored sphalerite have a wide variation (1.0–10.3 wt % NaCl equiv.) compared to that in light-colored sphalerite and quartz (0.0–3.4 wt % NaCl equiv.). These variations suggest that the conventional microthermometric data from light-colored sphalerite and quartz were inadequate to interpret the ore formation process. Dark-colored colloform sphalerite and a dark core of subhedral sphalerite formed from high-salinity fluids (6.5–10.3 wt % NaCl equiv.) under highly supersaturated conditions with respect to sphalerite.
The NIR and visible light microthermometry of fluid inclusions in sphalerite combined with its morphological observations is an invaluable method to infer the formation conditions of sphalerite. The NIR and visible light microthermometry is useful to reveal how the nature of ore fluids changed with time.     

Numerical study for specifying the major origin of low salinity water associated with <Emphasis Type="Italic">Chattonella</Emphasis> (Raphidophyceae) blooms in Tachibana Bay,Japan

In both 2009 and 2010, massive Chattonella blooms occurred in Tachibana Bay. Observation results show that high cell densities of Chattonella were distributed in the central area of Tachibana Bay with low salinity water. Model results indicate that the low salinity water originated from the Ariake Sea and intruded into Tachibana Bay during the northerly or weak winds. It is suggested that low salinity water was mainly discharged from the northern area of the Ariake Sea. Northerly wind enhanced the horizontal advection of the low salinity water intruding into Tachibana Bay originating from the northern area of the Ariake Sea.     

Seasonal Variability in Circulation Pattern and Residence Time of Suo-Nada

The development and evolution of the persistent counterclockwise circulation in Suo-Nada have been studied in detail using a three-dimensional numerical model. The realistic circulation has been reproduced from the monthly climatological fields of salinity, temperature along the open boundary, wind, heat flux and buoyancy input from twenty-two major rivers surrounding the basin. The seasonal variation of fresh-water discharge from the rivers proved to be the most important forcing mechanism driving the circulation. The expansion and contraction of coastal low salinity water well corresponded with the development of counterclockwise circulation from spring to summer and dissipation from autumn to winter. The circulation was found to be vertically homogenous and quasi-barotropic. However, confined along the coastal zone is an estuarine flow (i.e., oppositely directed currents in the upper and lower layers) whose horizontal dimension conforms to the period of maximum buoyancy flux from the rivers. This indicates that the flow pattern in Suo-Nada can be separated into two distinct regions where the relative dominance of estuarine circulation plays a significant role. Furthermore, the monthly water exchange capacity for autonomous purification of the basin has been evaluated from the average residence time of conservative material based on the calculated current field. It is demonstrated that the kinetic energy of the basin is directly responsible in promoting water exchange in Suo-Nada. This revised version was published online in August 2006 with corrections to the Cover Date.     

Intraannual variability of sea level around Tosa Bay

Through analysis of monthly in situ hydrographic, tide gauge, altimetry and Kuroshio axis data for the years 1993–2001, the intraannual variability of sea level around Tosa Bay, Japan, with periods of 2–12 months is examined together with the intraannual variability of the Kuroshio south of the bay. It is shown that the intraannual variation of steric height on the slope in Tosa Bay can account for that of sea level at the coast around the bay as well as on this slope. It is found that the steric height (or sea level) variation on the slope in this bay is mainly controlled by the subsurface thermal variation correlated with the Kuroshio variation off Cape Ashizuri, the western edge of Tosa Bay. That is, when the nearshore Kuroshio velocity south of the cape is intensified [weakened] concurrently with the northward [southward] displacement of the current axis, temperature in an entire water column decreases [increases] simultaneously, mainly due to the upward [downward] displacement of isotherms, coincident with that of the main thermocline. It follows that the steric height (or sea level) decreases [increases].     

Circulation and Material Transport in Suo-Nada during Spring and Summer

An attempt was made to reproduce the circulation pattern in Suo-Nada, Japan during spring and summer season in order to elucidate the water exchange mechanism in the basin. Two hydrographic surveys at the end of each season were conducted covering the entire Suo-Nada area. A three-dimensional hydrodynamic Princeton Ocean Model (POM) was used to compute the current resulting from the observed density and wind field. During spring, a very pronounced counter clockwise gyre is situated near the opening of the basin. This is replaced by a clockwise circulation which seemed to occupy the whole domain during summer. Within each season, however, the vertical distribution of current does not show any remarkable differences, indicating the dominance of horizontal current and a very weak estuarine flow. These observational and numerical results were used to estimate the remnant function and the corresponding average residence time of permanently dissolved matter (PDM) and transformable matter (TM). The results revealed a small difference in the average residence times of materials within each season but a large seasonal variability between spring and summer. Furthermore, calculations based on climatological density fields have indicated a similar trend of variation between the seasonal values of average residence times. This revised version was published online in July 2006 with corrections to the Cover Date.     

Tidal pump at the shelf edge

Material transport through the shelf edge to the deep ocean determines the fate of particulate matter generated in productive coastal seas. In stratified estuaries, onshore flow in the bottom layer generally keeps particulate matter generated in the upper layer and settled down to the bottom layer within the estuaries. AT the shelf edge of Tokyo Bay under the condition of average onshore flow in the bottom layer, we observed higher vertical sediment flux during ebb than flood tidal currents. The on-shelf and off-shelf differences in turbulent mixing and water depth mainly cause such difference in sediment flux. We propose to call this export process of particulate matter the tidal pump at the shelf edge.