Sequentially sampled gas hydrate water,coupled with pore water and bottom water isotopic and ionic signatures at the Kukuy mud volcano,Lake Baikal: ambiguous deep-rooted source of hydrate-forming water

The isotopic and ionic composition of pure gas hydrate (GH) water was examined for GHs recovered in three gravity cores (165–193 cm length) from the Kukuy K-9 mud volcano (MV) in Lake Baikal. A massive GH sample from core St6GC4 (143–165 cm core depth interval) was dissociated progressively over 6 h in a closed glass chamber, and 11 sequentially collected fractions of dissociated GH water analyzed. Their hydrogen and oxygen isotopic compositions, and the concentrations of Cl^– and HCO₃ ^– remained essentially constant over time, except that the fraction collected during the first 50 minutes deviated partly from this pattern. Fraction #1 had a substantially higher Cl^– concentration, similar to that of pore water sampled immediately above (135–142 cm core depth) the main GH-bearing interval in that core. Like the subsequent fractions, however, the HCO₃ ^– concentration was markedly lower than that of pore water. For the GH water fractions #2 to #11, an essentially constant HCO₃ ^–/Cl^– ratio of 305 differed markedly from downcore pore water HCO₃ ^–/Cl^– ratios of 63–99. Evidently, contamination of the extracted GH water by ambient pore water probably adhered to the massive GH sample was satisfactorily restricted to the initial phase of GH dissociation. The hydrogen and oxygen isotopic composition of hydrate-forming water was estimated using the measured isotopic composition of extracted GH water combined with known isotopic fractionation factors between GH and GH-forming water. Estimated δD of ?126 to ?133‰ and δ¹⁸O of ?15.7 to ?16.7‰ differed partly from the corresponding signatures of ambient pore water (δD of ?123‰, δ¹⁸O of ?15.6‰) and of lake bottom water (δD of ?121‰, δ¹⁸O of ?15.8‰) at the St6GC4 coring site, suggesting that the GH was not formed from those waters. Observations of breccias in that core point to a possible deep-rooted water source, consistent with published thermal measurements for the neighboring Kukuy K-2 MV. By contrast, the pore waters of core St6GC4 and also of the neighboring cores GC2 and GC3 from the Kukuy K-9 MV show neither isotopic nor ionic evidence of such a source (e.g., elevated sulfate concentration). These findings constrain GH formation to earlier times, but a deep-rooted source of hydrate-forming water remains ambiguous. A possible long-term dampening of key deep-water source signatures deserves further attention, notably in terms of diffusion and/or advection, as well as anaerobic oxidation of methane.     

Major and trace element abundances in volcanic glass shards in visible tephras in SG93 and SG06 drillcore samples from Lake Suigetsu,central Japan,obtained using femtosecond LA–ICP–MS

The major and trace element concentrations of volcanic glass shards from visible tephra layers in the SG93 and SG06 cores from Lake Suigetsu, central Japan, were determined by femtosecond laser ablation–inductively coupled plasma–mass spectrometry. The glass-shard analyses, together with the petrographic properties of the tephra samples, allow the Suigetsu tephra layers to be broadly classified into tephras derived from calderas on Kyushu Island, and from Daisen and Sambe volcanoes in the Chugoku district of southwest Japan. The layers correlated with tephras from Kuju caldera and Daisen volcano, and with the younger Sambe tephras, have adakitic elemental features. A Suigetsu tephra sample correlated with the Sambe−Kisuki tephra based on petrographic properties has an elemental pattern similar to that of the Toya tephra from Hokkaido Island, northeast Japan. This match implies that tephras from northeast Japan, as well as Kyushu–Chugoku tephras, are possible correlatives of the Suigetsu tephra layers. Both petrographic properties and major–trace element data of volcanic glass shards are essential for robust tephra correlations, and hierarchical cluster analysis proved additionally useful in statistically evaluating relationships among the tephras.     

Stick-slip behavior of Indian gabbro as studied using a NIED large-scale biaxial friction apparatus

This paper reports stick-slip behaviors of Indian gabbro as studied using a new large-scale biaxial friction apparatus, built in the National Research Institute for Earth Science and Disaster Prevention (NIED), Tsukuba, Japan. The apparatus consists of the existing shaking table as the shear-loading device up to 3, 600 kN, the main frame for holding two large rectangular prismatic specimens with a sliding area of 0.75 m² and for applying normal stresses σ_n up to 1.33 MPa, and a reaction force unit holding the stationary specimen to the ground. The shaking table can produce loading rates v up to 1.0 m/s, accelerations up to 9.4 m/s², and displacements d up to 0.44 m, using four servocontrolled actuators. We report results from eight preliminary experiments conducted with room humidity on the same gabbro specimens at v = 0.1-100 mm/s and σ_n = 0.66-1.33 MPa, and with d of about 0.39 m. The peak and steady-state friction coefficients were about 0.8 and 0.6, respectively, consistent with the Byerlee friction. The axial force drop or shear stress drop during an abrupt slip is linearly proportional to the amount of displacement, and the slope of this relationship determines the stiffness of the apparatus as 1.15×10⁸ N/m or 153 MPa/m for the specimens we used. This low stiffness makes fault motion very unstable and the overshooting of shear stress to a negative value was recognized in some violent stick-slip events. An abrupt slip occurred in a constant rise time of 16-18 ms despite wide variation of the stress drop, and an average velocity during an abrupt slip is linearly proportional to the stress drop. The use of a large-scale shaking table has a great potential in increasing the slip rate and total displacement in biaxial friction experiments with large specimens.     

Sequential Chemical Separation of Cr and Ti from a Single Digest for High‐Precision Isotope Measurements of Planetary Materials

Combined determination of Cr and Ti isotopes of planetary materials offers a means with which to investigate their genetic relationship and the evolution of the protoplanetary disk. Here, we report the new sequential chemical separation procedure for combined Cr and Ti isotope ratio measurements. It comprises three steps: (a) Fe removal using AG1‐X8 anion exchange resin, (b) Ti separation using TODGA resin and (c) Cr separation using AG50W‐X8 cation exchange resin (with one additional step of Ti purification using AG1‐X8 anion exchange resin for samples having high Cr/Ti and Ca/Ti ratios). We applied the proposed procedure to terrestrial and meteorite samples with various compositions. Typical recovery rates of 90–100% were achieved with total procedural Cr and Ti blanks of 3–5 and 2–3 ng, respectively. We measured the Cr and Ti isotope compositions of the separated samples using thermal ionisation mass spectrometry and multiple collector‐inductively coupled plasma‐mass spectrometry, respectively. Our Cr and Ti isotope data were found to be consistent with those of previous studies of individual Cr and Ti isotopic compositions of the meteorites. These results demonstrate the capability of our separation method when applied to combined high‐precision Cr and Ti isotope analyses for single digests of planetary materials.     

Observation of far ultraviolet radiation from early-type stars

Rocket-borne photon counters sensitive to bands 1060–1180, 1230–1350, and 1350–1480 were used to measure the celestial ultraviolet radiation above the terrestrial atmosphere. The energy spectra of six objects, Leo, CMa, Ori, , , Ori (combined), Ori, and Tau were obtained. The comparison of them with those calculated with the stellar model atmospheres indicates the deficiency of about 1 mag. in the ultraviolet region, when corrected for interstellar extinction, for all stars except Tau. The observed spectrum of Tau agreed with the theoretical one for normal interstellar extinction. The effects of line blanketing were examined for B1 and B2 stars, and found to account for a part of the difference between the observed and the theoretical values.     

The paradox of smooth and abrupt bends in two-dimensional in-plane shear-crack mechanics

It is pointed out, in the context of the boundary integral equation method (BIEM), that, in the mechanics of 2-D curved in-plane shear cracks, a smooth curve, along which the crack orientation changes continuously, and an abrupt kink, across which it changes discontinuously, are not equivalent to each other. The discrepancy is illustrated by numerical results, and a set of conceptual models is used to demonstrate analytically how the equations that govern the crack mechanics have inherently distinct forms depending on whether the crack orientation changes continuously or abruptly across a bend, as long as one abides by the principles of linear elasticity theory. This has serious implications for the numerical treatment of a curved crack, which can be modelled as a chain of finite elements that are connected either smoothly or at abrupt kinks, the two methods producing different numerical outcomes. No similar paradox arises in the cases of anti-plane shear or open in-plane cracks.     

Expansion of the Nishinomiya Built Environment Database

The Nishinomiya Built Environment Database, which can be used to analyze the disaster process of the 1995 Hanshin-Awaji Earthquake Disaster in Nishinomiya City, has been expanded with new data entries. The database contains the following very detailed datasets: (1) the urbanization area base map, (2) casualty data, (3) three sets of building damage data surveyed by the Nishinomiya City, the Architectural Institute of Japan and the City Planning Institute of Japan, and the Kobe University, (4) building property data based on the real estate tax roll, (5) photographs of the damaged buildings with the information on the place and orientation of the picture, and (6) the estimated distribution of the seismic ground motion. The seismic ground motion was simulated for the southern part of Nishinomiya City and two verification sites in Kobe City and Amagasaki City. In the simulation, the borehole data of public facilities were used to model the surface soils as one-dimensional layers, taking into consideration the fact that the spatial distribution of the sediment/basement interface forms a slope. The model of the fault rupture process simulated the characteristics of the seismic motion at basement level, and amplification effects of the surface layers were evaluated based on multiple reflection theory. The distribution of peak ground acceleration and peak ground velocity was estimated from acceleration response spectra at each borehole point. In addition, the relationship between simulated seismic ground motion and building damage was studied based on newly proposed band-passed spectrum intensity using the expanded database. This confirmed that detailed categorization is necessary in order to evaluate the fragility functions, especially for reinforced concrete structures. The database should provide fundamental information for identifying the relationship between the ground motions and the extent and pattern of building damage, or the pattern of the occurrence of casualties.Presently     

Isolation and chemical characterization of dissolved and particulate polysaccharides in Mikawa Bay

Isolation and chemical elucidation of dissolved and particulate polysaccharides in seawater were conducted. The water samples were collected in Mikawa Bay, Japan during a red tide bloom of the dinoflagellate, Prorocentrum minimum.Dissolved polysaccharides were concentrated from 5–101 of seawater with dialysis followed by separation by gel flitration, and isolation by ethanol precipitation. A heteropolysaccharide consisting of glucose, galactose, mannose, xylose, arabinose, fucose and rhamnose and a glucan were isolated from the polysaccharide component having a molecular weight more than 4,000 Dalton and were characterized by several chemical analyses. The heteropolysaccharide is a mucilaginous polysaccharide having a highly branched structure and a molecular weight of 10⁴?5 × 10⁶ Daltons and probably contains a sulfate half ester: the glucan is a polysaccharide with β-1,3- and 1,6-linkages (chrysolaminaran type). Concentrations of these were respectively ca. 20 and 67 μg l^?1 at 1 m, and 2 and 26 μg l^?1 at 6 m.A similar heteropolysaccharide was found in the boiling water extract of the particulate matter, while β-glucan was isolated in a much less purified form than the seawater β-glucan. In addition, a large amount of β-1,4 glucan was found in the strong alkali extract of the particulate matter, indicating that this glucan must be a cell wall polysaccharide derived from phytoplankton. These results strongly suggest that the heteropolysaccharide and chrysolaminaran type polysaccharide dissolved in seawater were derived from water soluble carbohydrates of phytoplankton through extracellular release or cell lysis.