Concentration of polychlorinated biphenyls (PCBs) in beached resin pellets: variability among individual particles and regional differences

Concentrations of polychlorinated biphenyls (PCBs) in beached resin pellets were examined to reveal variability between individual particles and differences among beaches. Fifty-five resin pellets from a beach in Tokyo were individually analyzed for PCBs, and showed concentrations ranging from <28 to 2,300 ng/g. This indicates that concentrations are highly variable between particles. Among several characters, discoloration (e.g., yellowing) had a positive relationship with PCB concentration: discolored pellets contained more PCBs than others on most of the beaches sampled. Given the color-selective ingestion of food by some organisms, this may be ecotoxicologically important. Measurements of samples from 47 beaches in Japan showed regional differences in PCB concentrations in resin pellets consistent with those in mussels. Sporadic high concentrations of PCBs were also found in pellets from remote islands, suggesting that resin pellets could be the dominant route of exposure to the contaminants at remote sites. The similarity of PCB concentrations between resin pellets and mussels suggests a potential use of resin pellets to monitor pollution in seawater.     

A Methodology for Predicting the In Situ Size and Shape Distribution of Rock Blocks

Summary In block caving, it is important to estimate the cavability of an ore body. This study proposes a new three dimensional (3D) model for predicting the characteristics of ore fragmentation in block caving, which is based on the Monte Carlo simulation technique. In this paper, the following subjects are discussed: sampling methods of discontinuity, 3D modeling algorithms and conceptualization for analyzing the distribution of discontinuities. In addition, the influence of each modeling parameter on the distribution of ore fragmentation was analyzed. The characteristics of ore fragmentation in a Northern China underground copper mine are used as a case study. Based on the methods discussed here, a software system named “MAKEBLOCK” was developed for analyzing the characteristics of discontinuities in an ore body and predicting the size distribution of ore fragments in block caving. The ore fragmentation attained by using this 3D model is in a good agreement with the field fragmentation measurements. Received November 30, 2001; accepted September 19, 2002; Published online February 25, 2003 Acknowledgement Support for this project came primarily from The National Science Foundation of China (approval No. 59704004). We would like to thank professor J. F. Archbald, head of Faculty of Mining Engineering, Queen's University, Canada, for his excellent advice and for checking the technical presentations of this paper. Authors' address: Dr. Liguan Wang, College of Resources and Safety Engineering, Central South University, Hunan, Changsha, China; e-mail: liguan_wang@hotmail.com     

Non-hypersingular boundary integral equations for two-dimensional non-planar crack analysis

We derive a set of non-hypersingular boundary integral equations, both elastodynamic and elastostatic, for the analysis of arbitrarily shaped 2-D anti-plane and in-plane cracks located in an infinite homogeneous isotropic medium, rendered in a unified nomenclature for all cases. The hypersingularities that appear in the usual formulations for the dynamic cases, existent both at the source point and at the wavefront, are removed by way of a regularization technique based on integration by parts. The equations for the in-plane cases are presented in terms of a local Cartesian coordinate system, one of the axes of which is always held locally tangential to the crack trace. The expressions for the elastic field at any point on the model plane are also given.
Our formulations are shown to yield accurate numerical results, as long as appropriate stabilization measures are taken in the numerical scheme. The numerical applicability of our method to non-planar crack problems is illustrated by simulations of dynamic growth of a hackly crack which has small off-plane side-branches. The results imply that the branching of a crack brings about a significant decrease in the crack-tip stress concentration level and consequently may play an essential role in the arrest of earthquake rupturing.     

Brightness distribution of diffuse soft X-rays

The brightness distribution of diffuse soft X-rays in the pulse height range 0.15–0.3 keV (L-band) and 0.5–0.8 keV (M-band) are obtained over a quarter of the sky centered at the galactic anticenter with 1.5 m polypropylene window proportional counters on board a sounding rocket. In theL-band three enhanced regions are noticed on the map. They coincide with the northern and southern Hi holes and the inner part of the galactic radio Loop II.In the northern Hi hole theN _H dependence of theL-band flux and the hardness ratioM/L can be fitted with a local hot plasma model with the absorption by a low velocity neutral hydrogen gas (|V|<25 km s^–1) along the line of sight. The X-ray feature of Loop II is similar to that of Loop I. In the lowN _H region (<3×10²⁰ H atoms cm^–2) theM/L value is lower than 0.3, whereas it varies in the range 0.1–0.4 at low latitudes (|b|<30⁰). This fact seems to be interpreted in terms of a model that a number of hot plasma clouds contribute to X-ray emission.     

Differential sorption of organic matter by various sized sediment particles in recent sediment from the bering sea

A recent unconsolidated marine sediment collected from the Aleutian basin of the Bering Sea (5702.9N, 17657.4W) was separated into eight size fractions by sieving. Each of the fractions was analyzed for density, organic carbon, total nitrogen and various organic materials. A detailed analysis of the correlation of organic carbon and total nitrogen to the mean diameter of the particles separated, indicated that the surface sorption processes of organic matter were the determinative factor controlling the concentration of organic carbon and total nitrogen on silt and clay particles of the sediments.Selective sorption of amino acids was found to occur in the 8–20 and 5–8m. fractions of the sediment. This is assumed to be due to their surface active property.     

Ecophysiology of juvenile flatfish in nursery grounds

Relationships between biotic and abiotic factors and the ecological performance of late larval and juvenile flatfish in nursery grounds are examined from ecophysiological viewpoints. The first events in the nursery are metamorphosis and settlement. Development of organs, osmoregulation and behavioural changes during metamorphosis, and size at metamorphosis are regulated by environmental factors. Various hormones play critical roles in this regulation. Effects of environmental conditions on individual growth in the nursery grounds are described on the basis of Fry's five environmental factors: limiting, controlling, masking, directive and lethal factors. The main limiting factors are food and dissolved oxygen; controlling factors are temperature and body size; masking factors are salinity and pollutants; lethal factors are extreme environments; and directive factors are food, predators and dissolved oxygen. In addition to temperature, it has been indicated that dissolved oxygen seems to be relatively important for flatfish of the eastern US and northern European countries, while food abundance appears to be more critical for Japanese flounder. The feasibility is discussed of ecophysiological modelling to predict individual growth and subpopulation production based on the assessment of the role of environmental variability using the above classification, which organises and integrates environmental effects.     

Origin and decomposition of sinking particulate organic matter in the deep water column inferred from the vertical distributions of its δN, δ and δ

Sinking particles were analyzed for their nitrogen isotopic ratio δ¹⁵N) of total particulate nitrogen (PN), stable carbon isotopic ratio (δ¹³C) and radioactive isotopic ratio (δ¹⁴C) of total particulate organic carbon (POC), at three different latitudinal (temperate, subpolar and equatorial) and geomorphological (trench, proximal abyssal plain and distal abyssal plain) sites in the western North Pacific Ocean using year-long time series sediment trap systems, to clarify the common vertical trends of the isotopic signals in deep water columns. Although the δ¹⁵N and δ¹³C values of sinking particulate organic matter (POM) were partly affected by the resuspension of sedimentary POM from the sea floor, especially in the trench, the changes in δ¹⁵N and δ¹³C values owing to the resuspension could be corrected by calculation of the isotopic mass balance from δ¹⁴C of sinking POC. After this correction, common downward decreasing trends in δ¹⁵N and δ¹³C values were obtained in the deep water columns, irrespective of the latitudes and depths. These coincidental isotopic signals between δ¹⁵N and δ¹³C values provide new constraints for the decomposition process of sinking POM, such as the preferential degradation of ¹⁵N- and ¹³C-rich compounds and the successive re-formation of the sinking particles by higher trophic level organisms in the deep water column.     

Factors controlling the temporal variation of fatty acids in piculate matter during a phytoplankton bloom in a marine mesocosm

Fatty acids present in suspended particles were examined following the onset of a phytoplankton bloom in an experimental marine mesocosm set up in Patricia Bay, Saanich Inlet, British Columbia, Canada. The predominantly diatom bloom, triggered by the addition of nutrients at the commencement of the experiment, was succeeded by several other phytoplankton forms, which in turn led to changes in particulate chl a, and organic carbon, and nitrogen within the experimental enclosure. An examination of individual fatty acids indicated that the variation of individual fatty acids can be classified into three groups, although the variation pattern of individual fatty acids differed from one another. An attempt was made to establish the factors controlling particulate fatty acid concentrations by principal component analysis. After Varimax rotation, six factors were extracted, of which four factors contributed to 83% of the data matrix. These were mainly dependent on the source of the particles i.e., diatoms, dinoflagellates, and bacteria.Fatty acid concentrations obtained by analysis of different lipid class fractions indicated that the production of fatty acids was distinctly related to the growth stage of the phytoplankton bloom. Fatty acids in triglycerides peaked during stationary phase, whereas fatty acids in polar lipids were high during the stage of an increase of phytoplankton biomass. However, fatty acid composition in both lipid classes changed under the influence of species succession of the phytoplankton population. This strongly suggested that species succession of the phytoplankton exerted the most significant control on fatty acid composition of particulate matter.