Preferential dissolution of SiO<Subscript>2</Subscript> from enstatite to H<Subscript>2</Subscript> fluid under high pressure and temperature

Stability and phase relations of coexisting enstatite and H₂ fluid were investigated in the pressure and temperature regions of 3.1–13.9 GPa and 1500–2000 K using laser-heated diamond-anvil cells. XRD measurements showed decomposition of enstatite upon heating to form forsterite, periclase, and coesite/stishovite. In the recovered samples, SiO₂ grains were found at the margin of the heating hot spot, suggesting that the SiO₂ component dissolved in the H₂ fluid during heating, then precipitated when its solubility decreased with decreasing temperature. Raman and infrared spectra of the coexisting fluid phase revealed that SiH₄ and H₂O molecules formed through the reaction between dissolved SiO₂ and H₂. In contrast, forsterite and periclase crystals were found within the hot spot, which were assumed to have replaced the initial orthoenstatite crystals without dissolution. Preferential dissolution of SiO₂ components of enstatite in H₂ fluid, as well as that observed in the forsterite H₂ system and the quartz H₂ system, implies that H₂-rich fluid enhances Mg/Si fractionation between the fluid and solid phases of mantle minerals.     

Geochemical assessment of arsenic contamination in well water and sediments from several communities in the Nawalparasi District of Nepal

Arsenic contamination of well water is a serious issue in the Nawalparasi District of the Terai region in Nepal. A local investigation was carried out on 137 tube wells in 24 communities of the district in December 2011. The investigation revealed that the average arsenic concentration in the tube wells was 350 μg/L, and that nearly 98 % of the wells exceeded the WHO guideline arsenic level limit of 10 μg/L. Highly contaminated well water, with more than 400 μg/L of arsenic, was found within the limited depth ranges of 18–22 and 50–80 m. High arsenic levels exceeding 500 μg/L were detected in shallower wells at Patkhauli, Mahuawa, Thulokunwar, and Goini located between 27.517° and 27.543°N and between 83.648° and 83.748°E. Boring sampling at five communities of Kashiya, Goini, Sanokunwar, Thulokunwar, and Mahuawa revealed two aquifers located at the two depths around 14–22 and 41–50 m in each community. Dark gray or black-colored peaty clay layers rich in organic matter were distributed at depths of 18–21 m beside the upper aquifers with high arsenic concentration in each community. Positive correlations were shown between iron and arsenic in the sediments from the five communities. It can be inferred that these results were caused by dissolution of iron-oxyhydroxide molecules with arsenic from solid phases. Microbial metabolisms have a great potential to induce the dissolution and release arsenic attached on the solid phases into aqueous phases depending on the level of redox potential and pH.     

Photoluminescence properties of anthophyllite

The photoluminescence (PL) spectra, optical excitation spectra and PL decay curves of anthophyllite from Canada were obtained at 300 and 10 K. The MnO content in the sample, determined using an electron probe microanalyzer, was high at 5.77 wt%. In the PL spectra obtained under 410-nm excitation, bright red bands with peaks at 651 and 659 nm were observed at 300 and 10 K, respectively. The origin of the red luminescence was ascribed to Mn²⁺ in anthophyllite from the analysis of the excitation spectra and PL decay times of 6.1–6.6 ms. In the PL spectra obtained under 240-nm excitation at 300 K, a small violet band with a peak at 398 nm was observed. On the violet band at 10 K, a vibronic structure was observed. The origin of the violet luminescence was attributed to a minor impurity in anthophyllite.     

Accuracy of formation factors for three-dimensional pore-scale images of geo-materials estimated by renormalization technique

The formation factor, the dimensionless electric resistivity of porous rock/sediment saturated with conductive fluid, is an important quantity in geophysical exploration for petroleum reservoirs and groundwater aquifers. The renormalization technique is a promising approximation method for the quick estimation of the formation factors from large three-dimensional images of porous geo-materials obtained by X-ray microtomography. In the present study, we applied the renormalization technique to various pore-scale image sets of real geo-materials (sandstones, pumice, lava, and sandy sediments). The purpose is to explore the factors controlling the estimation accuracy of the formation factor. The results revealed that the accuracy increases with increasing (i) porosity, (ii) degree of the pore elongation along the direction of the applied electric field, and (iii) size of the initial subsystem with which the renormalization step starts and with decreasing (iv) pore or grain size. Most importantly, a high degree of elongation of the pore structure along the applied field ensures good accuracy even if the porosity is low, the initial subsystem is small, and the pore or grain size is large.     

Pressure responses of portlandite and H–D isotope effects on pressure-induced phase transitions

The pressure responses of portlandite and the isotope effect on the phase transition were investigated at room temperature from single-crystal Raman and IR spectra and from powder X-ray diffraction using diamond anvil cells under quasi-hydrostatic conditions in a helium pressure-transmitting medium. Phase transformation and subsequent peak broadening (partial amorphization) observed from the Raman and IR spectra of Ca(OH)₂ occurred at lower pressures than those of Ca(OD)₂. In contrast, no isotope effect was found on the volume and axial compressions observed from powder X-ray diffraction patterns. X-ray diffraction lines attributable to the high-pressure phase remained up to 28.5 GPa, suggesting no total amorphization in a helium pressure medium within the examined pressure region. These results suggest that the H–D isotope effect is engendered in the local environment surrounding H(D) atoms. Moreover, the ratio of sample-to-methanol–ethanol pressure medium (i.e., packing density) in the sample chamber had a significant effect on the increase in the half widths of the diffraction lines, even at pressures below the hydrostatic limit of the pressure medium.     

Seismic activity beneath the Nankai trough revealed by DONET ocean-bottom observations

We conducted a detailed investigation of seismic activity from January 2011 to February 2013 along the Nankai trough off the Kii Peninsula, central Japan, by using data obtained from the DONET ocean-bottom observation network. The hypocenters are mostly within the subducting Philippine Sea (PHS) plate, although a few are along the plate boundary or in the sedimentary wedge below the Kumano forearc basin. The seismic activity can be separated into events above and below 20 km depth, which corresponds approximately to the Moho. The hypocenter distributions are distinctly different for these groups. The seismic activity in the oceanic crust can be further separated into three clusters. Most of the seismic activity recorded in our data represents aftershocks of the 2004 off the Kii Peninsula earthquakes (M _JMA = 7.1, 7.4, and 6.5), which occurred in the PHS plate. The hypocenter distribution in the oceanic crust correlates well with the location of the Paleo-Zenisu ridge, which is formed by a chain of seamounts that is subducting beneath the forearc basin. The hypocenters in the uppermost mantle are aligned on a plane dipping to the southeast, consistent with the existence of a thrust fault cutting through the lithosphere of the oceanic plate. The focal mechanisms of the earthquakes show that the axis of compressive stress in the PHS plate is oriented N–S, almost perpendicular to the direction of plate convergence, indicating a complex tectonic regime in this region. These results suggest that intraplate shortening may be occurring in the subducting oceanic plate.     

Formation mechanism of the Weddell Sea Polynya and the impact on the global abyssal ocean

An experiment using a global ocean–ice model with an interannual forcing data set was conducted to understand the variability in the Southern Ocean. A winter-persisting polynya in the Weddell Sea (the Weddell Polynya, WP) was simulated. The process of WP breaking out after no-WP years was explored using the successive WPs found in the late 1950s. The results suggested that the anomalously warm deep water, saline surface layer, and a cyclonic wind stress over the Maud polynya region in early winter are essential for the surface layer to be dense enough to trigger deep convections which maintain a winter-persisting polynya; also, the reanalyzed surface air temperature (SAT) over the observed polynya region is too high for an ocean–ice model’s bulk formula to yield sufficient upward heat fluxes to induce WP formation. Therefore the Weddell Polynya, a series of WPs observed from satellite in the mid-1970s, is reproduced by replacing the SAT with a climatological one. Subsequent to the successive WP events, density anomalies excited in the Weddell Sea propagate northward in the Atlantic deep basins. The Antarctic Circumpolar Current (ACC) is enhanced through the increased meridional density gradient. The enhanced ACC and its meandering over the abyssal ridges excite buoyancy anomalies near the bottom at the southwestern end of the South Pacific basin. The buoyancy signals propagate northward and eventually arrive in the northern North Pacific.     

Three‐dimensional structures and elemental distributions of Stardust impact tracks using synchrotron microtomography and X‐ray fluorescence analysis

Abstract— Three‐dimensional structures and elemental abundances of four impact tracks in silica aerogel keystones of Stardust samples from comet 81P/Wild 2 (bulbous track 67 and carrot‐type tracks 46, 47, and 68) were examined non‐destructively by synchrotron radiation‐based microtomography and X‐ray fluorescence analysis. Track features, such as lengths, volumes and width as a function of track depth, were obtained quantitatively by tomography. A bulbous portion was present near the track entrance even in carrot‐type tracks. Each impact of a cometary dust particle results in the particle disaggregated into small pieces that were widely distributed on the track walls as well as at its terminal. Fe, S, Ca, Ni, and eight minor elements are concentrated in the bulbous portion of track 68 as well as in terminal grains. It was confirmed that bulbous portions and thin tracks were formed by disaggregation of very fine fragile materials and relatively coarse crystalline particles, respectively. The almost constant ratio of whole Fe mass to track volume indicates that the track volume is almost proportional to the impact kinetic energy. The size of the original impactor was estimated from the absolute Fe mass by assuming its Fe content (CI) and bulk density. Relations between the track sizes normalized by the impactor size and impact conditions are roughly consistent with those of previous hypervelocity impact experiments.     

Use of similarity solutions for the problem of a wetting front — a question of unique representation

The use of similarity solutions for the problem of horizontal infiltration of water into a semi-infinite, dry and homogeneous porous medium is studied based upon some recent results of functional analysis. It is found that the so-called non-unique representation of reported experimental moisture profiles for this problem is not necessarily evidence against the validity of the extended Darcy's law for unsaturated flow through porous media.     

Particular solutions to the problem of horizontal flow of water and air through porous media near a water table

Particular solutions to the problem of horizontal flow of water and air through porous media near a water table are derived and regularity properties of the solutions are presented. It is found that a singularity occurs in the solutions at the water table and the water table can be interpreted as an acceleration wave of the nth order in terms of either air or water flow where n is a positive integer. Effects of air flow on water flow are discussed.