REE abundances in the matrix of the Allende (CV) meteorite: Implications for matrix origin

Abstract— The trace element distributions in the matrix of primitive chondrites were examined using four least‐contaminated matrix specimens from the polished sections of the Allende (CV) meteorite. Analysis of rare earth element (REE), Ba, Sr, Rb, and K abundances by isotope dilution mass spectrometry revealed that the elemental abundances of lithophile elements except for alkali metals (K, Rb) in the specimens of the Allende matrix studied here are nearly CI (carbonaceous Orgueil) chondritic (～1 × CI). Compared to refractory elements, all the matrix samples exhibited systematic depletion of the moderately volatile elements K and Rb (0.1–0.5 × CI). We suggest that the matrix precursor material did not carry significant amounts of alkali metals or that the alkalis were removed from the matrix precursor material during the parent body process and/or before matrix formation and accretion. The matrix specimens displayed slightly fractionated REE abundance patterns with positive Ce anomalies (CI‐normalized La/Yb ratio = 1.32–1.65; Ce/Ce* = 1.16–1.28; Eu/Eu* = 0.98–1.10). The REE features of the Allende matrix do not indicate a direct relationship with chondrules or calcium‐aluminum‐rich inclusions (CAIs), which in turn suggests that the matrix was not formed from materials produced by the breakage and disaggregation of the chondrules or CAIs. Therefore, we infer that the Allende matrix retains the REE features acquired during the condensation process in the nebula gas.     

A DETAILED CHEMICAL STUDY ON THE BARWISE CHONDRITE

Six fragments of the Barwise meteorite were analyzed for REE and eleven other elements (Al, Ca, Mg, Mn, Na, K, Cr, Fe, Co, Ni and Ba). In addition, two fragments were analyzed for Si and Mg. The chondrite-normalized REE patterns of six fragments studied show interesting systematic variations. Three fragments with relatively high La abundances show a negative Ce anomaly. Since the meteorite in question is a find, it could be suspected that the observed REE fractionations are due to terrestrial contamination. To examine this point, a soil sample from the find site was also analyzed for REE and major chemical elements. It is considered that several facts, especially, the relationships between La and SiO₂ and between SiO₂ and MgO, suggest the pre-terrestrial fractionation rather than the terrestrial contamination. Unexpectedly, it is shown that the REE fractionation observed in the investigated fragments correlates with the metal-silicate and the Fe-Co-Ni fractionations. In this connection, large metal grains were investigated for Fe, Co and Ni contents. A suggestion is presented that this chondrite was formed through the melting of the surface of a planetesimal and the subsequent collision, although the possibility of terrestrial contamination might not be ruled out.     

Seepage flow problems by variational inequalities: Theory and approximation

The theory of variational inequalities enables us to formulate and solve free boundary problems in fixed domains, while most other methods assume the position of the unknown domain in solving the problem. Here the problem of seepage flow through a rectangular dam with a free boundary is formulated as a vertical inequality following the ideas of Baiocchi. In order to demonstrate the essential ideas of extending the domain of the solution of problems with free boundaries, the problem of the deflection, of a string on a rigid support is first examined. Next, variational inequalities are derived which are associated with several cases of seepage problems. An approximation theory, including a priori error estimates, is developed using finite element methods, and an associated numerical scheme is given. It is shown that for linear and quadratic finite element methods, the rates of convergence are 0(h) and 0(h^1.25-δ), 0 < δ < 0.25, respectively, if the permeability is constant.     

Seasonal and annual change in community structure of meso-sized copepods in Tokyo Bay, Japan

Seasonal change in the meso-sized copepod community structure in the central part of Tokyo Bay was investigated from January 2006 to December 2008. Three seasonal community groups were detected, and seasonal shifts of these communities are explained by life history characteristics of indicator species and seasonal changes in the hydrographical environment. In the winter-spring community, Acartia omorii and Centropages abdominalis dominate because of high growth rates at low temperature. A shift to the early summer community is caused by a diapause of Ce. abdominalis as resting eggs and an increase in the growth and egg-production rate of Pseudodiaptomus marinus at high temperature. A shift to the summer-fall community is caused by a diapause of A. omorii at hypoxic and high temperature conditions and an increase of Temora turbinata, Paracalanus parvus and other oceanic species by an enhancement of the estuary circulation. Then, the community returns to a winter-spring one by the recovery of A. omorii and Ce. abdominalis with low temperatures and oxygenation of bottom water and by the disappearance of oceanic warm-water species at low temperature. Seasonal community shifts occurred almost regularly, but the shift from a winter-spring community to an early summer one occurred 1 month early in 2007 when the water temperature was warmer than in other years.     

Oxygen, silicon, and Mn-Cr isotopes of fayalite in the Kaba oxidized CV3 chondrite: Constraints for its formation history

The iron-rich olivine end-member, fayalite, occurs in the matrix, chondrules, Ca-Al-rich inclusions (CAIs), silicate aggregates, and dark inclusions in the Kaba and Mokoia oxidized CV3 chondrites. In most occurrences, fayalite is associated with magnetite and troilite. To help constrain the origin of the fayalite (Fa_98-100), we measured oxygen and silicon isotopic compositions and Mn-Cr systematics in fayalite from two petrographic settings of the Kaba meteorite. One setting consists of big fayalite laths embedded in the matrix and radiating from a core of fine-grained magnetite and sulfide, while the other setting consists of small fayalite-magnetite-sulfide assemblages within or at the surface of Type I barred or porphyritic olivine chondrules. Oxygen in the big fayalite laths and small chondrule fayalites falls on the terrestrial fractionation line, and is distinct from that in chondrule forsterites, which are enriched in ¹⁶O (Δ¹⁷O = ∼−4‰). Oxygen in the big fayalite laths may be isotopically heavier than that in chondrule fayalites. Silicon isotopes suggest that forsterite is ∼1‰/amu heavier than adjacent fayalite within Kaba chondrules. However, we were unable to confirm large silicon isotopic differences among fayalites reported previously. The Mn-Cr data for big Kaba fayalites give an initial ⁵³Mn/⁵⁵Mn ratio of (2.07 ± 0.17) × 10⁻⁶, consistent with literature results on Mokoia chondrule fayalites. The combined data suggest that fayalites in both petrographic settings formed at about the same time, ∼9.7 Ma after the formation of CAIs. Our data indicate that those fayalite-magnetite-troilite assemblages replacing metal inside and around chondrules formed by aqueous alteration on the meteorite parent body. The formation site and mechanism for the big fayalite laths is less clear, but the petrographic setting indicates that they did not form in situ. None of the models that have been suggested for formation of these fayalites is entirely satisfactory.     

ESR detection of seismic frictional heating events in the Nojima fault drill core samples, Japan

We have analyzed the Nojima fault NIED 1800 m drill core samples by ESR (Electron Spin Resonance) to detect seismic frictional heating events, especially during the 1995 Kobe Earthquake. Dark gray fault gouge with foliation > 10 cm away from the fault plane at about 1140 m in depth, which was produced by ancient fault movements, has a FMR (ferrimagnetic resonance) signal. Heating experiments show that this FMR signal is derived from ferrimagnetic trivalent ion oxides (γ-Fe₂O₃: maghemite) with imperfect crystallinity, which is produced by thermal dehydration of γ-FeOOH (lepidocrocite) or Fe(OH)₃ (limonite). The existence of the FMR signal means that dry heating such as frictional heating once occurred, and that the frictional heat temperature along the dark gray fault gouge may have risen to over 350 °C during ancient seismic fault slip. In order to detect frictional heating events in fault zones, the increase of the FMR signal and the color change of fault gouge into dark gray or black are important indexes. On the other hand, no FMR signal is detected from the fault gouges just on two fault planes at about 1140 m and 1300 m in depth, which are considered to be possible main fault planes in the 1995 Kobe Earthquake. These two fault planes may not have played an important role of fault slip in the Earthquake.     

Small-Amplitude Disturbances In A Radiating And Scattering Grey Medium Ii. Solutions Of Given Real Wave Number <Emphasis Type="BoldItalic">k</Emphasis>

We study the fundamental modes of radiation hydrodynamic waves arising from one-dimensional small-amplitude initial fluctuations with wave number k in a radiating and scattering grey medium using the Eddington approximation. The dispersion relation analyzed is the same as that of Paper I (Kaneko et al., 2000), but is solved as a quintic in angular frequency ω while a quadratic in k ² in Paper I. Numerical results reveal that wave patterns of five solutions are distinguished into three types of the radiation-dominated and type 1 and type 2 matter-dominated cases. The following wave modes appear in our problem: radiation wave, conservative radiation wave, entropy wave, Newtonian-cooling wave, opacity-damped and cooling-damped waves, constant-volume and constant-pressure diffusion modes, adiabatic sound wave, cooling-damped and drag–force-damped isothermal sound waves, isentropic radiation-acoustic wave, and gap mode. The radiation-dominated case is characterized by the gap between the isothermal sound and isentropic radiation-acoustic speeds within which there is not any acoustic wave propagating with real phase speed. One of the differences between type 1 and type 2 matter-dominated cases is the connectivity of the constant-volume diffusion mode, which originates from the radiative mode in the former case, while from the Newtonian-cooling wave in the latter case. Analytic solutions are derived for all wave modes to discuss their physical significance. The criterion, which distinguishes between radiation-dominated and type 1 matter-dominated cases, is given by Γ₀ = 9, where Γ₀ = C _p ^(tot)/C _V ^(tot) is the ratio of total specific heats at constant pressure and constant volume. Waves in a scattering grey medium are also analyzed, which provides us some hints for the effects of energy and momentum exchange between matter and radiation.     

1992 compilation of analytical data for rare-earth elements, scandium, yttrium, zirconium and hafnium in twenty-six GSJ reference samples

Abstract: Analytical data for fourteen rare-earth elements, scandium, yttrium, zirconium and hafnium, received by May 1992, have been compiled on twenty-six GSJ (Geological Survey of Japan) reference samples. Seventeen of them are 'Igneous rock series' and nine are "Sedimentary rock series". The reported data including personal communication were evaluated under the consideration on analytical methods and geochemical evidences. No significant difference has been observed between the values obtained by the different analytical methods. Based on the selected available data, 1992 compilation values were tabulated.     

ESR dating of quaternary tephra from Mt. Osore-zan using Al and Ti centres in quartz

Quaternary tephra of Mt. Osore-zan was dated by electron spin resonance. Quartz grains were separated from the tephra and ESR signals of Al and Ti centres were measured at 77 K. The signals of Al and Ti centres which have a complicated hyperfine structure were simplified by using wider field modulations width (5 gauss) than usually used (0.5–1 gauss). The influence of 5 gauss modulation width on the measurement of the signal intensity of Al and Ti centres was investigated. The intensity of the signal increases linearly with gamma irradiation and total doses obtained were 178 to 273 Gy and ESR ages were 0.19 to 0.32 Ma. These ages agree with the estimated age of about 0.3 Ma from the correlation of volcanic ash and terrace level.     

Nd and Sr isotopic variations in acidic rocks from Japan: significance of upper-mantle heterogeneity

Initial Nd and Sr isotopic ratios have been measured for Cretaceous acidic and related intermediate rocks (24 volcanic and two plutonic rocks) from the Inner Zone of Southwest Japan (IZSWJ) to investigate the genesis of acidic magmas. The initial Nd and Sr isotopic ratios for these rocks show three interesting features: (1) _Nd values for acidic rocks (+2 to –9) are negatively correlated with _Sr values (+10 to +90) together with those for intermediate rocks ( _Nd=+3 to -8; _Sr=0 to +65). (2) The _Nd values for silica rich rocks (>60% SiO₂) correlate with the longitude of the sample locality, decreasing from west to east in a stepwise fashion: Four areas characterized by uniform _Nd values are discriminated. (3) Low silica rocks (<60% SiO₂) in a certain area have distinctly different _Nd values from those of the high silica rocks in the same area.These results as well as those deduced from the additional samples collected, for comparison, from other provinces in Japan suggest that the acidic rocks can be formed neither by fractional crystallization processes from more basic magmas nor by crustal assimilation processes. The isotopic variations of the acidic rocks may reflect regional isotopic heterogeneity in the lower crust, and this heterogeneity may ultimately be attributed to the regional heterogeneity of the uppermost-mantle beneath the Japanese Islands.