Elemental distribution of coastal sea and stream sediments in the island-arc region of Japan and mass transfer processes from terrestrial to marine environments

A total of 49 elements have been identified in 338 coastal sea sediment samples collected from an area situated off the Ise-Tokai region of Japan for a nationwide marine geochemical mapping project. The spatial distribution patterns of the elemental concentrations in coastal seas along with the existing geochemical maps in terrestrial areas were used to define the natural geochemical background variation, mass transport, and contamination processes. The elemental concentrations of coastal sea sediments are determined primarily by particle size and regional differences. Most elemental concentrations increase with a decrease in particle size. Some elements such as Ca, Mn, and Yb are found to exist in large quantities in coarse particles containing calcareous shells, Fe–Mn oxides, and felsic volcanic sediments. Regional differences reflect the mass transfer process from terrestrial areas to coastal seas and the influence of the local marine geology. An analysis of variance (ANOVA) reveals that for many elements, the particle size effect is predominant over regional difference. The mean chemical compositions of coastal sea sediments are similar to those of stream sediments in adjacent terrestrial areas and in the upper crust of Japan. This observation supports the fact that coastal sea sediments have certainly originated from terrestrial materials. However, the spatial distributions of elemental concentrations are not always continuous between the land and coastal seas. The scale of mass movement observed in marine geochemical maps occurs at a distance of 20 km from the river mouth. A detailed examination of the spatial distribution patterns of K (K₂O) and Cr concentrations suggests that terrestrial materials supplied through rivers are deposited near the shore initially, and then gravity-driven processes shift the sediments deeper into the basin. Contamination with heavy metals such as Zn, Cd and Pb was observed in coastal bays surrounded by urban and industrial areas. It is noteworthy that the areas with the highest concentration of these elements usually do not occur near the shore (not near the contamination source) but at the center of the bay. Unexpected low concentrations of Zn, Cd and Pb near shore may either be due to a decreased anthropogenic load in the most recent sediments or to dilution by unpolluted flood sediments.     

Shear instabilities in arrested salt-wedge flows

‘One-sidedness’ in arrested salt-wedge flows is investigated with theoretical models based upon two-layer approximations. These models include the effects of rigid bottom boundaries and the effects of density interface displacement with respect to the centre of the shear layer. The results indicate that inclusion of both interface displacement and rigid boundaries in the model greatly contribute to the ‘one-sidedness’ phenomenon and influence the wave characteristics, especially their stability criteria. Data from laboratory experiments agreed well with the results produced by these models.     

The Preparation and Characterisation of Two New Geological Survey of Japan Geochemical Reference Materials: Copper ore JCu-1 and Zinc ore JZn-1

Two new geochemical reference materials, copper ore JCu-1 and zinc ore JZn-1 have been prepared by the Geological Survey of Japan (GSJ) for the determination of major and minor elements and isotopic compositions. JCu-1 is a sample of Cu-bearing sulfide ore typical of the Kamaishi mine in Iwate Prefecture, Japan, and is composed mainly of hedenbergite, chalcopyrite, quartz and calcite. Pyrrhotite, magnetite and actinolitic amphibole were also commonly found. The Zn-rich ore, JZn-1 is a crude ore from the Kamioka Pb-Zn mine in Gifu Prefecture, Japan. The sample consists of hedenbergite, quartz, calcite, sphalerite and epidote as main crystalline phase. Homogeneity test results showed that all studied constituents including ore elements such as Cu, Pb and Zn can be considered to be homogeneously distributed. Provisional collaborative analyses were carried out in ten laboratories, and the data were evaluated using a robust statistical method using z-scores. Recommended values for a number of major elements including TiO₂, Al₂O₃, MnO, MgO, CaO, Na₂O, K₂O, Fe (total), Zn, Cu and Pb were established. In addition, information values for eighteen major, minor and trace elements are presented to support future collaborative analyses.     

REE abundances in the matrix of the Allende (CV) meteorite: Implications for matrix origin

Abstract— The trace element distributions in the matrix of primitive chondrites were examined using four least‐contaminated matrix specimens from the polished sections of the Allende (CV) meteorite. Analysis of rare earth element (REE), Ba, Sr, Rb, and K abundances by isotope dilution mass spectrometry revealed that the elemental abundances of lithophile elements except for alkali metals (K, Rb) in the specimens of the Allende matrix studied here are nearly CI (carbonaceous Orgueil) chondritic (～1 × CI). Compared to refractory elements, all the matrix samples exhibited systematic depletion of the moderately volatile elements K and Rb (0.1–0.5 × CI). We suggest that the matrix precursor material did not carry significant amounts of alkali metals or that the alkalis were removed from the matrix precursor material during the parent body process and/or before matrix formation and accretion. The matrix specimens displayed slightly fractionated REE abundance patterns with positive Ce anomalies (CI‐normalized La/Yb ratio = 1.32–1.65; Ce/Ce* = 1.16–1.28; Eu/Eu* = 0.98–1.10). The REE features of the Allende matrix do not indicate a direct relationship with chondrules or calcium‐aluminum‐rich inclusions (CAIs), which in turn suggests that the matrix was not formed from materials produced by the breakage and disaggregation of the chondrules or CAIs. Therefore, we infer that the Allende matrix retains the REE features acquired during the condensation process in the nebula gas.     

ESR detection of seismic frictional heating events in the Nojima fault drill core samples, Japan

We have analyzed the Nojima fault NIED 1800 m drill core samples by ESR (Electron Spin Resonance) to detect seismic frictional heating events, especially during the 1995 Kobe Earthquake. Dark gray fault gouge with foliation > 10 cm away from the fault plane at about 1140 m in depth, which was produced by ancient fault movements, has a FMR (ferrimagnetic resonance) signal. Heating experiments show that this FMR signal is derived from ferrimagnetic trivalent ion oxides (γ-Fe₂O₃: maghemite) with imperfect crystallinity, which is produced by thermal dehydration of γ-FeOOH (lepidocrocite) or Fe(OH)₃ (limonite). The existence of the FMR signal means that dry heating such as frictional heating once occurred, and that the frictional heat temperature along the dark gray fault gouge may have risen to over 350 °C during ancient seismic fault slip. In order to detect frictional heating events in fault zones, the increase of the FMR signal and the color change of fault gouge into dark gray or black are important indexes. On the other hand, no FMR signal is detected from the fault gouges just on two fault planes at about 1140 m and 1300 m in depth, which are considered to be possible main fault planes in the 1995 Kobe Earthquake. These two fault planes may not have played an important role of fault slip in the Earthquake.     

ESR dating of quaternary tephra from Mt. Osore-zan using Al and Ti centres in quartz

Quaternary tephra of Mt. Osore-zan was dated by electron spin resonance. Quartz grains were separated from the tephra and ESR signals of Al and Ti centres were measured at 77 K. The signals of Al and Ti centres which have a complicated hyperfine structure were simplified by using wider field modulations width (5 gauss) than usually used (0.5–1 gauss). The influence of 5 gauss modulation width on the measurement of the signal intensity of Al and Ti centres was investigated. The intensity of the signal increases linearly with gamma irradiation and total doses obtained were 178 to 273 Gy and ESR ages were 0.19 to 0.32 Ma. These ages agree with the estimated age of about 0.3 Ma from the correlation of volcanic ash and terrace level.     

Geochemistry of eclogite‐ and blueschist‐facies rocks from the Bantimala Complex,South Sulawesi,Indonesia: Protolith origin and tectonic setting

We present the first data on bulk‐rock major and trace element compositions for a suite of eclogite‐ and blueschist‐facies rocks from the Bantimala Complex, Indonesia, with the aim of better constraining the protolith origins and nature of the subducted crust. The eclogites can be classified into two groups: glaucophane‐rich eclogite and glaucophane‐free eclogite, whereas the blueschists are divided into albite–epidote glaucophanite and quartz–glaucophane schists. SiO₂ contents of the eclogites are 43.3–49.6 wt%, with Na₂O + K₂O contents 3.7–4.7 wt%. The blueschists show a wider range of compositions, with SiO₂ = 40.7–63.8 wt% and Na₂O + K₂O = 2.7–4.5 wt%. Trace element data suggest that the eclogite protoliths include both enriched and normal mid‐oceanic ridge basalt (E‐MORB and N‐MORB) and also gabbroic cumulates. The blueschists show more variation in protoliths, which include N‐MORB, Oceanic Island Basalt (OIB) and Island Arc Basalt (IAB). Plots of element concentrations against the immobile Zr show considerable mobility of large ion lithophiles but not of high field‐strength elements during high‐pressure metamorphism, and indicate that the high SiO₂ content of some blueschists is probably due to metasomatism by a LILE‐rich siliceous aqueous fluid. Strong correlations between K, Rb, Ba and Cs suggests that enrichment of these elements occurred by a single process. All the protoliths were subducted, metamorphosed to blueschist/eclogite‐facies and subsequently exhumed. It is noteworthy that the samples deduced to have come from thicker‐crust environments (OIB, IAB) were subducted to shallower depths (blueschist‐facies) than MORB‐derived samples, all except one of which reached eclogite‐facies conditions. The geochemical data of this study demonstrate the variety of ocean floor types that were subducted under the southeast margin of Sundaland in the late Jurassic period.     

Long-term (36-year) observations on the dynamics of the fish-killing raphidophyte Chattonella in Harima-Nada,eastern Seto Inland Sea,Japan

Long-term changes of the fish-killing raphidophyte Chattonella spp. (Chattonella antiqua, Chattonella marina and Chattonella ovata) were examined in relation to environmental factors at 19 sampling stations in Harima-Nada, eastern Seto Inland Sea, Japan, for 36 years from 1973 to 2008. Long-term trends in the dynamics of Chattonella populations were considered to relate to environmental factors such as nutrient concentrations and water temperature. High nutrient levels during the period from the 1970s to the early 1980s have contributed to the high cell density and large-scale red tides of Chattonella spp. in Harima-Nada. However, nutrient levels exhibited a decreasing trend thereafter, and it is thought that Chattonella spp. cannot form large-scale blooms under the present conditions. After the mid-1990s, the occurrence period of vegetative cells of Chattonella spp. has been several weeks or 1 month earlier than that of the 1970s and early 1980s, and the appearance frequency of Chattonella spp. has increased in the northern coastal area, although the cell density and the spatial scale of the distribution have become lower and smaller than those in the previous decades. It is suggested that the timing of germination of Chattonella cysts has become earlier as a result of the increase in water temperature, and the chances of vegetative growth have also increased, especially at the northern coast where most of large rivers discharge into the Harima-Nada. In addition, the present results revealed that fewer diatoms were also one of the significant factors for the high abundance of Chattonella spp. in Harima-Nada.     

Epithermal Gold Mineralization in the Trenggalek District,East Java,Indonesia

Gold‐mineralized quartz veins at the Trenggalek district of the Southern Mountains Range in East Java, Indonesia, are hosted by Oligo‐Miocene volcaniclastic and volcanic rocks, and are distributed close to andesitic plugs in the northern prospects (Dalangturu, Suruh, Jati, Gregah, Jombok, Salak, and Kojan) and the southern prospects (Sentul and Buluroto). The plugs are subalkaline tholeiitic basaltic‐andesite to calc‐alkaline andesite in composition. ⁴⁰Ar–³⁹Ar dating of a quartz‐adularia vein at the Dalangturu prospect yielded an age of 16.29 ± 0.56 Ma (2σ), and a crystal tuff of a limestone‐pyroclastic rock sequence at the southwest of the Dalangturu prospect was determined as 15.6 ± 0.5 Ma (2σ). Statistic overlap of ages suggests that the gold mineralization in the northern prospects took place in a shallow marine to subaerial transitional environment. Hydrothermal alteration of the host rocks is characterized by the replacement of quartz, illite and adularia. Quartz veins in surface outcrops are up to 50 cm wide in the northern prospects and up to 3 m wide in the southern prospects, showing a banded or brecciated texture, and are composed of quartz, adularia, carbonates with pyrite, electrum, sphalerite, galena, and polybasite. Gold contents of quartz veins are positively correlated with Ag, Zn, Pb, and Cu contents in both the northern and southern prospects. The quartz veins at the Jati, Gregah, and Sentul prospects have relatively lower gold‐silver ratios (Ag/Au = 23.2) compared to those at the Kojan, Dalangturu, Salak, and Suruh prospects (Ag/Au = 66.8). The quartz veins at the Dalangturu prospect are relatively rich in base metal sulfides. Ag/(Au+Ag) ratios of electrum in the Dalangturu prospect range from 45.2 to 65.0 at%, and FeS contents of sphalerite range from 1.2 to 6.4 mol%. Fluid inclusion microthermometry indicates ore‐forming temperatures of 190–200°C and 220–230°C at the Sentul and Kojan prospects, respectively. Widely variable vapor/liquid ratio of fluid inclusions indicates that fluid boiling took place within the hydrothermal system at the Sentul prospect. Salinities of ore‐fluids range from 0 to 0.7 wt% (av. 0.4 wt% NaCl equiv.) and from 0.5 to 1.4 wt% (av. 0.9 wt%) for the Sentul and Kojan prospects, respectively. The boiling of hydrothermal fluid was one of the gold deposition mechanisms in the Sentul prospect.     

Origin of Bornite Pods in Intrusive Rocks at the Kingking Porphyry Copper-gold Deposit, Southeastern Mindanao, Philippines

At the Kingking porphyry copper-gold deposit, Compostela Valley, south-eastern Mindanao, Philippines, bornite pods occur in the brecciated parts in the biotite diorite porphyry, together with the volcanic rock and diorite fragments without associated stockworks of quartz veinlets. These pods are generally elongated in shape and measure several centimeters across their longest axes. They are composed of bornite and chalcopyrite with traces of calaverite. The δ³⁴S of bornite and subordinate chalcopyrite of bornite pods ranging from −2.2‰ to +0.1‰ are similar to the δ³⁴S of sulfides associated with quartz veinlets such as bornite and chalcopyrite ranging from −4.7‰ to ±0.0‰. This suggests that the ultimate source of sulfur is identical for bornite pods and sulfides associated with quartz veinlets. Bornite pods are associated with volcanic rock and dioritic fragments in the brecciated portion of the biotite diorite porphyry. It was observed that some dioritic fragments contain quartz veinlets, which may indicate an earlier episode of mineralization. Fragments of the earlier dioritic intrusive rocks and the volcanic rocks, together with the sulfides were incorporated into the biotite diorite porphyry magma. A molten sulfide is possible for the composition between bornite and intermediate solid solution at ∼800°C. The sulfides from the earlier dioritic intrusive rocks in the molten state were segregated and then eventually coalesce to form the bornite pods in the brecciated section of the biotite diorite porphyry.