Hydrogen isotopic substitution of solid methylamine through atomic surface reactions at low temperatures: A potential contribution to the D/H ratio of methylamine in molecular clouds

We experimentally studied hydrogen (H)–deuterium (D) substitution reactions of solid methylamine (CH₃NH₂) under astrophysically relevant conditions. We also calculated the potential energy surface for the H–D substitution reactions of methylamine isotopologues using quantum chemical methods. Despite the relatively large energy barrier of more than 18 kJ mol^?1, CH₃NH₂ reacted with D atoms to yield deuterated methylamines at 10 K, suggesting that the H–D substitution reaction proceeds through quantum tunneling. Deuterated methylamines reacted with H atoms as well. On the basis of present results, we propose that methylamine has potential for D enrichment through atomic surface reactions on interstellar grains at very low temperatures in molecular clouds. D enrichment would occur in particular in the methyl group of methylamine.     

hoxY基因的克隆及其在节旋藻和螺旋藻系统学研究的应用

从节旋藻属5个品系和螺旋藻属1个品系中克隆了hoxY基因的部分序列.序列长度都是479bp.在节旋藻中该基因GC含量为46.0%～46.6%,螺旋藻中为43.5%.节旋藻各品系间序列的相似性介于93.7%～100%,明显高于节旋藻属和螺旋藻属间的序列相似性（69.5%～72.2%）.2个属中镍铁氢化酶小亚基HoxY氨基酸序列的比较也表明螺旋藻和节旋藻之间存在较大差异.利用MEGA2通过比较核酸序列构建了系统树,表明螺旋藻和节旋藻属处于不同的分枝.     

A low cost meteor observation system using radio forward scattering and the interferometry technique

We present a low cost meteor observation system based on the radio forward scattering and interferometry technique at Kochi University of Technology (KUT). The system can be a suitable model for low budget educational institutes that target practical learning of astronomical objects and upper atmospheric characteristics. The system methodology for the automatic counting of meteor echoes, filtering noise and detecting meteor echo directions is described. Detection of the meteor echo directions, which is the basic element for determining the meteor trajectories and the orbital parameters of parent comets, is based on a software system developed for analysis of phase differences detected by interferometry. Randomly selected observation samples measured by the radio interferometer are compared to simultaneous optical observations by video cameras to verify the system accuracy. Preliminary error analysis revealed that the system accuracy is directly related to the duration of observed meteor echoes. Eighty percent of meteor echo samples with durations longer than 3 s showed agreement in azimuth and elevation angles measurements to within a 10° error range, while meteor echo samples with shorter durations showed lower agreement levels probably due to the low system sampling resolution of 0.1 s. The reasonable agreement level of meteor echoes with duration longer than 3 s demonstrated the applicability of the system methodology. Accurate observation of shorter duration meteor echoes could possibly be achieved by improving the system resolution.     

Initial rupture process of microearthquakes recorded by high sampling borehole seismographs at the Nojima fault, central Japan

We analyze high sampling waveforms of the initial part of P-wave recorded at the 1800-m-deep borehole seismographs at the Nojima fault from December 1999 to May 2000 to clarify the initial rupture process of microearthquakes. We select 12 events with high S/N, whose magnitudes range from −0.3 to 2.2 and hypocentral distances from 1 to 11 km. We adopt the two different source models by Sato and Hirasawa (1973) and by Sato and Kanamori (1999). The former (model by Sato and Hirasawa (SH model)) generates only a ramp-like onset of velocity pulse. The later (model by Sato and Kanamori (SK model)) is able to generate a weak initial phase that is controlled by a trigger factor and the length of pre-existing crack. We perform the waveform inversion to estimate the optimum source parameters of each model. Waveforms of 5 of the 12 events are clearly reproduced by both SH model and SK model with a large trigger factor and a small length of pre-existing crack. The others are explained by not SH model but only SK model with a small trigger factor and a large length of the pre-existing crack, indicating that the weak initial phase is a nucleation phase and reflects the source process. These seven events satisfy roughly a relation that a large event has a large length of the pre-existing crack; the final crack length is proportional to the length of the pre-existing crack.     

230Th/234U and 14C dating of a lowstand coral reef beneath the insular shelf off Irabu Island, Ryukyus, southwestern Japan

Abstract   High-resolution seismic reflection profiles delineated the distribution of mound-shaped reflections, which were interpreted as reefs, beneath the insular shelf western off Irabu Island, Ryukyus, southwestern Japan. A sediment core through one of the mounded structures was recovered from the sea floor at a depth of −118.2 m by offshore drilling and was dated by radiometric methods. The lithology and coral fauna of the core indicate that the mounded structure was composed of coral–algal boundstone suggesting a small-scaled coral reef. High-precision α-spectrometric ²³⁰Th/²³⁴U dating coupled with calibrated accelerator mass spectrometric ¹⁴C ages of corals obtained reliable ages of this reef ranging from 22.18 ± 0.63 to 30.47 ± 0.98 ka. This proves that such a submerged reef was formed during the lowstand stage of marine oxygen isotope stages 3–2. The existence of low-Mg calcite in the aragonitic coral skeleton of 22.18 ± 0.63 ka provides evidence that the reef had once been exposed by lowering of the relative sealevel to at least −126 m during the last glacial maximum in the study area. There is no room for doubt that a coral reef grew during the last glacial period on the shelf off Irabu Island of Ryukyus in the subtropical region of western Pacific.     

Geology of the summit limestone of Mount Qomolangma (Everest) and cooling history of the Yellow Band under the Qomolangma detachment

Abstract   Newly discovered peloidal limestone from the summit of Mount Qomolangma (Mount Everest) contains skeletal fragments of trilobites, ostracods and crinoids. They are small pebble-sized debris interbedded in micritic bedded limestone of the Qomolangma Formation, and are interpreted to have been derived from a bank margin and redeposited in peri-platform environments. An exposure of the Qomolangma detachment at the base of the first step (8520 m), on the northern slope of Mount Qomolangma was also found. Non-metamorphosed, strongly fractured Ordovician limestone is separated from underlying metamorphosed Yellow Band by a sharp fault with a breccia zone. The ⁴⁰Ar–³⁹Ar ages of muscovite from the Yellow Band show two-phase metamorphic events of approximately 33.3 and 24.5 Ma. The older age represents the peak of a Barrovian-type Eo-Himalayan metamorphic event and the younger age records a decompressional high-temperature Neo-Himalayan metamorphic event. A muscovite whole-rock ⁸⁷Rb–⁸⁶Sr isochron of the Yellow Band yielded 40.06 ± 0.81 Ma, which suggests a Pre-Himalayan metamorphism, probably caused by tectonic stacking of the Tibetan Tethys sediments in the leading margin of the Indian subcontinent. Zircon and apatite grains, separated from the Yellow Band, gave pooled fission-track ages of 14.4 ± 0.9 and 14.4 ± 1.4 Ma, respectively. These new chronologic data indicate rapid cooling of the hanging wall of the Qomolangma detachment from approximately 350°C to 130°C during a short period (15.5–14.4 Ma).     

Molecular cloning and mRNA expression of cytochrome P4501A1 and 1A2 in the liver of common minke whales (Balaenoptera acutorostrata)

This study presents full-length cDNA sequences of CYP1A1 and 1A2, in common minke whale (Balaenoptera acutorostrata) from the North Pacific. Both CYP1A1 and CYP1A2 cDNAs had an open reading frame of 516 amino acid residues, and predicted molecular masses were 58.3 kDa and 58.1 kDa, respectively. The deduced full-length amino acid sequence of CYP1A1 revealed higher identities with those of sheep (86%) and pig (87%), and that of CYP1A2 was most closely related to human (82%) and monkey CYP1A2 (82%) among species from which CYP1A2 has been isolated so far. Differences in certain conserved and functional amino acid residues of CYP1A1 and 1A2 between common minke whale and other mammalian species indicate the possibility of their specific metabolic function. Concentrations of organochlorine compounds (OCs) including PCBs and DDTs analyzed in common minke whale liver showed no significant correlation with hepatic mRNA expression levels of CYP1A1 and CYP1A2, indicating no induction of these enzymes by such OCs.