High-temperature neutron diffraction study of deuterated brucite

To study the structural behavior of brucite at high temperature, we conducted in situ neutron diffraction experiments of a deuterated brucite powder sample, Mg(OD)₂, in the temperature range 313–583 K. The sample was stable up to 553 K, above which it started to decompose into periclase (MgO) and D₂O vapor. Rietveld analyses of the obtained data were performed using both single-site and three-site split-atom hydrogen models. Our results show that with increasing temperature, unit-cell parameter c increases at a rate ~7.7 times more rapidly than a. This large anisotropy of thermal expansion is primarily due to rapid increase in the interlayer thickness along the c-axis on heating. The amplitudes of thermal vibration for Mg, O, and D increase linearly with increasing temperature; however, the rate of the increase for the lighter D is much larger. In addition, D vibrates anisotropically with a higher magnitude within the (001) plane, as confirmed by our first-principles phonon calculations. On heating, the interatomic distances between a given D and its associated O and D from the adjacent [MgO₆] layer increase, whereas the O–D bond length decreases. This behavior suggests weakened D···O and D···D interlayer interactions but strengthened O–D bonding with increasing temperature.     

顾及排序差异的对象群邻近关系相似性计算

针对空间邻近关系相似性的定量化计算问题,在确定邻近特征量的基础上,将相似性度量的要素模型和对准模型结合起来,建立了顾及排序差异的对象群邻近关系相似性计算方法,并验证了该方法的可用性。     

Oxygen depletion and phosphorus release following flooding of a cultivated wetland area in Denmark

Geografisk Tidsskrift, Danish Journal of Geography 108(2):17–25, 2008

The rewetting of altered wetlands is becoming increasingly widespread. When flooding cultivated soils, the oxygen (O₂) availability is reduced, subsequently, ferric hydroxides can dissolve and associated inorganic phosphorus (P) will be mobilized. This study shows the temporal and spatial dynamics of O₂ depletion following flooding using planar optodes and the subsequent release of Fe and P in two depth intervals in an experimental column set-up. The column was kept flooded for 48 days and thereafter partly drained and flooded again. Results document that large amounts of P (0.2 t P ha-¹) have accumulated in the present plough-layer (Ap) during the last 22 years, which represent roughly 15% of the present inorganic P stock in the Ap. As a result of flooding, fully anoxic conditions were observed within 3 days (within 10 h in Ap) and concentrations of dissolved Fe and P in the soil solution increased simultaneously after 7 days of flooding. Thus, P reaction kinetics was markedly delayed as compared to O₂ availability. P concentrations in soil water afterflooding (up to 0.15 mg L^?1) accounted for only 0.034% of the inorganic P stock in the Ap which is a significantly smaller fraction of the potential P-release as compared to previous investigations.

This is considered a result of only a minor fraction of the total inorganic P being directly associated with ferric hydroxides and thereby sensitive to short-term anoxic conditions as well as differences in the methodology used in this study (soil/water ratio). Finally, reactions releasing Fe and P were noted to be partly reversible upon draining.     

Turn calculations for the indoor application of the fewest turns path algorithm

ABSTRACT

Present-day indoor navigation systems are often not well adapted to the specific needs and requirements of its users. This research aims at improving those indoor navigation systems by providing navigation support that cognitively closer to user preferences and behaviour. More specifically, the focus is on the implementation of an accurate turn calculation method in a turn minimization algorithm, aiming to lower the complexity of routes and route instructions. This new-introduced perception-based turn calculation procedure is based on a direct door-to-door walking pattern, and, in contrast to previous algorithms, independent of the underlying indoor network type. It takes into account the effects of geometry of indoor space on human movement. To evaluate its functioning, both the traditional algorithm and the proposed perception-based algorithm are applied in the fewest turns path algorithm. It is demonstrated that the proposed algorithm accurately calculates turns in alignment with people’s perception. The implementation of the calculation algorithm in the fewest turns path algorithm also allows future applications in indoor simplest path algorithms, and overall contributes to cognitively richer indoor navigation systems.     

Inverted channel deposits on the floor of Miyamoto crater, Mars

Morphological features on the western floor of Miyamoto crater in southwestern Meridiani Planum, Mars, are suggestive of past fluvial activity. Imagery from the High Resolution Imaging Science Experiment (HiRISE) gives a detailed view of raised curvilinear features that appear to represent inverted paleochannel deposits. The inverted terrain appears to be capped with a resistant, dark-toned deposit that is partially covered by unconsolidated surficial materials. Subsequent to deposition of the capping layer, erosion of the surrounding material has left the capping materials perched on pedestals of uneroded basal unit material. Neither the capping material nor the surrounding terrains show any unambiguous morphological evidence of volcanism or glaciation. The capping deposit may include unconsolidated or cemented stream deposits analogous to terrestrial inverted channels in the Cedar Mountain Formation near Green River, Utah. In addition to this morphological evidence for fluvial activity, phyllosilicates have been identified in the basal material on the floor of Miyamoto crater by orbital spectroscopy, providing mineralogical evidence of past aqueous activity. Based on both the morphological and mineralogical evidence, Miyamoto crater represents an excellent site for in situ examination and sampling of a potentially habitable environment.     

Anthropogenic pollution stimulates oxidative stress in soft tissues of mussel <Emphasis Type="Italic">Crenomytilus grayanus</Emphasis> (Dunker1853)

The digestive gland and gills of the mussel Crenomytilus grayanus extracted from three locations — (i) sampled from a clean and (ii) polluted site and (iii) transplanted from the nonpolluted to polluted site - were analysed for antioxidant enzymes (superoxide dismutase, catalase, glutathione reductase), total oxyradical scavenging capacity and levels of lipid peroxidation products (malondialdehyde, conjugated dienes and lipofuscin). Perturbation of redox status was found in both digestive gland and gill tissues of mussels living in the polluted area. As the activities of superoxide dismutase and catalase were 1.2–3 times higher, the total oxyradical scavenging capacity was lower by 20–35% and the levels of lipid peroxidation products were 2–7 times higher compared to mussels from the reference site. In transplanted mussels, the lipid peroxidation process in both tissues was significantly stimulated (the level of conjugated dienes was increased 1.7–2.5-fold; malondialdehyde and lipofuscin contents were increased 3.5–5-fold) and the total oxyradical scavenging capacity fell by 50–70%. In addition, the transplantation generally resulted in transient and variable responses of antioxidant enzymes for both tissues. Complex response-behaviour of the antioxidant enzymes strongly points to the necessity of employing a combined approach that takes into account activities of antioxidant enzymes and the total oxyradical scavenging capacity, as well as measurement of oxidative damage (e.g., lipid peroxidation) to evaluate the physiological health of molluscs.     

Radiochemoecological Monitoring of the Salt Lakes of the Crimea

正1 Introduction The salt lakes of the Crimea contain the practically inexhaustible sources of salts of sodium,magnesium,bromine and other chemical elements(Ponizovskii,1965),being the potential powerful raw materials base for the     

New paleomagnetic data from Late Neoproterozoic sedimentary successions in Southern Urals,Russia: implications for the Late Neoproterozoic paleogeography of the Iapetan realm

We present the results of paleomagnetic study of Ediacaran sedimentary successions from the Southern Urals. The analysis of the sedimentary rocks of the Krivaya Luka, Kurgashlya and Bakeevo Formations reveal stable mid-temperature and high-temperature remanence components. Mid-temperature components were acquired during Devonian (Bakeevo Formation) and Late Carboniferous–Early Permian remagnetization events. The high-temperature components in Kurgashlya and Bakeevo Formations are interpreted to be primary, because they are supported by a positive conglomerate test (Bakeevo Formation) and magnetostratigraphic pattern (Kurgashlya Formation). The high-temperature component in the Krivaya Luka Formation is interpreted to be a Late Ediacaran overprint. Our new paleomagnetic poles together with some previously published Ediacaran poles from Baltica and Laurentia are used herein to produce a series of paleogeographic reconstructions of the opening of the Iapetus Ocean.     

Capabilities and limitations of numerical ice sheet models: a discussion for Earth-scientists and modelers

The simulation of dynamically coupled ice sheet, ice stream, and ice shelf-systems poses a challenge to most numerical ice sheet models. Here we review present ice sheet model limitations targeting a broader audience within Earth Sciences, also those with no specific background in numerical modeling, in order to facilitate cross-disciplinary communication between especially paleoglaciologists, marine and terrestrial geologists, and numerical modelers. The ‘zero order’ (Shallow Ice Approximation, SIA)-, ‘higher order’-, and ‘full Stokes’ ice sheet models are described conceptually and complemented by an outline of their derivations. We demonstrate that higher order models are required to simulate coupled ice sheet-ice shelf and ice sheet-ice stream systems, in particular if the results are aimed to complement spatial ice flow reconstructions based on higher resolution geological and geophysical data. The zero order SIA model limitations in capturing ice stream behavior are here illustrated by conceptual simulations of a glaciation on Svalbard. The limitations are obvious from the equations comprising a zero order model. However, under certain circumstances, simulation results may falsely give the impression that ice streams indeed are simulated with a zero order SIA model.