Predicted wavelengths of coronal transitions in the configurations 3s 23p 2, 3s 23p 3 and 3s 23p 4

The level intervals in the ground configurations 3s ²3p ^k(k = 2, 3, 4) have been studied through the isoelectronic sequences up to Ni. Semiempirical expressions for the parameters F ₂(pp) and _p, are derived from observed data and the intervals are recalculated from interpolated or extrapolated values of the parameters. As a result, predicted wavelengths of magnetic-dipole transitions within the configurations are obtained with an estimated uncertainty of one or two Å.     

四川黄龙沟景区钙华的起源和形成机理研究

对四川黄龙沟钙华景区的水化学测试发现，形成黄龙沟钙华的泉水具有很高的Ca^2 和HC03^-离子浓度，相应地，泉水的C02分压显著高于大气和土壤生物成因所能产生的C02分压。结合泉水出露的地质条件和泉口C02气体碳稳定同位素组成(δ^13C＝—6．8‰)的分析，进一步发现，高C02分压与深部成因的C02有关。可见，黄龙沟钙华属于热成因类钙华，而非原来普遍认为的“是气候岩溶作用的产物”。此外，黄龙沟钙华的大量出现与水中方解石的迅速沉积、Ca^2 和HC03^-浓度的大量降低有关。随着地下水自泉口出露，由于水的C02分压远高于大气，水中C02大量释放于大气，结果水的pH值迅速升高，方解石饱和指数由泉口的负值很快转变为高的正值，为方解石的沉积奠定了必要的物理化学基础。放置于水中的大理岩石片观测表明，流速较快的边石坝处的方解石沉积速率是其附近水池内的2—5倍，这清楚地显示了水动力条件对沉积速率的控制。进一步根据DBL理论模型分析发现，水动力条件对方解石沉积速率的控制在于其对固液界面间扩散边界层(DBL)厚度的影响，流速愈快，DBL厚度愈薄。且DBL厚度最终制约着沉积表面的化学组成浓度，即厚度愈小，表面H^ 浓度愈低(或pH愈高)、方解石饱和指数愈高，进而方解石沉积愈快。     

Toxic effects of decomposing red algae on littoral organisms

Large masses of filamentous red algae of the genera Polysiphonia, Rhodomela, and Ceramium are regularly washed up on beaches of the central Baltic Sea. As the algal masses start to decay, red coloured effluents leak into the water, and this tinge may be traced several hundred meters off shore. In this study, possible toxic effects of these effluents were tested on littoral organisms from different trophic levels. Effects on fertilisation, germination and juvenile survival of the brown seaweed Fucus vesiculosus were investigated, and mortality tests were performed on the crustaceans Artemia salina and Idotea baltica, as well as on larvae and adults of the fish Pomatoschistus microps. Fucus vesiculosus was the most sensitive species of the tested organisms to the red algal extract. The survival of F. vesiculosus recruits was reduced with 50% (LC50) when exposed to a concentration corresponding to 1.7 g l⁻¹ dw red algae. The lethal concentration for I. baltica, A. salina and P. microps were approximately ten times higher. The toxicity to A. salina was reduced if the algal extract was left to decompose during two weeks but the decline in toxicity was not affected by different light or temperature conditions. This study indicates that the filamentous red algae in the central Baltic Sea may produce and release compounds with negative effects on the littoral ecosystem. The effects may be particularly serious for the key species F. vesiculosus, which reproduce in autumn when filamentous red algal blooms are most severe.     

Relation between neighbouring grains in the upper part of the NorthGRIP ice core — Implications for rotation recrystallization

We propose a new method to investigate the relationships between neighbouring crystals and apply it to the textures measured along the upper 900 m of the NorthGRIP ice core. This method shows unexpected correlations between neighbours in the so-called normal grain growth regime, questioning the classical view on the onset of rotation recrystallization in ice-sheets. Moreover, the fractionation rate associated to the rotation recrystallization appears constant through time. Finally, grains with low-angle boundaries do not present a special distribution pattern of their c-axes. This suggests that rotation recrystallization is an isotropic process not affected by the direction of the macroscopic strain.     

The Sensitivity Of A Stratocumulus Transition: Model Simulations Of The Astex First Lagrangian

In this study, a one-dimensional ensemble-average model is used to simulatethe Atlantic Stratocumulus Transition Experiment firstLagrangian, where the same airmass was followed from the subtropical high pressure region en route towards the trade wind region. The airmass experiences increasing sea-surface temperature and achange from subsidence to weak ascent on its way south. Thiscauses the marine boundary layer (MBL)to grow and the cloud deck to change from a solid stratocumulus deck tomore broken stratocumulus clouds with cumulus cloudsdeveloping beneath, and reaching up into the stratocumulus clouds.A control run is analyzed and compared in detail with theobservations. Both a statistical evaluation and a more subjective evaluation are performed, where both establish confidencein the model performance. The model captures the MBL growth and the cloudliquid water, as well as the drizzle flux, is well predicted by the model.A sensitivity study was performed with the objective of examining theMBL and the cloud response to external and internal 'forces'.The results show that, if drizzle formation is not allowed,unrealistically high cloud liquid water mixing ratios are predicted. Even though the drizzle flux is very small, it is still important for the water budget of the MBL and for the boundary-layer dynamics.We also found that the sea-surface temperature increase is more important for the increasing cloud top height than the synoptic-scale divergence fields. However, the synoptic-scale subsidence is crucial during the first day, when the sea-surface temperature was constant, in keepingthe cloud top at a constant height. Drizzle evaporation below the cloud base seems to be important for below-cloud condensation. The drizzle predictions are significantly altered when the prescribed cloud droplet and/or drizzle drop numbers are altered.     

Impacts of Climate Change on Growth Period and Planting Boundaries of Spring Wheat in China under RCP4.5 Scenario

This article contributes to research on how climate change will impact crops in China by moving from ex-post empirical analysis to forecasting. We construct a multiple regression model, using agricultural observations and meteorological simulations by GCMs, to simulate the possible planting boundaries and suitable planting regions of spring wheat under RCP4.5 scenario for the base period 2040s and 2070s. We find that the south boundary of possible planting region for spring wheat spreads along the belt: south Shandong-north Jiangsu-north Anhui-central Henan-north Hubei-southeast Sichuan-north Yunnan provinces, and will likely move northward under RCP4.5 scenario in 2040s and 2070s, resulting in the decrease of possible planting area in China. Moreover, the sowing and harvest date of spring wheat in the base period shows a gradually delayed phenomenon from the belt: south Xinjiang - Gansu, to the Tibet Plateau. As a result, the growth period of spring wheat in China will shorten because of the impacts of climate change. These results imply that a variety of adaptations measures should be set up in response to changing climatic conditions, including developing the planting base for spring wheat, restricting the planting area of spring wheat in sub-suitable areas at risk while expanding the planting area of optimal crops.     

‘Modelling the Arctic Boundary Layer: An Evaluation of Six Arcmip Regional-Scale Models using Data from the Sheba Project’

A primary climate change signal in the central Arctic is the melting of sea ice. This is dependent on the interplay between the atmosphere and the sea ice, which is critically dependent on the exchange of momentum, heat and moisture at the surface. In assessing the realism of climate change scenarios it is vital to know the quality by which these exchanges are modelled in climate simulations. Six state-of-the-art regional-climate models are run for one year in the western Arctic, on a common domain that encompasses the Surface Heat Budget of the Arctic Ocean (SHEBA) experiment ice-drift track. Surface variables, surface fluxes and the vertical structure of the lower troposphere are evaluated using data from the SHEBA experiment. All the models are driven by the same lateral boundary conditions, sea-ice fraction and sea and sea-ice surface temperatures. Surface pressure, near-surface air temperature, specific humidity and wind speed agree well with observations, with a falling degree of accuracy in that order. Wind speeds have systematic biases in some models, by as much as a few metres per second. The surface radiation fluxes are also surprisingly accurate, given the complexity of the problem. The turbulent momentum flux is acceptable, on average, in most models, but the turbulent heat fluxes are, however, mostly unreliable. Their correlation with observed fluxes is, in principle, insignificant, and they accumulate over a year to values an order of magnitude larger than observed. Typical instantaneous errors are easily of the same order of magnitude as the observed net atmospheric heat flux. In the light of the sensitivity of the atmosphere–ice interaction to errors in these fluxes, the ice-melt in climate change scenarios must be viewed with considerable caution.     

The Greenland Ice Core Chronology 2005, 15–42 ka. Part 2: comparison to other records

A new Greenland Ice Core Chronology (GICC05) based on multi-parameter counting of annual layers has been obtained for the last 42 ka. Here we compare the glacial part of the new time scale, which is based entirely on records from the NorthGRIP ice core, to existing time scales and reference horizons covering the same period. These include the GRIP and NorthGRIP modelled time scales, the Meese-Sowers GISP2 counted time scale, the Shackleton–Fairbanks GRIP time scale (SFCP04) based on ¹⁴C calibration of a marine core, the Hulu Cave record, three volcanic reference horizons, and the Laschamp geomagnetic excursion event occurring around Greenland Interstadial 10. GICC05 is generally in good long-term agreement with the existing Greenland ice core chronologies and with the Hulu Cave record, but on shorter time scales there are significant discrepancies. Around the Last Glacial Maximum there is a more than 1 ka age difference between GICC05 and SFCP04 and a more than 0.5 ka discrepancy in the same direction between GICC05 and the age of a recently identified tephra layer in the NorthGRIP ice core. Both SFCP04 and the tephra age are based on ¹⁴C-dated marine cores and fixed marine reservoir ages. For the Laschamp event, GICC05 agrees with a recent independent dating within the uncertainties.