The geochemical composition of the terrestrial surface (without soils) and comparison with the upper continental crust

The terrestrial surface, the “skin of the earth”, is an important interface for global (geochemical) material fluxes between major reservoirs of the Earth system: continental and oceanic crust, ocean and atmosphere. Because of a lack in knowledge of the geochemical composition of the terrestrial surface, it is not well understood how the geochemical evolution of the Earth’s crust is impacted by its properties. Therefore, here a first estimate of the geochemical composition of the terrestrial surface is provided, which can be used for further analysis. The geochemical average compositions of distinct lithological classes are calculated based on a literature review and applied to a global lithological map. Comparison with the bulk composition of the upper continental crust shows that the geochemical composition of the terrestrial surface (below the soil horizons) is significantly different from the assumed average of the upper continental crust. Specifically, the elements Ca, S, C, Cl and Mg are enriched at the terrestrial surface, while Na is depleted (and probably K). Analysis of these results provide further evidence that chemical weathering, chemical alteration of minerals in marine settings, biogeochemical processes (e.g. sulphate reduction in sediments and biomineralization) and evaporite deposition are important for the geochemical composition of the terrestrial surface on geological time scales. The movement of significant amounts of carbonate to the terrestrial surface is identified as the major process for observed Ca-differences. Because abrupt and significant changes of the carbonate abundance on the terrestrial surface are likely influencing CO₂-consumption rates by chemical weathering on geological time scales and thus the carbon cycle, refined, spatially resolved analysis is suggested. This should include the recognition of the geochemical composition of the shelf areas, now being below sea level.     

In situ methods for measuring thermal properties and heat flux on planetary bodies

The thermo-mechanical properties of planetary surface and subsurface layers control to a high extent in which way a body interacts with its environment, in particular how it responds to solar irradiation and how it interacts with a potentially existing atmosphere. Furthermore, if the natural temperature profile over a certain depth can be measured in situ, this gives important information about the heat flux from the interior and thus about the thermal evolution of the body. Therefore, in most of the recent and planned planetary lander missions experiment packages for determining thermo-mechanical properties are part of the payload. Examples are the experiment MUPUS on Rosetta's comet lander Philae, the TECP instrument aboard NASA's Mars polar lander Phoenix, and the mole-type instrument HP³ currently developed for use on upcoming lunar and Mars missions. In this review we describe several methods applied for measuring thermal conductivity and heat flux and discuss the particular difficulties faced when these properties have to be measured in a low pressure and low temperature environment. We point out the abilities and disadvantages of the different instruments and outline the evaluation procedures necessary to extract reliable thermal conductivity and heat flux data from in situ measurements.     

Quaternary bimodal volcanism in the Niğde Volcanic Complex (Cappadocia,central Anatolia,Turkey): age,petrogenesis and geodynamic implications

The late Neogene to Quaternary Cappadocian Volcanic Province (CVP) in central Anatolia is one of the most impressive volcanic fields of Turkey because of its extent and spectacular erosionally sculptured landscape. The late Neogene evolution of the CVP started with the eruption of extensive andesitic-dacitic lavas and ignimbrites with minor basaltic lavas. This stage was followed by Quaternary bimodal volcanism. Here, we present geochemical, isotopic (Sr–Nd–Pb and δ¹⁸O isotopes) and geochronological (U–Pb zircon and Ar–Ar amphibole and whole-rock ages) data for bimodal volcanic rocks of the Ni?de Volcanic Complex (NVC) in the western part of the CVP to determine mantle melting dynamics and magmatic processes within the overlying continental crust during the Quaternary. Geochronological data suggest that the bimodal volcanic activity in the study area occurred between ca. 1.1 and ca. 0.2 Ma (Pleistocene) and comprises (1) mafic lavas consisting of basalts, trachybasalts, basaltic andesites and scoria lapilli fallout deposits with mainly basaltic composition, (2) felsic lavas consisting of mostly rhyolites and pumice lapilli fall-out and surge deposits with dacitic to rhyolitic composition. The most mafic sample is basalt from a monogenetic cone, which is characterized by ⁸⁷Sr/⁸⁶Sr = 0.7038, ¹⁴³Nd/¹⁴⁴Nd = 0.5128, ²⁰⁶Pb/²⁰⁴Pb = 18.80, ²⁰⁷Pb/²⁰⁴Pb = 15.60 and ²⁰⁸Pb/²⁰⁴Pb = 38.68, suggesting a moderately depleted signature of the mantle source. Felsic volcanic rocks define a narrow range of ¹⁴³Nd/¹⁴⁴Nd isotope ratios (0.5126–0.5128) and are homogeneous in Pb isotope composition (²⁰⁶Pb/²⁰⁴Pb = 18.84–18.87, ²⁰⁷Pb/²⁰⁴Pb = 15.64–15.67 and ²⁰⁸Pb/²⁰⁴Pb = 38.93–38.99). ⁸⁷Sr/⁸⁶Sr isotopic compositions of mafic (0.7038–0.7053) and felsic (0.7040–0.7052) samples are similar, reflecting a common mantle source. The felsic rocks have relatively low zircon δ¹⁸O values (5.6 ± 0.6 ‰) overlapping mantle values (5.3 ± 0.3 %), consistent with an origin by fractional crystallization from a mafic melt with very minor continental crustal contamination. The geochronological and geochemical data suggest that mafic and felsic volcanic rocks of the NVC are genetically closely related to each other. Mafic rocks show a positive trend between ⁸⁷Sr/⁸⁶Sr and Th, suggesting simultaneous assimilation and fractional crystallization, whereas the felsic rocks are characterized by a flat or slightly negative variation. High ⁸⁷Sr/⁸⁶Sr gneisses are a potential crustal contaminant of the mafic magmas, but the comparatively low and invariant ⁸⁷Sr/⁸⁶Sr in the felsic volcanics suggests that these evolved dominantly by fractional crystallization. Mantle-derived basaltic melts, which experienced low degree of crustal assimilation, are proposed to be the parent melt of the felsic volcanics. Geochronological and geochemical results combined with regional geological and geophysical data suggest that bimodal volcanism of the NVC and the CVP, in general, developed in a post-collisional extensional tectonic regime that is caused by ascending asthenosphere, which played a key role during magma genesis.     

High-grade metamorphism of ironstones in the Mesoarchaean of southwest Swaziland

A sequence of high-grade rocks collectively referred to as Mkhondo Valley Metamorphic Suite is exposed around the Nhlangano Gneiss Dome in southwest Swaziland and also less extensively further north. Meta-ironstones are part of this sequence and have been studied specifically with two main objectives in mind, firstly, to test the hypothesis of the high-grade metamorphic sequence correlating with lower-grade Pongola-age rocks nearby, and secondly, to assess the potential of these meta-ironstones for retrieving P-T conditions of metamorphism. The studied ironstones contain substantial Al due to terrigenous clastic input and also include Mn-rich varieties. Three compositional groups of meta-ironstones can be distinguished: garnet-orthopyroxene-bearing ones, garnet-bearing, orthopyroxene-free ones, and a garnet-poor to garnet-free type. A comparison of bulk rock compositions between these high-grade meta-ironstones and low-grade Mn-poor to Mn-rich ironstones from the Mozaan Group supports a stratigraphic correlation. Pseudosection modelling demonstrates that aluminous meta-ironstones provide useful P-T constraints at high peak temperatures as they do not tend to produce significant amounts of melt, if any. The presence of Al is critical for introducing garnet to amphibolite and granulite-facies assemblages, which also allows to apply conventional thermobarometers. The combination of pseudosection modelling and conventional thermobarometry yielded peak metamorphic conditions of 850–890 °C at 7 to 8 kbar. These data are compatible with the ones obtained from associated metapelitic gneisses, except that the latter indicate decompression to lower pressure granulite-facies conditions. The petrological, structural and geochronological data from southwest Swaziland confirm major orogenic activity in the eastern Kaapvaal Craton during the Neo-Archaean.     

Comparative study to evaluate three ground-based optical remote sensing techniques under field conditions by a gas tracer experiment

Today, ground-based optical remote sensing (ORS) has become an intensively used method for quantifying pollutant or greenhouse gas emissions from point or area sources, and for the validation of airborne or satellite remote sensing data. In this study, we present the results of a release experiment using acetylene (C₂H₂) as a tracer gas, where three ORS techniques were simultaneously tested for two main purposes: (1) the detection of emission sources and (2) the quantification of release rates. Therefore, passive and active open-path Fourier transform infrared spectroscopy (OP-FTIR) and open-path tunable diode laser absorption spectroscopy (TDLAS) were applied and evaluated. The concentration results of the active ORS methods are compared to those estimated by a Lagrangian stochastic atmospheric dispersion model. Our results reveal that passive OP-FTIR is a valuable tool for the rapid detection and imaging of emission sources and the spatial tracer gas distribution; while with active OP-FTIR and TDLAS, C₂H₂ concentrations in the sub-ppm range could be quantified that correlated well with the concentration data obtained by our modeling approach.     

Visualizing the temporal development of thermo-radiative features on ground-based thermographs

In urban microclimate research, ground-based thermography is used to gain insight into the spatial distribution of surface temperatures of various materials. Taking snapshots over a certain time span helps experts to observe the temporal thermo-radiative behavior of the monitored surface elements and therefore supports decisions on possible optimizations, e.g., improving the thermal comfort in a neighborhood. Appropriate visualization techniques facilitate decision-making and are thus crucial in the optimization process. In this study, we present a tool that eases the extraction of thermo-radiative features from multi-temporal thermographs taken from a monitored scene. Assisted by our tool, users can identify, choose, and register thermo-radiative features for each time step according to their individual research needs. The features’ temporal development is then visualized using a directed graph that encodes topological events as well as each feature’s size and summarizing statistics. To enhance this summary, a comprehensive animated sequence emphasizes the spatiotemporal behavior of the most significant thermo-radiative features. Salient developments are visually embedded and highlighted in the original infrared images, which are blended in an animation from time step to time step. Since we enable the user to interact with the data in a flexible way, noisy and low resolution image data sets can also be processed.     

Towards a complete magmatic barcode for the Zimbabwe craton: Baddeleyite U–Pb dating of regional dolerite dyke swarms and sill complexes

We present baddeleyite U–Pb ages of Neoarchaean to Palaeoproterozoic dyke swarms and the Mashonaland sill province in Zimbabwe. The 2575.0 ± 1.5 Ma age of the Umvimeela dyke is indistinguishable from the 2575.4 ± 0.7 Ma result (Oberthür et al., 2002) for a pyroxenite layer of the Great Dyke and testifies to synchronous emplacement of the Great Dyke and its satellites. Three samples of WNW- to NNW-trending dykes of the Sebanga swarm yielded ages of 2512.3 ± 1.8 Ma, 2470.0 ± 1.2 Ma and 2408.3 ± 2.0 Ma, the latter of which dates the Sebanga Poort Dyke of this swarm. These results suggest that emplacement took place over a protracted period which involved at least three generations of dykes within the swarm and, more importantly, invalidate previous inferences of a genetic link between the Sebanga swarm and the Mashonaland sills. Crystallisation ages of 1877 ± 2.2 Ma, 1885.9 ± 2.4 Ma and 1875.6 ± 1.6 Ma for three dolerite samples of the extensive Mashonaland sills from different parts of the Zimbabwe craton were also obtained. This is the oldest common igneous event that is recorded in the Zimbabwe and Kaapvaal cratons. Collectively with previous published geochronological and petrological evidence in favour of a major 2.0 Ga event within the Limpopo Belt, these results suggest that the Zimbabwe and Kaapvaal cratons did not form a coherent unit (Kalahari) until ca. 2.0 Ga.     

Zirconium and hafnium in meteorites

Abstract– The ratio of the two refractory trace elements zirconium (Zr) and hafnium (Hf) in meteorites has been proposed to be uniform. The most precise value available is 34.3 ± 0.2 (1σ). It was obtained by isotope dilution ICP‐MS applied to 15 chondrites, most of which were carbonaceous chondrites, and six achondrites. We reinvestigated the case and determined Zr/Hf ratios of a broad spectrum of meteoritic samples via laser ablation ICP‐MS. Our sample suite comprised 29 chondrites and five achondrites. The main objective of the study was two‐fold: we intended to verify the accuracy and precision of a relatively fast and inexpensive sample preparation method combined with expeditious laser ablation ICP‐MS techniques. Furthermore, we were looking into the possibility of systematic fine‐scale Zr/Hf variations among bulk meteoritic matter of different classes. The applied fusion technique together with laser ablation ICP‐MS turned out to be well suited to determine relative refractory trace element abundances. Absolute Zr/Hf ratios yield uncertainties of approximately 4% (1σ). As opposed to the most recent findings, we observed variable Zr/Hf ratios in different meteorites ranging from approximately 28 to approximately 38. Our value for Orgueil (CI1) is 34.0 ± 0.3 (1σ). Including literature data, we propose a solar system value of 34.1 ± 0.3. Our data also suggest that H chondrites tend to exhibit higher Zr/Hf ratios (average of 35.6 ± 0.5 [1σ]) while EL6 chondrites rather show low values (average of 30.8 ± 0.6 [1σ]). In addition to examining Zr/Hf ratios, we also explored the content of refractory major elements in different meteorite groups. Here, we found that EL6 chondrites often show very low Ca/Al ratios. The CI1 value for CaO/Al₂O₃ is 0.804. EL6 chondrites, however, display ratios as low as approximately 0.3. While the variation in Zr/Hf can be explained by fractional condensation processes in the early solar nebula, the observed low Ca/Al ratios in EL6 chondrites are probably attributable to deficits in oldhamite (CaS).     

Magnetic field evolution in simulations with Euler potentials

Using two- and three-dimensional hydromagnetic simulations for a range of different flows, including laminar and turbulent ones, it is shown that solutions expressing the field in terms of Euler potentials (EP) are in general incorrect if the EP are evolved with an artificial diffusion term. In three dimensions, standard methods using the magnetic vector potential are found to permit dynamo action when the EP give decaying solutions. With an imposed field, the EP method yields excessive power at small scales. This effect is more exaggerated in the dynamic case, suggesting an unrealistically reduced feedback from the Lorentz force. The EP approach agrees with standard methods only at early times when magnetic diffusivity did not have time to act. It is demonstrated that the usage of EP with even a small artificial magnetic diffusivity does not converge to a proper solution of hydromagnetic turbulence. The source of this disagreement is not connected with magnetic helicity or the three-dimensionality of the magnetic field, but is simply due to the fact that the non-linear representation of the magnetic field in terms of EP that depend on the same coordinates is incompatible with the linear diffusion operator in the induction equation.     

Experimental evidence of fast groundwater responses in a hillslope/floodplain area in the Black Forest Mountains,Germany

Analysis of water flow pathways from hillslopes to streams is essential for the optimal protection of water resources as well as for ecohydrological studies. This study addresses runoff generation processes at a hillslope and near‐stream shallow groundwater system in the Black Forest Mountains, southwestern Germany. The changing spatial and temporal flow patterns during differing hydrological situations were examined using a combined hydraulic and hydrochemical approach. Groundwater levels at 10 wells, discharge at a near‐stream saturated area, and several natural tracers (deuterium, dissolved silica, and major anions and cations) were observed at different locations during high and low flows. The importance of the groundwater component during flood formation was clearly demonstrated: its contribution was about 80% during a double peak flood event at the saturated area. In addition, a rapid change of the shallow groundwater levels was observed along two transects of groundwater wells in the floodplain. This led to an enhanced groundwater discharge into the saturated area located at the end of one study transect. The amount of groundwater additionally activated during the event was about 30% of total discharge recorded at the outlet of the saturated area. Two alternative hypotheses are discussed to explain this phenomenon: the establishment of locally confined conditions and the development of a pressure wave (hypothesis A), or the significant change of the three‐dimensional groundwater flow lines that caused a large increase of the groundwater catchment at the saturated area during the investigated event (hypothesis B). Even if the exact flow paths and mechanisms could not be clearly identified, the importance of rapid responding hillslope groundwater was undoubtedly demonstrated by a combination of tracer and hydrometric methods. Copyright © 2004 John Wiley & Sons, Ltd.