Stable isotope study of base metal deposits from the Eastern High Atlas,Morocco

Tertiary epigenetic lead ± zinc and copper mineralizations occur in the Mesozoic carbonate cover and stibnite, barite and copper mineralization in the Precambrian to Palaezoic basement in the Eastern High Atlas, Morocco. The carbon isotope data from host carbonates range from +3 to -1‰ PDB. The data are typical for marine carbon. There is no difference between surrounding dolomites and younger vein dolomites. The oxygen isotopic composition of the samples is enriched in ¹⁶O; the range is from -3 to -11‰ PDB with respect to that of carbonates in equilibrium with marine water. It is postulated that the isotopic composition was changed during dolomitization being caused by transition of connate formation waters diluted to some degree by meteoritic water. The bacteriogenically reduced sulphur from syngenetic sulphides and Mesozoic marine sulphate mobilized during Tertiary orogenesis are thought to be the source of H₂S and SO₄. Cambro-Ordovicien sulphate is also supposed to be the source of sulphur in the Jebel Zelmou barite deposit in the basement. Isotopic composition of lead from galenas in the Tertiary deposits from the Mesozoic cover are strikingly homogenous. Model ages vary between 230–180 Ma. It is suggested that important mobilization processes are responsible for Tertiary metallogeny in Morocco.

     

Variability of long-period pulsating stars. II. Additional parameters for classifying stars

Results are presented from an analysis of observations in a sample of 53 long-period pulsating stars (44 of which are Mira-type and 9 are semiregular variables). A catalog of the characteristics of the individual pulsation cycles of the light curves is obtained for these stars. A correlation analysis of the characteristics of the individual pulsation cycles is carried out for each star. A number if diagrams relating the variability of the characteristics of the individual cycles to the average parameters of the variability of the stars and to their spectral classes. New criteria for classifying long-period variables are proposed on the basis of these diagrams. __________ Translated from Astrofizika, Vol. 49, No. 4, pp. 595–612 (November 2006).     

Mineralogy of the Ibitira eucrite and comparison with other eucrites and lunar samples

Ibitira meteorite is interpreted as a strongly metamorphosed, unbrecciated, vesicular eucrite with a primary variolitic and secondary hornfelsic texture dominated by 60% pyroxene (bulk composition En₃₇Fs₄₈Wo₁₅ exsolved into lamellae several micrometers wide of augite En₃₂Fs₂₇Wo₄₁ and pigeonite En₄₀Fs₅₆Wo₄) and 30% plagioclase An₉₄ (mosaic extinction and variable structural state). Minor phases are 5% tridymite plates one-quarter occupied by plagioclase (An₉₄) inclusions; several percent intergrowths of ilmenite and Ti-chromite with trace kamacite Fe₉₉Co_0.5Ni_0.2 and narrow olivine (Fa₈₃) rims; one grain of low-Ti-chromite enclosed in tridymite; trace troilite with kamacite Fe₉₈Co_1.0Ni_0.9. Euhedral ilmenite, Ti-chromite, plagioclase and merrillite in vesicles indicate vapor deposition. These properties can be explained by a series of processes including at least the following: (1) igneous crystallization under pressure low enough to allow vesiculation, (2) prolonged metamorphism, perhaps associated with vapor deposition and reduction, to produce the coarse exsolution of the pyroxene and the coarse ilmenite-chromite intergrowths, (3) strong shock which affected the plagioclase and tridymite but not the pyroxene, (4) sufficient annealing to allow recrystallization of the plagioclase and tridymite, and partial conversion to the low structural state of the former.     

Evaluation of the removal of heavy metals in a natural wetland impacted by mining activities in Mexico

This research is focused on evaluating heavy metals (Cd, Cu, Fe, Mn, Pb, and Zn) uptake and removal by Eleocharis ovata, Cyperus manimae, Typha dominguensis, and Pteridium aquilinum in a natural wetland impacted by mining activities. We analyzed heavy metals content and distribution in native plants, soils, and water of a semipermanent natural wetland in Taxco de Alarcón, Guerrero, and we also determined the physicochemical characteristics of the water. Translocation factor (TF) and bioconcentration factor (BCF) were evaluated. Results showed that physical and chemical conditions are favorable for plants development. Correlation analysis showed a good and positive relation (0.95) between Cu and Pb in soils and plants. In the analyzed matrices: Zn (0.62–2.20 mg/L) exceeded the permissible limits in water, high concentrations of Pb and Zn (26.57–525.67 and 266.67–983.33 mg/kg, respectively) were detected in the studied soils, and Pb exceeded the normal range for E. ovata and P. aquilinum in the analyzed plants. Uptake of heavy metals in the tissues of different species was found in the following order: root > leaf. Data of TF and BCF showed that E. ovata is a tolerant plant with respect to heavy metals exposure since TF value was greater than 1. This study showed that E. ovata could be considered as a bioaccumulator of heavy metals in contaminated soils.     

Influence of precipitation and deep saline groundwater on the hydrological systems of Mediterranean coastal plains: a general overview

Abstract

The increasing water demand is a concern affecting many regions in the Mediterranean Basin. To overcome this situation rim countries resorted during the last decades to a massive mobilization of their water resources, often resulting in excessive water exploitation. In such a context, understanding the effects of present recharge and aquifer salinization is crucial for correct water management. Understanding the present hydrogeological situation of coastal plains requires the knowledge of both their past morphologic conditions and their recent geological evolution. Within this framework, this paper presents a review of water related problems in the Mediterranean Basin. It suggests a conceptual model for groundwater resources in Mediterranean coastal plains, deriving from the present and past recharge processes. Special attention is paid to providing a better understanding of climate change impacts on water quantity and quality, and conservation of ecological diversity.

Citation Re, V. & Zuppi, G. M. (2011) Influence of precipitation and deep saline groundwater on the hydrological systems of Mediterranean coastal plains: a general overview. Hydrol. Sci. J. 56(6), 966–980.     

Convection in the polar cap after the interplanetary magnetic field becomes northward

As shown by Iwasaki (1971); Maezawa (1976); Kuznetsov and Troshichev (1977) and other investigators, the electric field and the plasma convection in the polar cap change their direction after an appearance of a significant northward component of the interplanetary magnetic field. Two possible mechanisms of this phenomenon may be suggested: (i) the direct penetration of the dusk-to-dawn electric field from the solar wind into the magnetosphere, and (ii) the generation of the observed electric field and convection in a process of the decay of the three-dimensional current system which existed before the appearance of the northward interplanetary field. The latter mechanism implies that the value of the electric field generated in the polar cap will decrease with time after the appearance of the northward interplanetary magnetic field. The results of the experimental investigation show such a decrease which favours the second mechanism.     

Earthworm-based automatic system for real-time calculation of local earthquake source parameters

Experience in introduction of an automatic system of earthquake source parameter calculation based on an existing seismic network is described. Open source software products for automatic seismic data processing are reviewed. Methods for real-time waveform stream processing are discussed in detail. Parameters of some subroutines of the system are described. Information flows and data life cycle in the developed automatic system are outlined. Earthquake location errors in the system are analyzed. The detection capability of seismic networks is evaluated.     

Geochronological constraints on the evolution of the Embu Complex, São Paulo, Brazil

Petrologic and geochronological work was carried out on a roadside outcrop of amphibolite facies orthogneisses near São Lourenço da Serra, about 50 km southwest of São Paulo City. These orthogneisses belong to the Embu Complex, within the Neoproterozoic Brasiliano Orogenic Cycle mobile belts of SE Brazil. The outcrop consists of predominantly foliated biotite tonalites and granodiorites, which were cut by granitic veins and pegmatites prior to final deformation. SHRIMP U/Pb measurements on zircons from one granodioritic–tonalitic gneiss indicate magmatic crystallization of the protolith at 811±13 Ma (MSWD=1.0). Zircons with dates of ca. 2000 and ca. 1000 Ma in this rock are interpreted as inherited from older crust. One zircon analyzed from the gneiss and three zircons from a discordant pegmatitic vein indicate an event at 650–700 Ma, perhaps related to the intrusion of the pegmatites. A regression of Rb–Sr whole rock data for four biotite gneisses yielded an imperfect isochron, giving an apparent age of 821±68 Ma and an elevated initial ⁸⁷Sr/⁸⁶Sr ratio of 0.719±0.005. The elevated initial ⁸⁷Sr/⁸⁶Sr ratio and the inherited zircons indicate involvement of older crust in the genesis of the gneisses. Rb–Sr feldspar and whole rock pairs yield ca. 560 Ma tielines, giving the time of final cooling below 300–350 °C, and the cessation of medium-grade metamorphism and ductile deformation. These results document a series of tectono-thermal events spanning 250 million years during the Brasiliano Orogenic Cycle. They relate to ca. 800 Ma magmatic arc activity and later allochthonous terrane assembly during closure of the Adamastor Ocean, resulting in the accretion of Western Gondwana.