Solar Eclipses and the Surface Properties of Water

Earth, Moon, and Planets - During four solar eclipse events (two annular, one total and one partial) a correlation was observed between a change in water surface tension and the magnitude of the...     

Implications of land use change on the national terrestrial carbon budget of Georgia

Background  

Globally, the loss of forests now contributes almost 20% of carbon dioxide emissions to the atmosphere. There is an immediate need to reduce the current rates of forest loss, and the associated release of carbon dioxide, but for many areas of the world these rates are largely unknown. The Soviet Union contained a substantial part of the world's forests and the fate of those forests and their effect on carbon dynamics remain unknown for many areas of the former Eastern Bloc. For Georgia, the political and economic transitions following independence in 1991 have been dramatic. In this paper we quantify rates of land use changes and their effect on the terrestrial carbon budget for Georgia. A carbon book-keeping model traces changes in carbon stocks using historical and current rates of land use change. Landsat satellite images acquired circa 1990 and 2000 were analyzed to detect changes in forest cover since 1990.     

Patterns of development in tourist accommodation enterprises on farms in England and Wales

The spatial distribution of UK farm-based tourist accommodation is not known in detail, although this type of facility has been an important element in the growth of rural tourism and the most common option for farm diversification. A database of farms in England and Wales offering tourist accommodation has been prepared and the individual entries georeferenced to enable their locations to be determined with respect to selected Scenic Areas (Areas of Outstanding Natural Beauty, Heritage Coasts and National Parks). Exploratory analysis of this database indicates a possible ‘neighbourhood effect’ in which the provision of farm-based accommodation within buffer zones immediately surrounding these designated areas has a higher level of penetration in the farming community than in more distant areas. Further research is outlined to examine the interaction between actors in farming and planning communities using the geographical framework presented here.     

Relative contributions of silicate and carbonate rocks to riverine Sr fluxes in the headwaters of the Ganges

Exhumation of the Himalayan-Tibetan orogen is implicated in the marked rise in seawater ⁸⁷Sr/⁸⁶Sr ratios since 40 Ma. However both silicate and carbonate rocks in the Himalaya have elevated ⁸⁷Sr/⁸⁶Sr ratios and there is disagreement as to how much of the ⁸⁷Sr flux is derived from silicate weathering. Most previous studies have used element ratios from bedrock to constrain the proportions of silicate- and carbonate-derived Sr in river waters. Here we use arrays of water compositions sampled from the head waters of the Ganges in the Indian and Nepalese Himalaya to constrain the end-member element ratios. The compositions of tributaries draining catchments restricted to a limited range of geological units can be described by two-component mixing of silicate and carbonate-derived components and lie on a plane in multicomponent composition space. Key elemental ratios of the carbonate and silicate components are determined by the intersection of the tributary mixing plane with the planes Na = 0 for carbonate and constant Ca/Na for silicate. The fractions of Sr derived from silicate and carbonate sources are then calculated by mass-balance in Sr-Ca-Mg-Na composition space. Comparison of end-member compositions with bedrock implies that secondary calcite deposition may be important in some catchments and that dissolution of low-Mg trace calcite in silicate rocks may explain discrepancies in Sr-Ca-Na-Mg covariation. Alternatively, composition-dependent precipitation or incongruent dissolution reactions may rotate mixing trends on cation-ratio diagrams. However the calculations are not sensitive to transformations of the compositions by incongruent dissolution or precipitation processes provided that the transformed silicate and carbonate component vectors are constrained. Silicates are calculated to provide ∼50% of the dissolved Sr flux from the head waters of the Ganges assuming that discrepancies between Ca-Mg-Na covariation and the silicate rock compositions arise from addition of trace calcite. If the Ca-Mg-Na mixing plane is rotated by composition-dependent secondary calcite deposition, this estimate would be increased. Moreover, when ⁸⁷Sr/⁸⁶Sr ratios of the Sr inputs are considered, silicate Sr is responsible for 70 ± 16% (1σ) of the ⁸⁷Sr flux forcing changes in seawater Sr-isotopic composition. Since earlier studies predict that silicate weathering generates as little as 20% of the total Sr flux in Himalayan river systems, this study demonstrates that the significance of silicate weathering can be greatly underestimated if the processes that decouple the water cation ratios from those of the source rocks are not properly evaluated.     

Trace and minor elements in sphalerite: A LA-ICPMS study

Sphalerite is an important host mineral for a wide range of minor and trace elements. We have used laser-ablation inductively coupled mass spectroscopy (LA-ICPMS) techniques to investigate the distribution of Ag, As, Bi, Cd, Co, Cu, Fe, Ga, Ge, In, Mn, Mo, Ni, Pb, Sb, Se, Sn and Tl in samples from 26 ore deposits, including specimens with wt.% levels of Mn, Cd, In, Sn and Hg. This technique provides accurate trace element data, confirming that Cd, Co, Ga, Ge, In, Mn, Sn, As and Tl are present in solid solution. The concentrations of most elements vary over several orders of magnitude between deposits and in some cases between single samples from a given deposit. Sphalerite is characterized by a specific range of Cd (typically 0.2-1.0 wt.%) in each deposit. Higher Cd concentrations are rare; spot analyses on samples from skarn at Baisoara (Romania) show up to 13.2 wt.% (Cd²⁺ ↔ Zn²⁺ substitution). The LA-ICPMS technique also allows for identification of other elements, notably Pb, Sb and Bi, mostly as micro-inclusions of minerals carrying those elements, and not as solid solution. Silver may occur both as solid solution and as micro-inclusions. Sphalerite can also incorporate minor amounts of As and Se, and possibly Au (e.g., Magura epithermal Au, Romania). Manganese enrichment (up to ∼4 wt.%) does not appear to enhance incorporation of other elements. Sphalerite from Toyoha (Japan) features superimposed zoning. Indium-sphalerite (up to 6.7 wt.% In) coexists with Sn-sphalerite (up to 2.3 wt.%). Indium concentration correlates with Cu, corroborating coupled (Cu⁺In³⁺) ↔ 2Zn²⁺ substitution. Tin, however, correlates with Ag, suggesting (2Ag⁺Sn⁴⁺) ↔ 3Zn²⁺ coupled substitution. Germanium-bearing sphalerite from Tres Marias (Mexico) contains several hundred ppm Ge, correlating with Fe. We see no evidence of coupled substitution for incorporation of Ge. Accordingly, we postulate that Ge may be present as Ge²⁺ rather than Ge⁴⁺. Trace element concentrations in different deposit types vary because fractionation of a given element into sphalerite is influenced by crystallization temperature, metal source and the amount of sphalerite in the ore. Epithermal and some skarn deposits have higher concentrations of most elements in solid solution. The presence of discrete minerals containing In, Ga, Ge, etc. also contribute to the observed variance in measured concentrations within sphalerite.     

Syn‐sedimentary salt diapirism as a control on fluvial‐system evolution: an example from the proximal Permian Cutler Group,SE Utah,USA

Loading of subsurface salt during accumulation of fluvial strata can result in halokinesis and the growth of salt pillows, walls and diapirs. Such movement may eventually result in the formation of salt‐walled mini‐basins, whose style of architectural infill may be used to infer both the relative rates of salt‐wall growth and sedimentation and the nature of the fluvial‐system response to salt movement. The Salt Anticline Region of the Paradox Basin of SE Utah comprises a series of elongate salt‐walled mini‐basins, arranged in a NW‐trending array. The bulk of salt movement occurred during deposition of the Permian Cutler Group, a wedge of predominantly quartzo‐feldspathic clastic strata comprising sediment derived from the Uncompahgre Uplift to the NE. The sedimentary architecture of selected mini‐basin fills has been determined at high resolution through outcrop study. Mini‐basin centres are characterized by multi‐storey fluvial channel elements arranged into stacked channel complexes, with only limited preservation of overbank elements. At mini‐basin margins, thick successions of fluvial overbank and sheet‐like elements dominate in rim‐syncline depocentres adjacent to salt walls; many such accumulations are unconformably overlain by single‐storey fluvial channel elements that accumulated during episodes of salt‐wall breaching. The absence of gypsum clasts suggests that sediment influx was high, preventing syn‐sedimentary surface exposure of salt. Instead, fluvial breaching of salt‐generated topography reworked previously deposited sediments of the Cutler Group atop growing salt walls. Palaeocurrent data indicate that fluvial palaeoflow to the SW early in the history of basin infill was subsequently diverted to the W and ultimately to the NW as the salt walls grew to form topographic barriers. Late‐stage retreat of the Cutler fluvial system coincided with construction and accumulation of an aeolian system, recording a period of heightened climatic aridity. Aeolian sediments are preserved in the lees of some salt walls, demonstrating that halokinesis played a complex role in the differential trapping of sediment.     

A quantitative approach to fluvial facies models: Methods and example results

Traditional facies models lack quantitative information concerning sedimentological features: this significantly limits their value as references for comparison and guides to interpretation and subsurface prediction. This paper aims to demonstrate how a database methodology can be used to generate quantitative facies models for fluvial depositional systems. This approach is employed to generate a range of models, comprising sets of quantitative information on proportions, geometries, spatial relations and grain sizes of genetic units belonging to three different scales of observation (depositional elements, architectural elements and facies units). The method involves a sequential application of filters to the knowledge base that allows only database case studies that developed under appropriate boundary conditions to contribute to any particular model. Specific example facies models are presented for fluvial environmental types categorized on channel pattern, basin climatic regime and water‐discharge regime; the common adoption of these environmental types allows a straightforward comparison with existing qualitative models. The models presented here relate to: (i) the large‐scale architecture of single‐thread and braided river systems; (ii) meandering sub‐humid perennial systems; (iii) the intermediate‐scale and small‐scale architecture of dryland, braided ephemeral systems; (iv) the small‐scale architecture of sandy meandering systems; and (v) individual architectural features of a specific sedimentary environment (a terminal fluvial system) and its sub‐environments (architectural elements). Although the quantification of architectural properties represents the main advantage over qualitative facies models, other improvements include the capacity: (i) to model on different scales of interest; (ii) to categorize the model on a variety of environmental classes; (iii) to perform an objective synthesis of many real‐world case studies; (iv) to include variability‐related and knowledge‐related uncertainty in the model; and (v) to assess the role of preservation potential by comparing ancient‐system and modern‐system data input to the model.     

40Ar-39Ar and Rb-Sr geochronology of high-pressure metamorphism and exhumation history of the Tavsanli Zone, NW Turkey

Geochronological investigations in high- and ultra-high-pressure metamorphic rocks are problematic since firstly the low temperatures lead to fine grain size and disequilibrium assemblages, and secondly the problem of “excess argon” affects ⁴⁰Ar-³⁹Ar systematics, the most commonly used isotopic system. The Tavsanli Zone is a belt of high-pressure low-temperature (HP-LT) rocks spanning NW Turkey and is one such region where previous geochronological studies have produced a range of estimates for the age of HP-LT metamorphism, raising the question of whether they are geologically significant. This study presents new data from the Tavsanli Zone; ⁴⁰Ar-³⁹Ar ages are in the range 60 Ma to 175 Ma, whilst Rb-Sr ages are restricted to 79.7 Ma to 82.8 Ma, confirming the presence of excess argon. Detailed ultra-violet laser ablation microprobe (UVLAMP) studies have revealed younger ⁴⁰Ar-³⁹Ar ages in the cores of coarser white micas, which in conjunction with ⁴⁰Ar-³⁹Ar ages from the finest grained lithologies and the Rb-Sr white mica crystallisation ages, constrain the post-HP-LT metamorphism exhumation rates of these rocks. Petrological and regional constraints suggest that syn-subduction exhumation and cooling took place initially by synchronous subduction and exhumation by underplating. This is followed by a phase of syn-continent-continent collision at a rate of approximately 1.5 mma⁻¹ and exhumation to the surface via thrusting. The ⁴⁰Ar-³⁹Ar hornblende data from a granodiorite intruding the HP-LT rocks constrain the later parts of exhumation path. This study highlights the importance of a multi-system geochronological approach when attempting to determine the history of HP-LT rocks. Received: 12 May 1998 / Accepted: 21 April 1999     

Paleogene crustal anatexis and metamorphism in Lhasa terrane, eastern Himalayan syntaxis: Evidence from U-Pb zircon ages and Hf isotopic compositions of the Nyingchi Complex

In the eastern Himalayan syntaxis, the southern Lhasa terrane is dominated by middle- to high-grade metamorphic rocks (Nyingchi Complex), which are intruded by felsic melts. U-Pb zircon dating and zircon Hf isotopic composition of these metamorphic and magmatic rocks provide important constraints on the tectono-thermal evolution of the Lhasa terrane during convergent process between Indian and Asian continents. U-Pb zircon data for an orthogneiss intruding the Nyingchi Complex yield a protolith magma crystallization age of 83.4 ± 1.2 Ma, with metamorphic ages of 65-46 Ma. This orthogneiss is characterized by positive ε_Hf (t) values of + 8.3 and young Hf model ages of ~ 0.6 Ga, indicating a derivation primarily from a depleted-mantle or juvenile crustal source. Zircons from a quartz diorite yield a magma crystallization age of 63.1 ± 0.6 Ma, with ε_Hf (t) values of − 8.2 to − 2.7, suggesting that this magma was sourced from partial melting of older crustal materials. Zircon cores from a foliated biotite granite show ages ranging from 347 to 2690 Ma, with age peaks at 347-403 Ma, 461-648 Ma and 1013-1183 Ma; their zircon ε_Hf (t) values range from − 30.6 to + 6.9. Both the U-Pb ages and Hf isotopic composition of the zircon cores are similar to those of detrital zircons from the Nyingchi Complex paragneiss, implying that the granite was derived from anatexis of the Nyingchi Complex metasediments. The zircon rims from the granite indicate crustal anatexis at 64.4 ± 0.7 Ma and subsequent metamorphism at 55.1 ± 1.3 and 41.4 ± 2.3 Ma. Our results suggest that the late Cretaceous magmatism in the southern Lhasa terrane resulted from Neo-Tethys oceanic slab subduction and we infer that Paleocene crustal anatexis and metamorphism were related to the thermal perturbation caused by rollback of the northward subducted Neo-Tethyan oceanic slab.     

A CORINE map of Great Britain by automated means. Techniques for automatic generalization of the Land Cover Map of Great Britain.

Abstract

The European Commission (EC) programme ‘Co–ordination of Information on the Environment’ (CORINE) includes a project to map the land cover of member states. The CORINE map is essentially one which combines land cover and land use, giving 44 separate classes, in vector, displayed at a scale of 1:100000 with a minimum mappable unit of 25 ha. The Institute of Terrestrial Ecology (ITE) has compiled a digital land cover map of Great Britain (LCMGB) from classification of Landsat–TM data, resampled to a 25 m raster, with a minimum mappable unit of 0.125 ha and 25 cover types. This paper describes a pilot study which demonstrates the successful spatial generalisation with contextual interpretation to convert the LCMGB to CORINE specifications using semi–automated techniques within a GIS environment.