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651.
Julian A. Lockington Nigel J. Cook Cristiana L. Ciobanu 《Mineralogy and Petrology》2014,108(6):873-890
Sphalerite is a common sulphide and is the dominant ore mineral in Zn-Pb sulphide deposits. Precise determination of minor and trace element concentrations in sulphides, including sphalerite, by Laser-Ablation Inductively-Coupled-Plasma Mass-Spectrometry (LA-ICP-MS) is a potentially valuable petrogenetic tool. In this study, LA-ICP-MS is used to analyse 19 sphalerite samples from metamorphosed, sphalerite-bearing volcanic-associated and sedimentary exhalative massive sulphide deposits in Norway and Australia. The distributions of Mn, Fe, Co, Cu, Ga, Se, Ag, Cd, In, Sn, Sb, Hg, Tl, Pb and Bi are addressed with emphasis on how concentrations of these elements vary with metamorphic grade of the deposit and the extent of sulphide recrystallization. Results show that the concentrations of a group of trace elements which are believed to be present in sphalerite as micro- to nano-scale inclusions (Pb, Bi, and to some degree Cu and Ag) diminish with increasing metamorphic grade. This is interpreted as due to release of these elements during sphalerite recrystallization and subsequent remobilization to form discrete minerals elsewhere. The concentrations of lattice-bound elements (Mn, Fe, Cd, In and Hg) show no correlation with metamorphic grade. Primary metal sources, physico-chemical conditions during initial deposition, and element partitioning between sphalerite and co-existing sulphides are dominant in defining the concentrations of these elements and they appear to be readily re-incorporated into recrystallized sphalerite, offering potential insights into ore genesis. Given that sphalerite accommodates a variety of trace elements that can be precisely determined by contemporary microanalytical techniques, the mineral has considerable potential as a geothermometer, providing that element partitioning between sphalerite and coexisting minerals (galena, chalcopyrite etc.) can be quantified in samples for which the crystallization temperature can be independently constrained. 相似文献
652.
Sarah K. Appleby Martin R. Gillespie Colin M. Graham Richard W. Hinton Grahame J. H. Oliver Nigel M. Kelly 《Contributions to Mineralogy and Petrology》2010,160(1):115-132
In contrast to I-type granites, which commonly comprise infracrustal and supracrustal sources, S-type granites typically incorporate
predominantly supracrustal sources. The initial aim of this study was to identify the sources of three Scottish Caledonian
(~460 Ma) S-type granites (Kemnay, Cove and Nigg Bay) by conducting oxygen, U–Pb and Hf isotope analyses in zircon in order
to characterise one potential end-member magma involved in the genesis of the voluminous late Caledonian (~430–400 Ma) I-type
granites. Field, whole-rock geochemical and isotopic data are consistent with the generation of the S-type granites by melting
their Dalradian Supergroup country rocks. While Hf isotope compositions of magmatic zircon, U–Pb data of inherited zircons,
and high mean zircon δ18O values of 9.0 ± 2.7‰ (2SD) and 9.8 ± 2.0‰ for the Kemnay and Cove granites support this model, the Nigg Bay Granite contains
zircons with much lower δ18O values (6.8 ± 2.1‰), similar to those found in Scottish I-type granites. This suggests that the Nigg Bay Granite contains
low-δ18O material representing either altered supracrustal material, or more likely, an infracrustal source component with mantle-like
δ18O. Mixing trends in plots of δ18O vs. εHf for S-type granite zircons indicate involvement of at least two sources in all three granites. This pilot study
of Scottish Caledonian S-type granites demonstrates that, while field and whole-rock geochemical data are consistent with
local melting of only supracrustal sources, the oxygen isotopic record stored in zircon reveals a much more complex petrogenetic
evolution involving two or more magma sources. 相似文献
653.
An archaeological geophysics investigation was conducted at the site of the Wright Brothers' 1910 hangar near Dayton, Ohio. The hangar was destroyed as part of base renovation during the buildup to World War II, and its exact location is unknown. The purpose of the investigation is to confirm the exact location of the hangar and to locate any buried artifacts from the Wright Brothers occupation of the site. Ground penetrating radar (GPR), electromagnetic, and magnetic surveys were conducted over a 68 × 100 m area, approximately centered on the suspected location of the hangar. Localized anomalies as well as areal anomalies are identified in the geophysical data. Rectangular anomalous areas are identified that are generally consistent with the suspected location of the hangar. A 1924 aerial photograph showing the hangar was digitally scanned and georeferenced to the site survey area. Two of the rectangular geophysical anomalous areas are consistent with the hangar location from the aerial photograph location. A third rectangular area, defined from GPR survey data, is immediately adjacent to the aerial photograph location. It is postulated that base engineers may have bulldozed the hangar debris onto an area adjacent to its original location and either burned it there or buried it in a trench. A prioritized exploratory program is proposed for investigating the sources of the geophysical anomalies. © 1994 John Wiley & Sons, Inc. 相似文献
654.
Ian A. Simpson Sophia Perdikaris Gordon Cook John L. Campbell William J. Teesdale 《Geoarchaeology》2000,15(8):743-763
The development of specialized and commercial fishing activity in the island archipelago of Lofoten and Vesterålen in northern Norway is a critical foundation from which to understand the subsequent spread of commercial fishing across the north Atlantic region during the medieval and early modern period. One little understood aspect of this development is the relationship between medieval commercial fishing stations (fiskevaer) and earlier fishing activity. In this article, cultural sediment deposits at Langenesværet, Vesterålen, Northern Norway provide an opportunity to examine this relationship and its implications for current historical models of fishing development in northern Norway and the north Atlantic region. Conventional and AMS radiocarbon dating techniques are used to establish a chronology for the deposits, while activities associated with the sediments are characterized using thin‐section micromorphology supported by proton induced X‐ray emission spectrometry (PIXE). The results suggest that the site commenced formation as early as ca. 3000 B.C. and that the site was first used for specialized fishing activity from the early centuries A.D. The medieval commercial fiskevaer settlement at Langenesværet was introduced to an area that had a longstanding tradition of specialised fishing activity. © 2000 John Wiley & Sons, Inc. 相似文献