Palaeomagnetism of middle Proterozoic (c. 1.25 Ga) dykes from central North Greenland

From a nunatak in central North Greenland (81.5°N, 44.7°W) nine sites of Middle Proterozoic basic dykes, cutting Archaean basement, were palaeomagnetically investigated. After AF and thermal cleaning the nine dyke sites and three adjacently baked gneiss sites give a stable characteristic remanent mean direction of D = 265°, I = 21.5° ( N = 12, α ₉₅= 5.6°), the direction being confirmed by a detailed and positive baked contact test.
The polarity of the dykes in the nunatak area is opposite to that of the Zig-Zag Dal Basalts and the Midsommersø Dolerites in eastern North Greenland some 200–300 km away, the volcanics of which are assumed to be of similar age (about 1.25 Ga). The remanent directions of the two sets of data are antiparallel within the 95 per cent significance level of confidence.
When rotating Greenland 18° clockwise back to North America by the 'Bullard fit', the pole of the central North Greenland dolerites (NDL) falls at (14.3°N, 144.3°W). The reversed pole (14.3°S, 35.7°E) fits well on to the loop between 1.2 and 1.4 Ma on the apparent polar wander swath of Berger & York for cratonic North America.
The palaeomagnetic results from the Middle Proterozoic basic dykes from central North Greenland thus strengthen previous palaeomagnetic results from the Midsommersø Dolerites and Zig-Zag Dal Basalts from the Peary Land Region in eastern North Greenland, suggesting that Greenland was part of the North American craton at least for the period between c . 1.3 and 1 Ma (and probably up to the end of Cretaceous time). The major geographical meridian of Greenland was orientated approximately E–W, and the palaeo-latitude of Greenland was about 10°–15°.     

A study of focusing telescopes for soft gamma rays

A study is presented on the feasibility of using Bragg diffraction from crystals to focus soft gamma-rays in the energy range up to 2 MeV. For astrophysics this band contains several very interesting gamma-ray lines from novae, supernovae and X- and gamma-ray transients.The study concludes that, in the energy range between 300 and 1300 keV, a Bragg-telescope with a focal length of about 50 meters could achieve a sensitivity for point sources which is between 5 and 10 times better than that currently expected for the ESA/NASA INTEGRAL-mission/1/. In addition, the angular resolution of the Bragg telescope would also be an order of magnitude better. Despite the large physical dimensions of the telescope, its feasibility does not seem out of reach. The requirements do not go appreciably beyond those of other scientific projects which have been studied and found technically feasible by ESA and NASA /2, 3/. The Bragg-telescope therefore may become the logical next step in soft gamma-ray astronomy following a sensitive survey project like INTEGRAL.     

Characterization of the reactivity of riverine heterogeneous sediments using a facies-based approach; the Rhine–Meuse delta (The Netherlands)

Large groundwater resources are found in densely populated lowland areas, which consist often of young unconsolidated and reduced sediments. When anthropogenic activities lead to oxygenation of the aquifer, breakdown of the main reduced fractions, i.e. sedimentary organic matter (SOM) and pyrite, could lead to severe groundwater deterioration such as acidification, heavy metal mobilization, and increased hardness. The characterization of the reactive properties of these sediments is important in predicting groundwater deterioration, but is often complicated by the high degree of heterogeneity of these sediments. In this study, the potential reduction capacity (PRC, based on SOM and pyrite content), the potential buffer capacity (PBC, based on carbonate content), potential acidification capacity (PAC, based on the potential acid production by sulfide oxidation), and the measured reduction capacity (MRC) of five facies, which are typical of the riverine sediments in the Rhine–Meuse delta (The Netherlands) were determined. A universal facies-classification model was used to classify the deposits into more homogeneous sub-units based on lithologic and geogenic properties, with a further sub-division into oxic or anoxic redox environment based upon groundwater data and field observations. The bulk chemical data show strong variation across facies for the median values of PRC (186–9093 mmol O₂ kg⁻¹), PBC (17–132 mmol O₂ kg⁻¹), and PAC (36–1530 mmol H⁺ kg⁻¹). The MRC was measured as reactivity to molecular O₂ exposure and was 0.5–567.3 mmol O₂ kg⁻¹. Steady-state oxidation rates were in the wide range of 0.001–10.355 mmol O₂ kg⁻¹ day⁻¹ but were typically about 3–8 times faster in fine facies than in coarse facies. Both the PRC and MRC depend strongly on grain size, but also on the syn/post-depositional environment and redox conditions. The main part of the PRC consists of SOM, but pyrite reactivity is higher than SOM reactivity as shown by the relative depletion of pyrite in oxic subfacies and the preferential oxidation during the oxidation experiments. Some facies are very prone to acidification because the PAC is higher than the PBC, but the oxidation experiments also show that acidification could already start before the PRC is fully exhausted. This study, is one of the few that combines bulk chemical data, groundwater data, and reactivity measurements and shows that a facies-based approach is a practical tool in characterizing the reactivity of heterogeneous deposits.     

Determination Of The Surface Drag Coefficient

This study examines the dependence of the surface drag coefficienton stability, wind speed, mesoscale modulation of the turbulent flux and method of calculation of the drag coefficient. Data sets over grassland, sparse grass, heather and two forest sites are analyzed. For significantly unstable conditions, the drag coefficient does not depend systematically on z/L but decreases with wind speed for fixed intervals of z/L, where L is the Obukhov length. Even though the drag coefficient for weak wind conditions is sensitive to the exact method of calculation and choice of averaging time, the decrease of the drag coefficient with wind speed occurs for all of the calculation methods. A classification of flux calculation methods is constructed, which unifies the most common previous approaches.The roughness length corresponding to the usual Monin–Obukhovstability functions decreases with increasing wind speed. This dependence on wind speed cannot be eliminated by adjusting the stability functions. If physical, the decrease of the roughness length with increasing wind speed might be due to the decreasing role of viscous effectsand streamlining of the vegetation, although these effects cannot be isolated from existing atmospheric data.For weak winds, both the mean flow and the stress vector often meander significantly in response to mesoscale motions. The relationship between meandering of the stress and wind vectors is examined. For weak winds, the drag coefficient can be sensitive to the method of calculation, partly due to meandering of the stress vector.     

Pulled array continuous electrical sounding with an additional inductive source: an experimental design study

Electrical and electromagnetic profiling methods are used extensively in environmental geophysical investigations for many different purposes. The pulled array continuous electrical sounding (PACES) method, where a tail of electrodes is towed behind a small vehicle while continuously and simultaneously measuring several electrode configurations, has been used extensively for mapping the vulnerability of aquifers in Denmark. Measurements are taken every 1 m, and 10–15 km of profile can be achieved in one day.
This paper presents a theoretical study of the resolution capabilities of PACES measurements as they are now performed, and an experimental design study for including an inductive source in the measuring equipment. The joint interpretation of the galvanic data set of ordinary PACES measurements with inductive data from a horizontal magnetic dipole source will enhance the resolution capabilities of the data set significantly. The study is carried out as an analysis of the uncertainty of the model parameters of one-dimensional three-layer models using the estimation error variances of the inversion problem.
The results indicate that the addition of only two frequency data from a magnetic dipole source will substantially improve the resolution of the subsurface resistivity structure. The improvement is model dependent, but reduction in the relative error of model parameters by an order of magnitude is observed.     

Thellier palaeointensity experiments on Faroes flood basalts: technical aspects and geomagnetic implications

Based on palaeomagnetic and rock magnetic results, 108 samples from 27 flows from Palaeogene flood basalts of Faroe Islands were chosen for whole-rock Thellier palaeointensity experiments. Altogether 90 samples were rejected due to either chemical alterations or typical multidomain (MD) behaviour evidenced by pTRM-tails. AF pre-treatment was used to reduce the effect of MD grains on Thellier experiments. Only five flows (18 samples) yielded acceptable palaeointensity estimates, with flow mean VDMs ranging from 3.5 to 7.4×10²² A m². Modest selection criteria imposed on all published 5-160 Ma palaeointensity data left only 15 palaeomagnetic dipole moments: eight from whole-rock samples, six from submarine basaltic glass and one from single plagioclase crystals. More data are needed before the intriguing differences between results from different materials can be put into a geomagnetic context.     

Reactions of Cl Atoms with Selected VOCs: Kinetics, Products and Mechanisms

The reactions of isoprene, MBO (2-methyl-3-buten-2-ol) and toluene with chlorine atoms have been studied at 298 ± 5 K and 740 ± 5 Torr with the use of FTIR spectroscopy. Major products of the isoprene-Cl reaction and of the MBO-Cl reaction have been identified and quantified, and reaction mechanisms have been tentatively proposed in order to explain the products formed. The reaction between isoprene and Cl atoms yields mainly HCl, formyl chloride, formic acid, methylglyoxal (pyruvic aldehyde), CO and CO2, while the MBO-Cl reaction forms acetone, HCl, formyl chloride, formic acid, CO, CO2. As products from the reaction between toluene and Cl we identified and quantified HCl and benzaldehyde. The rate constants for the reactions of isoprene and toluene with Cl atoms have also been determined using a relative rate method. The measured values are: kisoprene = (5.5 ± 1.0) × 10–10 cm3 molecule–1 s–1 and ktoluene = (5.6 ± 1.3) × 10–11 cm3 molecule–1 s–1. Atmospheric lifetimes have been estimated from these values.     

Diffusive and total oxygen uptake of deep-sea sediments in the eastern South Atlantic Ocean:in situ and laboratory measurements

Total O₂ uptake rates were measured by the benthic flux chamber lander ELINOR, and O₂ microprofiles were measured by the profiling lander PROFILUR in the eastern South Atlantic. Diffusive O₂ fluxes through the diffusive boundary layer and the depth distribution of O₂ consumption rates within the sediment were calculated from the obtained microprofiles. The depth integrated O₂ consumption rate agreed closely with the diffusive O₂ uptake at all stations. Total O₂ uptake was 1.2–4.2 times the diffusive O₂ uptake, and the difference correlated with the abundance of macrofauna in the sediment. Diffusive O₂ uptake and O₂-penetration depths correlated with the organic content of the sediments and exhibited an inverse correlation with water depth. Total and diffusive rates of in situ O₂ uptake were higher than previously published data for shelf and abyssal sediments in the Atlantic, but were comparable to rates from upwelling areas in the eastern Pacific. Laboratory measurements on recovered sediment cores showed lower O₂ penetration depths and higher diffusive uptake rates than in situ measurements. The differences increased with increasing water depth. We primarily ascribe this compression of O₂ profiles to a transiently increased temperature during recovery and enhanced microbial activity in decompressed sediment cores. Total O₂ uptake rates measured in the laboratory on macrofauna-rich stations were, in contrast, lower than those measured in situ because of underrepresentation and disturbance of the macrofauna.     

The Importance of Posidonia oceanica and Cymodocea nodosa as Contributors of Free Amino Acids in Water and Sediment of Seagrass Beds

Abstract. Dissolved free amino acids (DFAA) were measured in sediment porewater and overlying sea water in seagrass beds of Posidonia oceanica and Cymodocea nodosa at a water depth of 8–10 m in Corsica, France. In the sea water, DFAA concentrations from 0.5 to 1.9μM were found. Lowest concentrations occurred in the afternoon in surface water samples, while higher concentrations were measured in morning surface samples and in all bottom samples. The most abundant amino acids were serine, glycine, and alanine. In the sediment, the upper 4cm contained the highest concentrations of DFAA (177nmol cm^-3 or 367 μM), while lower concentrations (<50nmol cm^-3 or 104 μM) prevailed deeper in the sediment. Glycine, glutamic acid, alanine, and β-alanine were the major components of the DFAA. The photosynthetic activity of the seagrasses influenced sediment porewater pools of DFAA. When a Posidonia bed was covered with a black polyethylene shield, the interstitial amino acids were reduced at a rate of 16nmol cm^-2 h^-1 (0-10cm depth). Conversely, extended daylight (floodlight) increased the DFAA pool in sediment depths below 4 cm. Free amino acids were released to the overlying sea water from both seagrass sediment and individual shoots, the rates being highest in the dark. The present investigation indicates that a substantial portion of the N-cycling of the seagrass sediment includes free amino acids.