尼日尔Termit盆地上白垩统成藏条件分析与勘探策略

尼日尔Termit盆地纵向上主要发育白垩系和古近系两套大的成藏组合,其中上组合古近系Sokor组为主力成藏组合,下组合白垩系为潜在成藏组合。盆地整体从下到上发育了下白垩统陆相-上白垩统海相-古近系陆相沉积旋回,发育了特殊的海侵层序。随着Termit盆地古近系主力成藏组合的勘探程度越来越高,亟待开辟新的勘探领域。基于研究和勘探实践,对Termit盆地下组合(白垩系)勘探新层系进行了探索。下组合白垩系又可以细分为K1、Donga组和Yogou组上段(YS3段)3个成藏组合,通过构造建模、沉积体系研究和油气成藏条件分析,认为YS3段具有较好的成藏条件,是下步勘探的重点领域。YS3段形成于海平面高频震荡下行时期,总体为海陆过渡相,三角洲体系发育,以砂泥互层沉积为主;其中发育的泥岩为该盆地主力烃源岩且大面积成熟,生烃潜力大,同时又是非常好的局部盖层;三角洲相石英砂岩结构和成分成熟度高,可做良好储层,且与烃源岩交互发育,埋藏适中,因此YS3段具有良好的“近源”油气成藏条件。结合构造研究和钻井揭示特征进行Yogou组时期沉积体系研究,建立时间与空间演化序列特征,评价物源体系和储层发育特征,进而优选有利勘探区带。通过盆地东、西和南缘沉积期古地形的对比研究,认为Yogou组时期盆地在不同盆地边缘位置具有不同的地形和沉积体系发育特征,西部Dinga断阶带为“陡坡带”特征,隆起区通过几组深大断裂快速进入深凹区,连接隆起和深凹区的斜坡区较窄;南部Yogou斜坡区和东部Fana低凸起地区地形较缓,斜坡区域面积大,有利区带广,据此建立了“陡坡带”和“缓坡带”沉积模式。东部隆起带在晚白垩世为Termit盆地的主力物源区,西部和南部为次要物源区,因此在海侵层序后期在东部广泛发育大规模三角洲前缘砂与泥岩互层的层序,南部次之,西部规模最小。烃源岩研究认为YS3段烃源岩为陆源有机质,与物源规模有关。因此沉积体系研究认为盆地西南部和东南部“缓坡带”储层和烃源岩都更加发育,成藏条件和可勘探面积都优于盆地西部“陡坡带”。下组合白垩系Yogou组YS3段与上组合古近系Sokor组比缺乏区域盖层,上组合反向断块勘探策略不适合YS3段层系,应重点针对背斜圈闭、小断距反向断块、顺向断块和岩性圈闭进行勘探。     

土壤类型及组分对热活化过硫酸盐氧化降解土壤中挥发性氯代烃的影响

为了探究高级氧化技术对土壤中有机氯代烃的氧化降解作用,为ISCO（in situ chemical oxidation）技术体系提供重要的理论依据和数据支撑,考察了热活化过硫酸盐（persulfate,PS）氧化降解不同类型土壤（砂类土壤、黏土类土壤）中挥发性氯代烃污染物（三氯乙烯（TCE）、三氯乙烷（TCA）、顺式-1,2-二氯乙烯（cis-1,2-DCE）、1,2-二氯乙烷（1,2-DCA））的效能;同时,通过硫酸盐与土壤相互作用过程研究,探究了不同土壤介质中有机质和无机组分在过硫酸盐消耗中所占比例。结果表明：在50℃时,热活化过硫酸盐可有效降解土壤中1,2-DCA、cis-1,2-DCE、TCA和TCE,砂类土壤介质中4种氯代烃降解效果依次为25%、89%、5%和61%,黏土类土壤介质中4种氯代烃降解效果依次为35%、86%、8%和63%;4种氯代烃的降解效果从高到低顺序依次为cis-1,2-DCE、TCE、1,2-DCA、TCA,砂类土壤中的氯代烃总体降解效果优于黏土类土壤中氯代烃的降解效果。另外,土壤中过硫酸盐氧化降解氯代烃反应研究发现,砂类和黏土类土壤介质组分中有机质消耗率分别为81.3%和72.6%,铁元素消耗率分别为80.5%和38.6%,表明土壤介质组分与过硫酸盐发生了氧化还原反应,从而导致过硫酸盐自身的大量消耗。由此可知,土壤介质中的有机质、铁元素等矿物质均参与过硫酸盐的消耗过程,且土壤有机质、铁元素与氯代烃之间在消耗过硫酸盐反应上存在竞争关系,土壤组分过多地消耗了过硫酸盐,导致了氯代烃的氧化降解效率较低。因此,针对实际有机氯代烃污染场地,采用过硫酸盐氧化技术进行修复时,过硫酸盐的实际投加量要远高于化学计量值,需充分考虑到土壤组分对过硫酸盐自身的消耗作用。     

CICE5.0与BCC_CSM2.0模式的耦合及对北极海冰的模拟评估

本文将美国Los Alamos国家实验室发展的最新海冰模式CICE5.0引入国家气候中心气候系统模式BCC_CSM2.0,替代原有的海冰模式SIS,形成一个新的耦合模式。在此基础上,评估新耦合模式对1985-2009年北极海冰的模拟性能,检验引入CICE5.0后对耦合模式中北极海冰、海洋和大气模拟结果的改进。结果表明,引入CICE5.0后,模式能较好地模拟出北极海冰的空间分布、季节以及年际变化特征。相比于旧版本耦合模式,新耦合模式模拟的北极多年冰增多、一年冰减少,同时,海冰增厚、海冰流速减慢,模拟效果得到显著改进,对波弗特涡流模拟的改善尤为明显。进一步分析发现,相比于SIS,CICE5.0对北极海冰特别是海冰厚度模拟性能的提升,在耦合进入BCC_CSM2.0后,会触发冰-温的正反馈机制,改进了模式对海平面气压场、表层气温和海表温度的模拟,由此进一步提高了模式对北极海冰的模拟能力。     

农牧交错带农田土壤风蚀PM10释放特征

粉尘释放是风蚀造成危害的一个重要过程。以农牧交错带沙区和非沙区农田土壤为研究对象,利用室内风洞模拟实验,实时监测了风蚀过程中释放的PM₁₀,分析了PM₁₀的动态变化特征,以深入认识土壤风蚀粉尘释放机理。结果表明：非沙区农田土壤风蚀强度远低于沙区农田,与风速呈指数函数关系;非沙区农田的土壤粉尘释放在不同风速下均以气流直接抬升模式为主,平均PM₁₀通量与风速呈线性函数关系,最大PM₁₀通量与风速呈幂函数关系;沙区农田的土壤粉尘释放在风速增大到一定程度后呈气流直接抬升和砂粒跃移冲击复合模式,最大PM₁₀通量增加不明显,但平均PM₁₀通量明显高于非沙区农田;对于沙区和非沙区农田而言,平均PM₁₀通量与风蚀速率呈对数函数关系。     

Dye adsorption on electrochemical exfoliated graphene oxide nanosheets: pH influence,kinetics and equilibrium in aqueous solution

Graphene oxide nanosheets were synthesized by electrochemical exfoliation. X-ray diffraction, scanning electron microscopy, atomic force microscopy, Raman spectrometry and Fourier transform infrared spectrometry were used to characterize crystal structure, particle size, thickness and function groups of the nanosheets. The nanosheets were examined for adsorption of methyl orange, an anionic dye, in aqueous solution at different pHs and temperatures. The maximum adsorption capacity of methyl orange on graphene oxide nanosheets obtained from the Langmuir isotherm was 138.69 mg/g at pH 2.0, which is larger than that of other carbonaceous adsorbents. The large adsorption affinity of graphene oxide nanosheets to methyl orange might be due to the presence of hydrogen bonding and π–π interaction between methyl orange and graphene oxide nanosheets. Adsorption kinetics followed a pseudo-second-order kinetic model, and the isotherm adsorption results were fitted with Langmuir isotherm model in a monolayer adsorption manner. The thermodynamic studies indicated that the adsorption reaction was a spontaneous physisorption process.     

Dissolution sequestration mechanism of CO<Subscript>2</Subscript> at the Shiqianfeng saline aquifer in the Ordos Basin,northwestern China

This study focused on the target injection layers of deep saline aquifers in the Shiqianfeng Fm. in the Carbon Capture and Sequestration (CCS) Demonstration Projects in the Ordos Basin, northwestern China. The study employed a combination method of experiments and numerical simulation to investigate the dissolution mechanism and impact factors of CO₂ in these saline aquifers. The results showed (1) CO₂ solubility in different types of water chemistry were shown in ascending order: MgCl₂-type water < CaCl₂-type water < Na₂SO₄-type water < NaCl-type water < Na₂CO₃-type water < distilled water. These results were consistent with the calculated results undertaken by TOUGHREACT with about 5% margin of error. CO₂ solubility of Shiqianfeng Fm. saline was 1.05 mol/L; (2) compared with distilled water, the more complex the water’s chemical composition, the greater the increase in HCO₃ ^?concentration. While the water’s composition was relatively simple, the tested water’s HCO₃ ^?concentrations were in close accord with the calculated value undertaken by the TOUGHREACT code, and the more complex the water’s composition, the poorer the agreement was, probably due to the complex and unstable HCO₃ ^? complicating matters when in an aqueous solution system including both tested HCO₃ ^?concentration and calculated HCO₃ ^?concentration; (3) the CO₂ solubility in the saline at the temperature conditions of 55 °C and 70 °C were 1.17 and 1.02 mol/L. When compared with the calculated value of 1.20 and 1.05 mol/L, they were almost the same with only 1 and 3% margin of error; concentrations of HCO₃ ^? were 402.73 mg/L (0.007 mol/L) and 385.65 mg/L (0.006 mol/L), while the simulation results were 132.16 mg/L (0.002 mol/L) and 128.52 mg/L (0.002 mol/L). From the contrast between the tested data and the calculated data undertaken by the TOUGHREACT code, it was shown that TOUGHRACT code could better simulate the interaction between saline and CO₂ in the dissolution sequestration capacity. Therefore, TOUGHREACT code could be used for the inter-process prediction of CO₂ long-term geological storage of CO₂; (4) The Ca²⁺ concentration and SO₄ ^2?concentration in saline water had less effect on the solubility of CO₂ and HCO₃ ^?concentration. In addition, TDS and pH values of saline affected not only the solubility of CO₂, but also the conversion of CO₂ to HCO₃ ^? due to that they can affect the activity and acid-base balance. So in fact, we just need to consider that the TDS and pH values are main impact factors in the dissolution sequestration capacity of CO₂ geological sequestration in deep saline aquifers.     

The diagenetic geochemistry and contamination assessment of iron,cadmium, and lead in the sediments from the Shuangtaizi estuary,China

Sediment and pore water samples have been collected from the coastal tidal flat in the Shuangtaizi estuary, China, in order to investigate the geochemical behavior of iron, cadmium, and lead during diagenesis and to assess the degree of contamination. The calculated enrichment factors and geoaccumulation indices for separate elements show that anthropogenic activities have had no significant influence on the distribution of Fe and Pb in the study area, whereas the distribution of Cd has been closely influenced in this way. The high percentage of exchangeable Cd (average of 56.34%) suggests that Cd represents a potential hazard to benthic organisms in the estuary. The calculated diffusive fluxes of metals show that the most mobilized metal is Fe (9.22 mg m^?2 a^?1), followed by Cd (0.54 mg m^?2 a^?1) and Pb (0.42 mg m^?2 a^?1). Low Fe²⁺ contents in surface pore water, alongside high chromium-reducible sulfur contents, and low acid-volatile sulfur, and elemental sulfur contents at 0–25 cm depth in sediments show that Fe²⁺ is formed by the reduction of Fe oxides and is transformed first to a solid phase of iron monosulfides (FeS) and eventually to pyrite (FeS₂). The release of adsorbed Pb due to reductive dissolution of Fe/Mn oxides during early diagenesis could be a source of Pb²⁺ in pore water. From the relatively low total organic carbon contents measured in sediments (0.46–1.28%, with an average of 0.94%) and the vertical variation of Cd²⁺ in pore water, sulfide or Fe/Mn oxides (instead of organic matter) are presumed to exert a significant influence on carrying or releasing Cd by the sediments.     

A distributed parameter model of a frame pin‐supported wall structure

Many reinforced‐concrete frames collapse via a soft‐story mechanism during severe earthquakes. Such collapses are mainly attributed to concentrated deformation in a soft story. Deformation control is thus important in preventing collapse. The frame pin‐supported wall structure is a type of rocking structure that releases constraints at the bottom of the wall. Previous research has obtained good results for the deformation control of this type of structure. However, the interior forces and strength demands of the pin‐supported wall have not been systematically explored. In this paper, a distributed parameter model is developed to investigate the strength demand of the wall in a frame pin‐supported wall structure. In the model, the pin‐supported wall is simplified as a bending beam and the frame is simplified as a shear beam. The two beams are joined by distributed shear connectors, so that the shear force can be transferred at any location on the interface. The model can be solved using differential equations based on equilibrium and compatibility. The accuracy of the model is verified using SAP2000 (Computers and Structures Inc., Berkeley, CA, USA). Displacement distribution of the structure and distributions of the moment and shear force within the pin‐supported wall are obtained for two typical external force profiles. It is found that the pin‐supported wall can effectively reduce the drift concentration factor. Distributions of the displacement, moment, and shear force are closely correlated with the relative stiffness of the wall and frame. Finally, recommendations on the stiffness and strength of a pin‐supported wall are made. Copyright © 2015 John Wiley & Sons, Ltd.     

Land cover mapping using time series HJ-1/CCD data

It is very difficult to have remote sensing data with both high spatial resolution and high temporal frequency; thus, two categories of land-use mapping methodology have been developed separately for coarser resolution and finer resolution data. The first category uses time series of data to retrieve the variation of land surface for classification, which are usually used for coarser resolution data with high temporal frequency. The second category uses fine spatial resolution data to classify different land surface. With the launch of Chinese satellite constellation HJ-1in 2008, four 30 m spatial resolution CCDs with about 360 km coverage for each one onboard two satellites made a revisit period of two days, which brought a new type of data with both high spatial resolution and high temporal frequency. Therefore, by taking the spatiotemporal advantage of HJ-1/CCD data we propose a new method for finer resolution land cover mapping using the time series HJ-1/CCD data, which can greatly improve the land cover mapping accuracy. In our two study areas, the very high resolution remote sensing data within Google Earth are used to validate the land cover mapping results, which shows a very high mapping accuracy of 95.76% and 83.78% and a high Kappa coefficient of 0.9423 and 0.8165 in the Dahuofang area of Liaoning Province and the Heiquan area of Gansu Province respectively.     

高速铁路对中国城市空间相互作用强度的影响

高速铁路作为一种新型的交通方式,其快速发展将会带来交通运输史上一次重大的飞跃,且其对区域空间结构、人口流动、经济联系和土地利用等的影响也越来越成为人们关注的焦点。在中国区域经济一体化进程不断加快的背景下,研究高速铁路对城市空间相互作用强度的影响,对加强区域间经济联系、促进区域经济发展和地域空间组织模式的重构具有重要意义。本文基于GIS网络分析工具,构建时间成本矩阵,研究中国333个地级行政单元和4个直辖市对外经济联系总量和城市对间经济联系强度的空间分布特征,构建无高铁、高铁现状和规划高铁三种情景,并对三种情景进行模拟与探讨。结果显示：① 城市空间相互作用呈现出明显的地带性和“廊道效应”,反映了高速交通在重塑区域空间结构中的作用;② 高速铁路建设提升了城市对外经济联系强度总量,且逐渐从追求“效率”转向“公平性”;③ 高速铁路建设缩小了全国城市对外经济联系总量的差异,但却扩大了城市对间经济联系强度的差异;④ 三大城市群成为城市对外经济总量绝对获益量最大的地区,而其毗邻的中小城市成为提升速率最大的城市。