Imaging DOAS for volcanological applications

The simultaneous quantitative determination of two-dimensional bromine monoxide (BrO) and sulphur dioxide (SO₂) distributions in volcanic gas plumes is described. Measurements at the fumarolic field on the island Vulcano (autumn 2004) and in the plume of Mt. Etna volcano (spring 2005) were carried out with an Imaging DOAS instrument. The SO₂ fluxes of several fumaroles were estimated from two-dimensional distributions of SO₂. Additionally, the first two-dimensional distributions of BrO within a volcanic plume were successfully retrieved. Slant column densities of up to 2.6 × 10¹⁴ molecules per square centimetre were detected in the plume of Mt. Etna. The investigation of the BrO/SO₂ ratio, calculated from the two-dimensional distributions of SO₂ and BrO, shows an increase from the centre to the edge of the volcanic plume. These results have significance for the involvement of ozone during BrO formation processes in volcanic emissions.     

Morphological signatures of normal faulting in low‐gradient alluvial rivers in south‐eastern Louisiana,USA

We explore the fluvial response to faulting in three low‐gradient, sand‐bed rivers in south‐eastern Louisiana, USA, that flow across active normal faults from footwall (upstream) to hangingwall (downstream). We calculate sinuosity, migration rate and migration direction in order to identify anomalies spatially associated with fault scarps. In two of the rivers we model one‐dimensional steady water flow to identify anomalies in surface water slope, width‐to‐depth ratio, and shear stress. In each of these rivers there is one location where flow modeling suggests potential channel incision through the footwall, as indicated by relatively high surface water slopes and shear stress values. In one of these footwall locations, the river straightens and width‐to‐depth ratios decrease, likely contributing to higher surface water slopes and shear stress. This is in contrast to previous studies that have proposed increased sinuosity across fault footwalls and decreased sinuosity across hangingwalls. However, in two hangingwall locations we also observe relatively less sinuous channels. Other planform changes on the hangingwall include topographic steering of channels along and towards the fault and one example of an avulsion. The most notable anomaly in migration rate occurs on the hangingwall of a fault where a river has cut off a meander loop. Although fluvial response to faulting varies here, comparatively large and small channels exhibit similar responses. Further, Pleistocene fault slip rates are orders of magnitude lower than the channel migration rates, suggesting that faulting should not be a major influence on the fluvial evolution. Nonetheless, notable channel anomalies exist near faults, suggesting that recent fault slip rates are higher than Pleistocene rates, and/or that low‐gradient alluvial channels are more sensitive to faulting than previous studies have suggested. Rivers appear to be influenced by faulting in this setting, however background rates of meander loop cutoff may be just as influential as faulting. Copyright © 2015 John Wiley & Sons, Ltd.     

Comprehensive Parametrization of Surface-Layer Transfer Coefficients for Use in Atmospheric Numerical Models

A new non-iterative bulk parametrization for surface-layer transfer coefficients for momentum and heat is presented. It is applicable for a wide range of aerodynamic and thermal roughness lengths, and includes the effect of the roughness sublayer. As a consequence, the non-iterative method is suitable for every surface type, especially for urban surfaces for which existing non-iterative parametrizations fail. The analytical approximation compares very well with an iterative approach. Our method can be easily implemented in atmospheric numerical models that already employ a non-iterative approach.     

Ageing effect on the mineral and chemical composition of Opalinus Clays (Mont Terri,Switzerland) after excavation and surface storage

Samples of Opalinus Clays from Mont Terri Underground Research Laboratory in the Swiss Jura were analyzed repetitively relative to the duration of their exposure to atmosphere. The objective was the evaluation of such a progressive exposure on the chemical composition of whole-rock samples, and on the chemical and Sr isotopic compositions of leachates obtained by leaching the rock powders with dilute acetic acid. This chemical study was complemented by scanning electron microscope observations to identify the related mineral alterations. The chemical data for the rock powders remained quite constant whatever the duration of the storage, whereas significant changes were observed for the leachates. Similar changes were observed in the leachates of samples collected progressively closer to the walls of a previously excavated niche. When storage time or distance to gallery wall increases, the main variations are: (1) a progressive decrease of the element contents and of the ⁸⁷Sr/⁸⁶Sr ratio in the leachates, (2) an alteration of pyrite followed by precipitation of Ca-sulfate in the rocks, both observed by SEM, and (3) a probable precipitation of new mineral phases in the rocks, such as Fe-oxyhydroxides and/or jarosite that could not be visualized by electron microscopic observation because of their very limited amount and very small grain size. The modifications call for an oxidation of pyrite that probably induced also an oxidation of the organic matter. It could also be shown that the reactions were enhanced by temperature increase, and that they were less pronounced in the samples behind the gallery wall than in the cores stored in laboratory conditions.     

Quaternary glaciation of Mount Everest

The Quaternary glacial history of the Rongbuk valley on the northern slopes of Mount Everest is examined using field mapping, geomorphic and sedimentological methods, and optically stimulated luminescence (OSL) and ¹⁰Be terrestrial cosmogenic nuclide (TCN) dating. Six major sets of moraines are present representing significant glacier advances or still-stands. These date to >330 ka (Tingri moraine), >41 ka (Dzakar moraine), 24–27 ka (Jilong moraine), 14–17 ka (Rongbuk moraine), 8–2 ka (Samdupo moraines) and ～1.6 ka (Xarlungnama moraine), and each is assigned to a distinct glacial stage named after the moraine. The Samdupo glacial stage is subdivided into Samdupo I (6.8–7.7 ka) and Samdupo II (～2.4 ka). Comparison with OSL and TCN defined ages on moraines on the southern slopes of Mount Everest in the Khumbu Himal show that glaciations across the Everest massif were broadly synchronous. However, unlike the Khumbu Himal, no early Holocene glacier advance is recognized in the Rongbuk valley. This suggests that the Khumbu Himal may have received increased monsoon precipitation in the early Holocene to help increase positive glacier mass balances, while the Rongbuk valley was too sheltered to receive monsoon moisture during this time and glaciers could not advance. Comparison of equilibrium-line altitude depressions for glacial stages across Mount Everest reveals asymmetric patterns of glacier retreat that likely reflects greater glacier sensitivity to climate change on the northern slopes, possibly due to precipitation starvation.     

Hydrogeological and hydrochemical characterization of two karstic discharge areas in San Luis Potosí, Mexico

Two karstic discharge areas, Río Verde (RV) and Ciénega de Cabezas (CC), located in a distance of 80 km to each other are chosen to determine the influence of local variations in geology and climatic condition on water chemistry and to examine if the groundwater, supplying the discharge areas, undergoes the same evolution and has a common source. Both study areas are situated on the carbonate platform Valles-San Luis Potosí and comprise a similar geological setting, but despite of their spatial vicinity the climate is semiarid in RV and humid in CC presenting an important factor on the amount of discharge and the concentrations of ions in the discharge. The investigation encompasses discharge, hydrochemical and physico-chemical parameter evaluations as well as the determination of saturation indices, hydrochemical modelling and water type characterization of surface water samples to derive knowledge of the groundwater systems. Scatterplots and saturation indices were used to proof the influence of lithological variability. Both study areas represent normal alkaline water, marked by high concentrations of calcium and magnesium with varying concentrations of bicarbonate and sulphate. In RV, the water interacts with dolomite rocks and gypsum layers, whereas in CC the dolomite content is depleted and the influence of limestone rocks increases. The climatic impact on the groundwater in RV is noticeable by the increase in ionic concentrations due to higher evaporation. In CC the higher amount of precipitation dilutes the groundwater and causes decreasing ionic concentrations.     

Is the world's economic centre of gravity already in Asia?

This paper proposes a novel and simple measure of the world's economic centre of gravity. Over the recent decades, this centre has shifted towards Asia, but is still located in Europe.