Organotemplate silica deposition in Neoproterozoic deep-marine environments: evidence from the Penganga Group, Adilabad, India

Silica in bedded cherts interstratified with manganese carbonates in a deep‐water carbonate ramp succession of the Neoproterozoic Penganga Group, India, displays film‐like, spherical to rod‐shaped, and tubular branching microstructures. The microstructures resemble mineralized extracellular polysaccharides, biofilms and bacterial morphologies. The microstructures suggest silicification by nucleation of silica on organic‐templates or indirectly as sorbed species accumulating on organic templates. Given that similar microstructures have also been documented in Archean cherts it is proposed that organotemplates might have been an important sink for the deposition of silica in Precambrian deep‐water marine environments.     

Low-cost volcano surveillance from space: case studies from Etna, Krafla, Cerro Negro, Fogo, Lascar and Erebus

 Satellite data offer a means of supplementing ground-based monitoring during volcanic eruptions, especially at times or locations where ground-based monitoring is difficult. Being directly and freely available several times a day, data from the advanced very high resolution radiometer (AVHRR) offers great potential for near real-time monitoring of all volcanoes across large (3000×3000 km) areas. Herein we describe techniques to detect and locate activity; estimate lava area, thermal flux, effusion rates and cumulative volume; and distinguish types of activity. Application is demonstrated using data for active lavas at Krafla, Etna, Fogo, Cerro Negro and Erebus; a pyroclastic flow at Lascar; and open vent systems at Etna and Stromboli. Automated near real-time analysis of AVHRR data could be achieved at existing, or cheap to install, receiving stations, offering a supplement to conventional monitoring methods. Received: 21 January 1997 / Accepted: 3 April 1997     

Interstitial water chemistry of villefranche bay sediments: Trace metal diagenesis

Pore water aliquots were taken with an in situ close interval sampler: the “Peeper”.We report here the pore water concentration profiles of TCO₂, SO₄, TH₂S, Ca and the trace metals Mn, Cu, Pb, Cd and Cr from sediments of a relatively polluted area, the Villefranche Bay, on the French Riviera (close to Nice).We investigated the major ion concentrations in order to establish geochemical mass balances of organic matter oxidation. ΔTCO₂/ΔSO₄ was <−2.0, reflecting the precipitation of calcite as confirmed by the calcium profile. Reduction of sulfate led to increasing sulfide concentrations with depth.Trace metal interstitial water concentrations decreased from 63 to 5 nM, 18 to 4 nM and 6.6 to less than 2 nM for Cu, Pb and Cr, respectively. Cd showed a different pattern with top and deep values of 0.7 nM and a minimum of 0.27 nM.Thermodynamic calculations were performed which suggest the potential formation of mineral phases such as sulfides.     

Structure cristalline d'une ménéghinite naturelle pauvre en cuivre,Cu0,58Pb12,72(Sb7,04Bi0,24)S24Crystal structure of a Cu-poor natural meneghinite,Cu0.58Pb12.72(Sb7.04Bi0.24)S24

Cu-poor meneghinite from La Lauzière Massif (Savoy, France) has the composition (electron microprobe) (in wt%): Pb 59.50, Sb 20.33, Bi 1.19, Cu 0.87, Ag 0.05, Fe 0.03, S 17.62, Se 0.05, Total 99.64. Its crystal structure (X-ray on a single crystal) was solved with R1=0.0506, wR2=0.1026, with an orthorhombic symmetry, space group Pnma, and a=24.080(5) Å, b=4.1276(8) Å, c=11.369(2) Å, V=1130.0(4) Å³, Z=4. Relatively to the model of Euler and Hellner (1960), this structure shows a significantly lower site occupancy factor for the tetrahedral Cu site (0.146 against 0.25). Among the five other metallic sites, Bi appears in the one with predominant Sb. Developed structural formula: Cu_0.15Pb₂(Pb_0.53Sb_0.47)(Pb_0.46Sb_0.54)(Sb_0.75Pb_0.19Bi_0.06)S₆; the reduced one: Cu_0.58Pb_12.72(Sb_7.04Bi_0.24)S₂₄. The formation of such a Cu-poor variety seems to be related to specific paragenetic conditions (absence of coexisting galena), or to crystallochemical constraints (minor Bi). To cite this article: Y. Moëlo et al., C. R. Geoscience 334 (2002) 529–536.     

Habitat, occurrence and conservation of Saharo-Arabian-Turanian element Forsskaolea tenacissima L. in the Iberian Peninsula

The aim of this study is to assess the Iberian populations of Forsskaolea tenacissima L. according to its biogeographical interest, habitat, geographical range and conservation status. Results point out that they are restricted to gravel wadis of Tabernas Desert (SE Spain), are scarcely included in protected areas and represent historically isolated populations with relict behaviour. We also describe a new association, Senecioni-Forsskaoleetum tenacissimae. Conservation status of species is cause for concern and two conservation actions must be carried out. Firstly, protected areas should house Forsskaolea populations and secondly, phytosociological characterization of a community allows inventorying its habitat and directing conservation efforts to community level.     

Apport de l'imagerie satellitaire radar pour l'exploration géologique en zones arides

The potential of radar imagery in geological exploration was investigated at a study site in Mauritania (Akjoujt region). Compared with optical images, the results obtained show how radar imagery can help not only in detecting surface geological structures such as dykes and veins, but also mapping subsurface structures beneath a shallow layer of sand (palaeochannels). The mapping potential was found to be much better at long wavelengths than at short ones (L-band, compared with C- and X-band). As for optical images, their contribution is much more limited in the mapping of surface geological structures, and inappropriate for detecting subsurface structures. We conclude that spatial remote sensing enables the improvement of existing geological maps and the optimization of cartographic surveying. To cite this article: N. Baghdadi et al., C. R. Geoscience 337 (2005).     

North Atlantic atmospheric circulation and surface wind in the Northeast of the Iberian Peninsula: uncertainty and long term downscaled variability

The variability and predictability of the surface wind field at the regional scale is explored over a complex terrain region in the northeastern Iberian Peninsula by means of a downscaling technique based on Canonical Correlation Analysis. More than a decade of observations (1992–2005) allows for calibrating and validating a statistical method that elicits the main associations between the large scale atmospheric circulation over the North Atlantic and Mediterranean areas and the regional wind field. In an initial step the downscaling model is designed by selecting parameter values from practise. To a large extent, the variability of the wind at monthly timescales is found to be governed by the large scale circulation modulated by the particular orographic features of the area. The sensitivity of the downscaling methodology to the selection of the model parameter values is explored, in a second step, by performing a systematic sampling of the parameters space, avoiding a heuristic selection. This provides a metric for the uncertainty associated with the various possible model configurations. The uncertainties associated with the model configuration are considerably dependent on the spatial variability of the wind. While the sampling of the parameters space in the model set up moderately impact estimations during the calibration period, the regional wind variability is very sensitive to the parameters selection at longer timescales. This fact illustrates that downscaling exercises based on a single configuration of parameters should be interpreted with extreme caution. The downscaling model is used to extend the estimations several centuries to the past using long datasets of sea level pressure, thereby illustrating the large temporal variability of the regional wind field from interannual to multicentennial timescales. The analysis does not evidence long term trends throughout the twentieth century, however anomalous episodes of high/low wind speeds are identified.     

Shear sense inversion in the Hilti mantle section (Oman ophiolite) and active mantle uprise

Structural analyses in the well-exposed Hilti mantle section in the Oman ophiolite suggest a model of forceful horizontal flow in the uppermost mantle at the edge of a diapir below a oceanic spreading center. Detailed structural mapping, focussed on high-T deformation (i.e., asthenospheric flow), revealed a gently undulated flat structure with a uniform east-west flow direction. When it is related to the N–S to NNW–SSE trending, vertical sheeted dike complex located to the east, this mantle flow is parallel to the spreading direction. Because the Moho is so flat lying, a large dunite occurrence at the south-western region is possibly ascribed to the Moho Transition Zone. Kinematic analysis shows that the shear direction generally changes from top-to-the west in the upper level, to top-to-the east in the lower level with respect to the Moho. This shear sense inversion is explained by a model of forceful flow due to an active mantle uprise and it is not compatible with a passive mantle uprise. In the plan section, the boundary of the shear sense inversion is subparallel to the flow direction and subperpendicular to the spreading axis. In cross section, the boundary appears to occur at various depths in the range of 200 m to 500 m. It shows that the active mantle uprise in the diapir center resulted in a channelled horizontal flow.