Probing the IRC+10 ° 216 circumstellar envelope using spectroscopic observations of background stars

A unique and novel set of observations has been undertaken to study the circumstellar envelope (CSE) of the nearby (130 pc) carbon star IRC +10° 216 using optical absorption spectroscopy towards twobackground stars lying beyond the envelope.The primary aim of the observations is to search for diffuse band (DIB)carriers in the CSE. The circumstellar H+2H₂column density expected along the line of sight towards the targets islarge compared to that derived from the small interstellar reddening inthis region, E _B-V< 0.03 mag. We summarise our mainfindings, already reported in Kendall et al. (2002): The 6284Å DIB is detected in the VLT/UVES spectrum of one target, but clearly arises inthe foreground ISM. No other DIB is seen. Hence the DIB carriers, if present in the CSE, have a low abundance relative to H in the C-rich envelope of IRC +10°216, in comparison with this ratio in theISM. An important new result, previously unreported, concerns the detectionof circumstellar C₂ via absorption of the Phillips bandnear 8760Å.     

Cadmium,copper and lead in the western Mediterranean Sea

The results of determinations of cadmium, copper and lead in western Mediterranean waters collected during the PHYCEMED 81 cruise are discussed in this paper. The analyses were carried out according to two different methods: flameless atomic absorption and anodic stripping voltammetry. Very strict conditions of sampling and treatment were maintained in order to reduce the chance of contamination. The concentrations found are considerably lower than those usually reported for Mediterranean waters. The distributions are homogeneous, both vertically and from one station to another. The average concentrations are 8 ng 1^?1 for Cd, 90 ng 1^?1 for Cu and 30–40 ng^?1 for Pb. This homogeneity, as well as the concentrations of cadmium and lead, may be explained by the hydrological conditions of the Mediterranean Sea.     

Bioremediation and toxicity determination of natural seawater polluted with weathered crude oil by salt-tolerant consortia in a SBR

The aim of this research was to compare the bioremediation treatment of seawater polluted with two different concentrations of weathered crude oil (0.2 for experiment (a) and 1.14% for experiment (b), v/v) by salt-tolerant consortia enriched from the sludge of a refinery wastewater treatment facility, in a SBR. The use of a commercial bioremediation stimulant (S200) was also evaluated as an alternative to the traditional nitrogen and phosphorus supplement.     

Presumed magnetic biosignatures observed in magnetite derived from abiotic reductive alteration of nanogoethite

The oriented chains of nanoscale Fe-oxide particles produced by magnetotactic bacteria are a striking example of biomineralization. Several distinguishing features of magnetite particles that comprise bacterial magnetosomes have been proposed to collectively constitute a biosignature of magnetotactic bacteria (Thomas-Keprta et al., 2001). These features include high crystallinity, chemical purity, a single-domain magnetic structure, well-defined crystal morphology, and arrangement of particles in chain structures. Here, we show that magnetite derived from the inorganic breakdown of nanocrystalline goethite exhibits magnetic properties and morphologies remarkably similar to those of biogenic magnetite from magnetosomes. During heating in reducing conditions, oriented nanogoethite aggregates undergo dehydroxylation and transform into stoichiometric magnetite. We demonstrate that highly crystalline single-domain magnetite with euhedral grain morphologies produced abiogenically from goethite meets several of the biogenicity criteria commonly used for the identi?cation of magnetofossils. Furthermore, the suboxic conditions necessary for magnetofossil preservation in sediments are conducive to the reductive alteration of nanogoethite, as well as the preservation of detrital magnetite originally formed from goethite. The findings of this study have potential implications for the identification of biogenic magnetite, particularly in older sediments where diagenesis commonly disrupts the chain structure of magnetosomes. Our results indicate that isolated magnetofossils cannot be positively distinguished from inorganic magnetite on the basis of their magnetic properties and morphology, and that intact chain structures remain the only reliable distinguishing feature of fossil magnetosomes.     

Back front of seismicity induced by non‐linear pore pressure diffusion

Borehole fluid injections are accompanied by microseismic activity not only during but also after termination of the fluid injection. Previously, this phenomenon has been analysed, assuming that the main triggering mechanism is governed by a linear pressure diffusion in a hydraulically isotropic medium. In this context the so‐called back front of seismicity has been introduced, which allows to characterize the hydraulic transport from the spatiotemporal distribution of post‐injection induced events. However, rocks are generally anisotropic, and in addition, fluid injections can strongly enhance permeability. In this case, permeability becomes a function of pressure. For such situations, we carry out a comprehensive study about the behaviour and parametrization of the back front. Based on a model of a factorized anisotropic pressure dependence of permeability, we present an approach to reconstruct the principal components of the diffusivity tensor. We apply this approach to real microseismic data and show that the back front characterizes the least hydraulic transport. To investigate the back front of non‐linear pore‐fluid pressure diffusion, we numerically consider a power‐law and an exponential‐dependent diffusivity. To account for a post‐injection enhanced hydraulic state of the rock, we introduce a model of a frozen (i.e., nearly unchanged after the stimulation) medium diffusivity and generate synthetic seismicity. We find that, for a weak non‐linearity and 3D exponential diffusion, the linear diffusion back front is still applicable. This finding is in agreement with microseismic data from Ogachi and Fenton Hill. However, for a strong non‐linear fluid–rock interaction such as hydraulic fracturing, the back front can significantly deviate from a time dependence of a linear diffusion back front. This is demonstrated for a data set from the Horn River Basin. Hence, the behaviour of the back front is a strong indicator of a non‐linear fluid–rock interaction.     

Modeling acid-gas generation from boiling chloride brines

Background  

This study investigates the generation of HCl and other acid gases from boiling calcium chloride dominated waters at atmospheric pressure, primarily using numerical modeling. The main focus of this investigation relates to the long-term geologic disposal of nuclear waste at Yucca Mountain, Nevada, where pore waters around waste-emplacement tunnels are expected to undergo boiling and evaporative concentration as a result of the heat released by spent nuclear fuel. Processes that are modeled include boiling of highly concentrated solutions, gas transport, and gas condensation accompanied by the dissociation of acid gases, causing low-pH condensate.