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51.
A. P. Dickin N. W. Jones M. F. Thirlwall R. N. Thompson 《Contributions to Mineralogy and Petrology》1987,96(4):455-464
Twelve138Ce/136Ce isotope determinations, 31 Nd isotope analyses, and 31 REE profiles are presented for Tertiary basic to intermediate igneous rocks from the Isle of Skye, NW Scotland. The aim of this work is to precisely identify the contamination mechanisms of basic magmas emplaced through old crust, and to test the effectiveness of Ce isotope analysis as a petrogenetic tool.Combined Ce/Nd isotope analysis enables the modelling of the light REE profiles of the mantle-derived precursors to contaminated lavas, using different crustal end-members, in order to compare these with the magmatic lineage of uncontaminated Skye lavas. The geochemical data support a contamination mechanism involving a granitic melt, produced either by large degree melting of Scourian granulitefacies acid sheets, or (possibly) by melting of intermediate gneiss out of isotopic equilibrium.Basaltic lavas showing strong isotopic contamination effects yield calculated degrees of crustal contamination by large degree granitic melts of ca. 8 or 9% based on Ce and Nd isotopic data respectively. However, for lavas with liquidus temperatures of over 1250° C, the temperature dependence of the degree of contamination is weak.The combination of this evidence with new and published Pb isotope data suggests that the bulk of crustal contamination of the Skye lavas occurred in sill complexes at distinct levels in the crust, rather than during the actual ascent of magma through the crust in dykes. It is suggested on the basis of published fluid dynamic and field evidence that the assimilation of large degree melts of acid gneiss by turbulently flowing magma is more likely than assimilation of small degree disequilibrium melts from more refractory intermediate gneisses.It is concluded that Ce isotope analysis is a viable and useful adjunct to Nd isotope data in petrogenetic studies of continental igneous rocks emplaced through old basement. 相似文献
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R. N. Thompson A. P. Dickin I. L. Gibson M. A. Morrison 《Contributions to Mineralogy and Petrology》1982,79(2):159-168
One of the major puzzles presented by the geochemistry of the Palaeocene plateau lavas of Skye and Mull (N.W. Scotland) is that, although a very strong case can be made that the magmas are variably isotopically contaminated by Archaean Lewisian continental crust, little evidence has been gleaned to date from their major- and trace-element compositions to illuminate this hypothetical process. The combined results of published Sr-, Nd- and Pb-isotope studies of these lavas allow the basalts and hawaiites to be divided into three broad groups: essentially uncontaminated; contaminated with granulite-facies Archaean crust; contaminated with amphibolite-facies Archaean crust. Members of each group show distinctive chondrite-normalised incompatible-element patterns. The processes which gave rise to isotopic contamination of these lavas also affected the abundances and ratios of Ba, Rb, Th, K, Sr and light REE in the magmas, whilst having negligible effects on their abundances and ratios of Nb, Ta, P, Zr, Hf, Ti, Y and middle-heavy REE. Because such a wide range of elements were affected by the contamination process, it is postulated that the contaminant was a silicate melt of one or more distinctive crustal rock types, rather than an aqueous or similar fluid causing selective elemental movements from wall rocks into the magmas. As previous experimental and isotopic studies have shown that the Skye and Mull basic magmas were not constrained by cotectic equilibria at the time when they interacted with sial, the compositions of the contaminated lavas have been modelled in terms of simple magma-crust mixtures. Very close approximations to both the abundances and ratios of incompatible elements in the two groups of contaminated basalts may be obtained by adding 15% to 20% of Lewisian leucogneisses to uncontaminated Palaeocene basalt. Nevertheless, major-element constraints suggest that the maximum amount of granitic contaminant which has been added to these magmas lies between 5% and 10%. These estimates may be reconciled by postulating that the contaminants were large-fraction cotectic partial melts of Lewisian leucogneisses, leaving plagioclase residua. A corollary of this hypothesis is that it is necessary to postulate that the magma chambers where the sialic contamination occurred were, in fact, dykes or (more probably) sills. The very large surface-to-volume ratios of such magmas bodies would permit the systematic stripping, by partial melting, of the most-easily-fusible leucogneisses and pegmatites from the Lewisian crust, whilst failing to melt its major rock types. A present-day analogue to this situation may be the extensive sill-like magma bodies detected by geophysical methods within the continental crust beneath the Rio Grande Rift, southwestern U.S.A. 相似文献
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Chemical and mineralogical studies of fresh and hydrothermally altered rhyolitic material in Upper and Lower Geyser Basins, Yellowstone National Park, show that all the altered rocks are enriched in Cs and that Cs is selectively concentrated in analcime. The Cs content of unaltered rhyolite lava flows, including those from which the altered sediments are derived, ranges from 2.5 to 7.6 ppm. The Cs content of analcime-bearing altered sedimentary rocks is as high as 3000 ppm, and in clinoptilolite-bearing altered sedimentary rocks Cs content is as high as 180 ppm. Altered rhyolite lava flows which were initially vitrophyres, now contain up to 250 ppm Cs, and those which were crystallized prior to hydrothermal alteration contain up to 14 ppm. Mineral concentrates of analcime contain as much as 4700 ppm Cs. The Cs must have been incorporated into the analcime structure during crystallization, rather than by later cation substitution, because analcime does not readily exchange Cs. The of the fluids circulating through the hydrothermal system varies, suggesting that Cs is not always a conservative ion and that Cs is lost from upflowing thermal waters due to water-rock interaction resulting in crystallization of Cs-bearing analcime.The source of Cs for Cs enrichment of the altered rocks is from leaching of rhyolitic rocks underlying the geyser basins, and from the top of the silicic magma chamber that underlies the area.Analcime is an important natural Cs sink, and the high Cs concentrations reported here may prove to be an important indicator of the environment of analcime crystallization. 相似文献
57.
I. Camilo Higuera-Díaz Philip J. Carpenter Michael D. Thompson 《Environmental Geology》2007,53(4):805-812
Karst aquifers are highly susceptible to contamination, with numerous points of entry for contaminants through recharge features
such as sinkholes, swallow holes and solutionally enlarged fractures. These recharge features may be filled or obscured at
the surface, requiring the use of geophysical or remote sensing techniques for their identification. This study uses seismic
refraction data collected at the Ft. Campbell Army Airfield (CAAF), Kentucky, USA, to test the hypothesis that refraction
tomography is a useful tool for imaging bedrock depressions beneath thick overburden (greater than 20 m of unconsolidated
sediment). Southeast of the main taxiway of CAAF seismic velocity tomograms imaged a bedrock low, possibly a closed depression,
at a depth of 25 m that had been earlier identified through delay-time analysis of the same refraction data. Tomography suggests
the bedrock low is about 250-m wide by 10-m deep at its widest point. High rates of contaminant vapor extraction over the
western extension of this feature suggest a high concentration of contaminants above, and within, this filled bedrock low,
the base of which may contain solutionally enlarged fractures (i.e. karst conduits) that could funnel these contaminants to
the upper or lower bedrock aquifers. This study thus demonstrates the viability of seismic refraction tomography as a tool
for identification of filled sinkholes and bedrock depressions in karst areas. 相似文献
58.
The thick (>1 km) Neoproterozoic Otavi Group of Namibia accumulated after ca. 760 Ma along >700 km of the faulted margin of the Congo Craton. The margin shows a north to south, downbasin transition from a shallow‐water carbonate shelf (Otavi Platform) to offshore deepwater slope (Outjo Basin). Within the latter, the Abenab and Tsumeb Subgroups contain large volumes of poorly sorted breccias, conglomerates and diamictites composed principally of locally derived carbonate. Diamictite facies were reported in the 1930s as tillites left by an ice sheet (although the absence of striated clasts and other key glacial indicators was viewed as problematic). Later workers rejected a glacial origin concluding that Outjo basin facies were deposited as parts of prograding submarine wedges built by mass flows during active rifting. Recently, the Snowball Earth hypothesis has returned to the earlier glacial interpretation; arguing that these strata represent a record of extraordinary late Neoproterozoic glacial and interglacial climates when global temperatures fluctuated by up to 100°C. Facies analysis of breccias, diamictites, conglomerates and sandstone strata of the Otavi Group identifies them as genetically related, subaqueously deposited sediment gravity flows. They lack diagnostic indicators of any one specific climate in source areas. These facies were all deposited in deepwater at the foot of landslide‐prone scarp blocks where debris flows and turbidity currents moved large volumes of coarse, freshly broken carbonate debris produced by faulting. Breccias, diamictites, conglomerates and sandstones occur in composite fining‐ and thinning‐upward bundles that are directly analogous to those reported from many other faulted margins in the Phanerozoic stratigraphic record. These rocks provide no clear sedimentological signature of a glacial source or catastrophic Snowball Earth‐type temperature fluctuations. Instead, they point to a dominant tectonic control on sedimentation related to faulting along the margin of the Congo Craton. 相似文献
59.
W. Douglas Thompson Daniel Wartenberg 《Stochastic Environmental Research and Risk Assessment (SERRA)》2007,21(5):635-646
Much research in environmental epidemiology relies on aggregate-level information on exposure to potentially toxic substances
and on relevant covariates. We compare the use of additive (linear) and multiplicative (log-linear) regression models for
the analysis of such data. We illustrate how both additive and multiplicative models can be fit to aggregate-level data sets
in which disease incidence is the dependent variable, and contrast these results with similar models fitted to individual-level
data. We find (1) that for aggregate-level data, multiplicative models are more likely than additive models to introduce bias
into the estimation of rates, an effect not found with individual-level data; and (2) that under many circumstances multiplicative
models reduce the precision of the estimates, an effect also not found in individual-level models. For both additive and multiplicative
models of aggregate-level data, we find that, in the presence of covariates, narrow confidence interval are obtained only
when two or more antecedent factors are strongly related to the measured covariate and/or the exposure of primary substantive
interest. We conclude that the equivalency of fitting additive versus multiplicative models in studies with individual-level
binary data does not carry over to studies that analyze aggregate-level information. For aggregate data, we strongly recommend
use of additive models.
Supported by Grant #1 U19 EH000102 from the National Center for Environmental Health, Centers for Disease Control and Prevention,
Atlanta, GA. 相似文献
60.