Geochemistry and chronology of the Bunburra Rockhole ungrouped achondrite

Bunburra Rockhole is a unique basaltic achondrite that has many mineralogical and petrographic characteristics in common with the noncumulate eucrites, but differs in its oxygen isotope composition. Here, we report a study of the mineralogy, petrology, geochemistry, and chronology of Bunburra Rockhole to better understand the petrogenesis of this meteorite and compare it to the eucrites. The geochemistry of bulk samples and of pyroxene, plagioclase, and Ca‐phosphate in Bunburra Rockhole is similar to that of typical noncumulate eucrites. Chronological data for Bunburra Rockhole indicate early formation, followed by slow cooling and perhaps multiple subsequent heating events, which is also similar to some noncumulate eucrites. The ²⁶Al‐²⁶Mg extinct radionuclide chronometer was reset in Bunburra Rockhole after the complete decay of ²⁶Al, but a slight excess in the radiogenic ²⁶Mg in a bulk sample allows the determination of a model ²⁶Al‐²⁶Mg age that suggests formation of the parent melt for this meteorite from its source magma within the first ~3 Ma of the beginning of the solar system. The ²⁰⁷Pb‐²⁰⁶Pb absolute chronometer is also disturbed in Bunburra Rockhole minerals, but a whole‐rock isochron provides a re‐equilibration age of ~4.1 Ga, most likely caused by impact heating. The mineralogy, geochemistry, and chronology of Bunburra Rockhole demonstrate the similarities of this achondrite to the eucrites, and suggest that it formed from a parent melt with a composition similar to that for noncumulate eucrites and subsequently experienced a thermal history and evolution comparable to that of eucritic basalts. This implies the formation of multiple differentiated parent bodies in the early solar system that had nearly identical bulk elemental compositions and petrogenetic histories, but different oxygen isotope compositions inherited from the solar nebula.     

Load or concentration,logged or unlogged? Addressing ten years of uncertainty in neural network suspended sediment prediction

This paper addresses current inconsistencies in methodological approaches for neural network modelling of suspended sediment. An expansion in the number of case studies being published over the last decade has yet to result in agreed guidelines on whether suspended sediment load or concentration should be modelled, and whether log‐transformation of data is either necessary or potentially beneficial. This contrasts with the well‐recognized guidelines that direct traditional sediment rating curve studies. The paper reports a comprehensive set of single‐input single‐output neural network suspended sediment modelling experiments performed on two catchments in Puerto Rico. It examines the impact of internal complexity, input variable choice and data transformation on the form, consistency and physical rationality of model outputs, the existence of localized overfitting and the usefulness of global performance metrics. Sound guidance on whether to model sediment load or concentration, and whether to model log‐transformed data is provided. Copyright © 2011 John Wiley & Sons, Ltd.     

Radiocarbon and 230Th data reveal rapid redistribution and temporal changes in sediment focussing at a North Atlantic drift

In locations of rapid sediment accumulation receiving substantial amounts of laterally transported material the timescales of transport and accurate quantification of the transported material are at the focus of intense research. Here we present radiocarbon data obtained on co-occurring planktic foraminifera, marine haptophyte biomarkers (alkenones) and total organic carbon (TOC) coupled with excess Thorium-230 (²³⁰Th_xs) measurements on four sediment cores retrieved in 1649–2879 m water depth from two such high accumulation drift deposits in the Northeast Atlantic, Björn and Gardar Drifts. While ²³⁰Th_xs inventories imply strong sediment focussing, no age offsets are observed between planktic foraminifera and alkenones, suggesting that redistribution of sediments is rapid and occurs soon after formation of marine organic matter, or that transported material contains negligible amounts of alkenones. An isotopic mass balance calculation based on radiocarbon concentrations of co-occurring sediment components leads us to estimate that transported sediment components contain up to 12% of fossil organic matter that is free of or very poor in alkenones, but nevertheless appears to consist of a mixture of fresh and eroded fossil material. Considering all available constraints to characterize transported material, our results show that although focussing factors calculated from bulk sediment ²³⁰Th_xs inventories may allow useful approximations of bulk redeposition, they do not provide a unique estimate of the amount of each laterally transported sediment component. Furthermore, our findings provide evidence that the occurrence of lateral sediment redistribution alone does not always hinder the use of multiple proxies but that individual sediment fractions are affected to variable extents by sediment focussing.     

Trial by Fire: natural hazards,mixed-methods and cultural research

This paper considers the issues of research ‘relevance’ and ‘use’ to reflect upon a cultural geography research project on bushfire that did not begin with any specific aim of being useful to policy makers but which has garnered considerable and ongoing interest from a broad audience. It provides an example of how the integration of quantitative and qualitative research methods and data can enhance research into cultural aspects of natural hazards whilst simultaneously playing a key role in ensuring that the research results are of interest to a wide range of groups. Using a mixed-methods research approach was found to provide insight into complex factors that influence attitudes and actions towards bushfire amongst diverse landholders in rural–urban interface areas in south-east Australia. We argue that mixed-methods research is a powerful tool in building and enhancing a cultural geography that has policy relevance, retains analytical depth, and is acceptable to risk managers. The ability of cultural geography through mixed-methods research to illuminate how socio-cultural processes are central to environmental attitudes and preparedness behaviour has direct relevance to recent international discussions of how to manage the vulnerability of the growing number of people living in bushfire-prone rural–urban interface areas.     

The effect of hedgerow wild-margins on topsoil hydraulic properties,and overland-flow incidence,magnitude and water-quality

Overland and shallow-subsurface flows from agricultural catchments are believed to contribute towards flood-risk and water-quality degradation across the globe. Hedgerows are commonplace agricultural features that may disrupt these rapid hydrological pathways. Research into the hydrological functioning of hedgerows is very limited however, with no field-based quantitative comparison of overland-flows within hedgerows versus other land-uses. This research is the first globally to observe changes in overland-flow incidence, volume and water-quality, alongside topsoil hydraulic and physico-chemical properties, induced by a hedgerow and adjoining wild-margin within a grassland landscape. Observations were conducted within two replicated paired-plots between a hedgerow wild-margin and a bordering pasture, within Cumbria, UK. Compared to adjacent pasture, hedge-margins significantly reduced topsoil dry bulk-density and increased porosity, and significantly increased the topsoil median permeability by a factor of 22–27. Overland-flow models, based on direct observations, highlight that hedge-margins are slower to produce overland-flows than pastures, requiring an equal or greater amount of saturation before the onset of overland-flow generation. Hedge-margins resultantly produced less overland-flow volume, likely due to increased infiltration, percolation and/or evapotranspiration. Soil saturation models, also based on direct observations, confirm pastures saturate faster than hedge-margins, with hedge-margins having extremely variable dynamics in relation to precipitation, whereas pastures have more moderate and consistent dynamics. Overland-flow water-quality from ‘wash-off’ experiments highlight that hedge-margins may store substantially more nitrate (70–260%), nitrate-nitrite (640–650%), and loose sediment (540–3970%) on the ground surface compared to pastures; although further experimentation is needed to determine contaminant mobilization potential.     

A threatened world city: the benefits of protecting London from the sea

This paper describes the options appraisal undertaken in the UK within the major TE2100 project to investigate the future of protecting London from flooding from the sea. An economic analysis, within a Benefit-Cost framework complemented by Multi-Criteria Analysis, shows that improving the existing flood defences and, in 2070, constructing a new Thames Barrier downstream from the existing one are the “front runner” options for tackling the increase in flood risk that is anticipated in the future. Both sensitivity and scenario analysis have little effect on option choice. Uncertainties inevitably remain, however, when looking so far ahead, but it is clear that continuing to protect this area from the sea is highly cost-beneficial. Also the very high standard of protection now, and the robustness of the existing flood defence assets, mean that major new interventions will not be needed for some time (i.e. until c. 2070). We therefore have time to monitor the situation, carefully plan measures to maintain and enhance the existing defences, and to seek to restrain the growth of risk in the Estuary and in London through carefully designed and implemented resilience-building flood plain management measures. Rather than having to rush to new engineering works, because we have not anticipated what is needed but are forced to respond hastily to a “crisis” situation, the adaptive approach that is now possible is a key legacy of the TE2100 project.     

A discrete Bayesian network to investigate suspended sediment concentrations in an Alpine proglacial zone

In this study, a Bayesian Network (BN) is used to model the suspended sediment concentrations (SSC) in the catchments of the glaciers Noir and Blanc in the Ecrins National Park, France, and at the distal end of the proglacial zone into which both torrents drain. Relationships between air temperature, glacier discharge and SSC are represented as random variables; thereby taking the natural next step from proposed modified rating curve methods which increasingly approximate random variable approaches. Hydrological relationships are propagated through the network via conditional probability distributions computed from 980 field records obtained at three monitoring sites during July 2005. Rainfall affected data are removed from the modelling process. A two‐sample Kolmogorov–Smirnov goodness‐of‐fit (two‐sample KS) test (n = 5) shows good agreement between the probability distributions of SSC predicted by the BN, and those recorded in the field at the outflow of the proglacial zone over an air temperature range of 5–25 °C. The BN performs poorly for air temperatures between 25 and 30 °C and this is attributed to limited field records covering this temperature range. Discussion of the significant limitations surrounding the widespread application of BNs in hydrological modelling are offered with a focus on data volume and temporal limitations. Copyright © 2008 John Wiley & Sons, Ltd.     

Granites are not diapiric!

How are granite magmas transported from their source regions in the deep crust, through 10–40 km of overlying solid rock and emplaced close to the Earth's surface? What are the mechanical processes that allow this to take place and how long does it all take? These problems have challenged and preoccupied geologists since the days of Hutton. In the ensuing 200 years or so, a range of ideas from the plausible to the eccentric have been put forward to explain the granite phenomenon. As a result of developments in our understanding of the physical behaviour of granitic magmas and their host rocks over the last decade, we are now in a position to begin to offer some more informed and realistic models of the processes involved.