The use of echelle gratings in single-pass spectrometers

Tests of the performance of replicas of the latest echelle gratings are reported.     

High‐resolution seismic reflection profiling of neotectonic faults in Lake Timiskaming,Timiskaming Graben,Ontario‐Quebec,Canada

The Timiskaming Graben is a 400 km long, 50 km wide north‐west trending morphotectonic depression within the Canadian Shield of eastern North America and experiences frequent intraplate earthquakes. The graben extends along the border of Ontario and Quebec, connecting southward with the Nipissing and Ottawa‐Bonnechere grabens and the St. Lawrence Rift System which includes a similar structure underlying the Hudson Valley of the eastern USA. Together they form a complex failed rift system related to regional extension of North American crust during the breakup of Rodinia and, later, Pangea. The Timiskaming Graben lies within a belt of heightened seismic activity (Western Quebec Seismic Zone) with frequent moderate magnitude (greater than magnitude 5) earthquakes including a magnitude 6.2 in 1935. These events threaten aging urban infrastructure built on soft glacial sediments; post‐glacial landslides along the Ottawa Valley suggest earthquakes as large as magnitude 7. The inner part of the Timiskaming Graben is filled by Lake Timiskaming, a large 110 km long post‐glacial successor to glacial Lake Barlow that was ponded by the Laurentide Ice Sheet 9500 years ago. The effects of frequent ground shaking on lake floor sediments was assessed by collecting more than 1000 line kilometres of high‐resolution ‘chirp’ seismic profiles. Late glacial Lake Barlow glaciolacustrine and overlying post‐glacial sediments are extensively deformed by extensional faults that define prominent horsts and grabens; multibeam bathymetry data suggest that faults influence the morphology of the modern lake floor, despite high sedimentation rates, and indicate recent neotectonic deformation. The Lake Timiskaming area provides evidence of post‐glacial intracratonic faulting related to recurring earthquake activity along a weak spot within the North American plate.     

A preliminary methods comparison for measurement of dissolved organic nitrogen in seawater

Routine determination of dissolved organic nitrogen (DON) is performed in numerous laboratories around the world using one of three families of methods: UV oxidation (UV), persulfate oxidation (PO), or high temperature combustion (HTC). Essentially all routine methods measure total dissolved nitrogen (TDN) and calculate DON by subtracting the dissolved inorganic nitrogen (DIN). While there is currently no strong suggestion that any of these methods is inadequate, there are continuing suspicions of slight inaccuracy by UV methods.This is a report of a broad community methods comparison where 29 sets (7 UV, 13 PO, and 9 HTC) of TDN analyses were performed on five samples with varying TDN and DIN concentrations. Analyses were done in a “blind” procedure with results sent to the first author. With editing out one set of extreme outliers (representing 5 out of 145 ampoules analyzed), the community comparability for analyzing the TDN samples was in the 8–28% range (coefficient of variation representing one standard deviation for the five individual samples by 28 analyses). When DIN concentrations were subtracted uniformly (single DIN value for each sample), the comparability was obviously worse (19–46% cv). This comparison represents a larger and more diverse set of analyses, but the overall comparability is only marginally better than that of the Seattle workshop of a decade ago. Grouping methods, little difference was seen other than inconclusive evidence that the UV methods gave TDN values for several of the samples higher than HTC methods. Since there was much scatter for each of the groups of methods and for all analyses when grouped, it is thought that more uniformity in procedures is probably needed. An important unplanned observation is that variability in DIN analyses (used in determining the final analyte in most UV and PO methods) is essentially as large as the variability in the TDN analyses.This exercise should not be viewed as a qualification exercise for the analysts, but should instead be considered a broad preliminary test of the comparison of the families of methods being used in various laboratories around the world. Based on many independent analyses here, none of the routinely used methods appears to be grossly inaccurate, thus, most routine TDN analyses being reported in the literature are apparently accurate. However, it is not reassuring that the ability of the international community to determine DON in deep oceanic waters continues to be poor. It is suggested that as an outgrowth of this paper, analysts using UV and PO methods experiment and look more carefully at the completeness of DIN conversion to the final analyte and also at the accuracy of their analysis of the final analyte. HTC methods appear to be relatively easy and convenient and have potential for routine adoption. Several of the authors of this paper are currently working together on an interlaboratory comparison on HTC methodology.     

The effects of humic substances on the transport of radionuclides: Recent improvements in the prediction of behaviour and the understanding of mechanisms

Some recent developments made during the European Union 6th Framework Integrated Project FUNMIG in the understanding and prediction of behaviour in ternary systems of radionuclides, humic substances and mineral surfaces are described. These developments are placed in the context of the existing literature. The aim is to describe the current understanding of humic substance mediated radionuclide transport as it may be applied to calculations in support of Radiological Performance Assessment. Some improvements in experimental techniques that provide the raw data to calibrate metal ion binding models are explained. The various metal ion binding models that are available are described and contrasted, before the recent development of ternary system models, in particular the Ligand Charge Distribution model that can predict metal ion and humic substance behaviour in ternary systems. The kinetic effects in ternary systems are described along with the models that are used to describe them. Finally, the remaining challenges in making predictions of radionuclide transport for the Radiological Performance Assessment of radioactive waste repositories are discussed.     

Seasonal Rainfall Forecasts for the Yangtze River Basin in the Extreme Summer of 2020※

Seasonal forecasts for Yangtze River basin rainfall in June, May–June–July (MJJ), and June–July–August (JJA) 2020 are presented, based on the Met Office GloSea5 system. The three-month forecasts are based on dynamical predictions of an East Asian Summer Monsoon (EASM) index, which is transformed into regional-mean rainfall through linear regression. The June rainfall forecasts for the middle/lower Yangtze River basin are based on linear regression of precipitation. The forecasts verify well in terms of giving strong, consistent predictions of above-average rainfall at lead times of at least three months. However, the Yangtze region was subject to exceptionally heavy rainfall throughout the summer period, leading to observed values that lie outside the 95％ prediction intervals of the three-month forecasts. The forecasts presented here are consistent with other studies of the 2020 EASM rainfall, whereby the enhanced mei-yu front in early summer is skillfully forecast, but the impact of midlatitude drivers enhancing the rainfall in later summer is not captured. This case study demonstrates both the utility of probabilistic seasonal forecasts for the Yangtze region and the potential limitations in anticipating complex extreme events driven by a combination of coincident factors.     

Assessing the significance of wet-canopy evaporation from forests during extreme rainfall events for flood mitigation in mountainous regions of the United Kingdom

There is increased interest in the potential of tree planting to help mitigate flooding using nature-based solutions or natural flood management. However, many publications based upon catchment studies conclude that, as flood magnitude increases, benefit from forest cover declines and is insignificant for extreme flood events. These conclusions conflict with estimates of evaporation loss from forest plot observations of gross rainfall, through fall and stem flow. This study explores data from existing studies to assess the magnitudes of evaporation and attempts to identify the meteorological conditions under which they would be supported. This is achieved using rainfall event data collated from publications and data archives from studies undertaken in temperate environments around the world. The meteorological conditions required to drive the observed evaporation losses are explored theoretically using the Penman–Monteith equation. The results of this theoretical analysis are compared with the prevailing meteorological conditions during large and extreme rainfall events in mountainous regions of the United Kingdom to assess the likely significance of wet canopy evaporation loss. The collated dataset showed that event Ewc losses between approximately 2 and 38% of gross rainfall (1.5 to 39.4 mm day⁻¹) have been observed during large rainfall events (up to 118 mm day⁻¹) and that there are few data for extreme events (>150 mm day⁻¹). Event data greater than 150 mm (reported separately) included similarly high percentage evaporation losses. Theoretical estimates of wet-canopy evaporation indicated that, to reproduce the losses towards the high end of these observations, relative humidity and the aerodynamic resistance for vapour transport needed to be lower than approximately 97.5% and 0.5 to 2 s m⁻¹ respectively. Surface meteorological data during large and extreme rainfall events in the United Kingdom suggest that conditions favourable for high wet-canopy evaporation are not uncommon and indicate that significant evaporation losses during large and extreme events are possible but not for all events and not at all locations. Thus the disparity with the results from catchment studies remains.     

Groundwater flow through Pleistocene glacial deposits in the rapidly urbanizing Rouge River–Highland Creek watershed,City of Scarborough,southern Ontario,Canada

The city of Scarborough lies on the eastern margin of the Greater Toronto Area of southern Ontario, Canada, along the northern coastline of Lake Ontario. The City has a population of 500,000 and is presently one of the fastest growing communities in Canada. The City is expanding northwards onto rural land on the south slope of the large Pleistocene glacial Oak Ridges Moraine system. The moraine system is underlain by a thick (150 m) succession of tills, sands and gravels and is a regionally-significant recharge area for three principle aquifer systems that discharge to numerous watercourses that flow to Lake Ontario. Protection of deeper aquifers from surface-generated urban contaminants is a particular concern. A groundwater flow model using Visual MODFLOW was developed for the 350-km² Rouge River–Highland Creek (RRHC) drainage basin using an extensive GIS-based collection of subsurface geological, geophysical and hydrogeological data, maps of land use and surficial geology. The RRHC model was calibrated against point water level data, known potentiometric surfaces of the principal aquifers and baseflow measurements from streamflow gauging stations and determined to be within acceptable limits. Water balance calculations indicate that 70% of the basin recharge (106,000 m³/day) enters the Upper Aquifer along the crest and immediate flanks of the Oak Ridges Moraine. To the south, Upper Aquifer water moving through fractured till aquitards accounts for more than 75% of recharge to deeper aquifers. Water quality data confirm previous observations that urban- and rural-sourced contaminants (chlorides and nitrates) present in Upper Aquifer waters are moving rapidly into deeper aquifers. Some 83% of total RRHC recharge water is ultimately discharged as baseflow to creeks draining to Lake Ontario; the remainder discharges to springs and along eroding lakeshore bluffs. Model results demonstrate that deeper aquifers are poorly protected from urban contaminants and that long-term protection of ground and surface water quality has to be a priority of municipal planners if the resource is not to be severely degraded. Electronic Publication     

Using fine‐scale catch predictions to examine spatial variation in growth and catchability of Panulirus cygnus along the west coast of Australia

Puerulus settlement has been monitored throughout the western rock lobster Panulirus cygnus fishery for nearly 40 years. These data, in combination with indices of effort and water temperature, were used to produce recruitment‐catch relationships for each 1° transect of latitude in the coastal part of this fishery from Kalbarri to Cape Leeuwin, as well as at the offshore Abrolhos Islands (total of eight transects). The fine spatial scales of these models provided estimates of certain life history traits that are known to affect lobster catches between adjacent fishing ports. This catch modelling showed that the proportions of 3‐ and 4‐year‐old post‐settlement lobsters contributing to the catches varied markedly from the southern to northern transects, suggesting that juvenile lobsters grow substantially faster in the warmer northern and offshore waters of this fishery. These proportions provide accurate estimates of juvenile growth rates, which are vital in the construction of location‐specific growth algorithms required by the age‐structured models used in the management of this fishery. Model estimates of density‐dependent mortality were greater in the more densely populated centre of the fishery and markedly lower at the northern and southern limits of this species distribution. Annual increases in fishing efficiency were also found to be lowest at the northern and southern extremes of the fishery and greatest in the centre of the fishery, where technology advances and increased fleet mobility have enabled the fleet to increase efficiency by 1–3% each year. Catchability (q) was found to be most influenced by water temperatures in the cooler southern transects, whereas at the Abrolhos Islands, changes in water temperature produced almost no discernable change in q. The catch modelling was also used to quantify the impact of management changes introduced in the 1993/94 fishing season. Increased protection of female lobsters and an 18% pot reduction resulted in a 3–4% permanent reduction in the catch rates of lobsters throughout most of the coastal fishery, whereas at the offshore Abrolhos Islands, catch rates increased by c. 20%, presumably owing to a reduction in the level of pot saturation.     

Spectroscopic surveys of cosmic evolution

ALMA will be the premier instrument for the study of galaxy evolution in the early universe—enabling studies of the gas content, dynamics and dynamical masses, and star formation with unparalleled resolution and sensitivity. Galaxy evolution and AGN growth in the early universe are believed to be strongly driven by merging and dynamical interactions. Thus, a full exploration of the environmental influence is absolutely essential. The Cosmic Evolution Survey (COSMOS) is specifically designed to probe the correlated coevolution of galaxies, star formation, active galactic nuclei (AGN) and dark matter (DM) large-scale structure (LSS) over the redshift range z>0.5 to 3. In this contribution I review the characteristics of the COSMOS survey and very exciting initial results on mapping large scale structure in galaxies and dark matter. The survey includes multi-wavelength imaging and spectroscopy from X-ray to radio wavelengths covering a 2 square degree equatorial field. Given the very high sensitivity and resolution of these datasets, COSMOS will provide unprecedented samples of objects at z>3 for followup studies wit ALMA.