X射线衍射技术应用于宝石鉴定-合成及晶体结构研究进展

因宝石检测常附带无损要求、宝石评价具科学性和不确定性等特点,X射线衍射(XRD)在宝石学这门矿物学的分支学科中的应用具有特殊性,其应用领域主要集中在三个方面。①宝石鉴定领域:对单晶宝石和多晶宝石进行物相鉴定、宝石产地特征研究以及宝石矿物多型的种类划分等。例如根据XRD图谱,可将品种繁多的微晶石英隐晶质变种玉髓中不同的SiO₂质矿物相精确区分;通过黏土矿物成分及其含量可将鸡血石中"地"的种类进行划分。②宝石矿物的晶体结构研究:对成分复杂的单晶宝石进行晶体化学分析、获取矿物类质同象替代情况、利用结晶度划分宝石品质。例如晶格参数中的c/a比值可将绿柱石的Al八面体类质同象替代和Be四面体类质同象替代进行区分;软玉中通过XRD数据计算出的结晶度与软玉的品质关系密切。③宝石学研究技术的开发:对宝石的优化处理过程进行监测,在宝石合成过程中检验矿物晶形大小、结晶质量及内应力等,以有机宝石的晶体结构为基础的人工养殖技术研究。例如尖晶石在热处理过程中,Mg离子由四面体中的T位迁移至八面体中的M位,导致M-O和T-O键长随温度变化,并反映在尖晶石的色调中;在托帕石合成过程中,XRD数据显示770~800℃时形成含氟托帕石(与天然托帕石结构相同),而在950℃和1000℃出现含氟托帕石离解成刚玉和莫来石。目前,我国在宝石学的XRD应用方面起步较晚,国外在宝石鉴定、优化与合成方面的应用相对成熟。本文认为,该技术与扫描电镜、质子探针等分析技术的联用仍有很大发展空间。     

准噶尔盆地油气源、油气分布与油气系统

准噶尔盆地是中国西部典型的多旋回叠合盆地,发育有石炭系、二叠系、三叠系、侏罗系、白垩系和古近系6套烃源岩,同时存在6大类原油和3大类天然气,广泛分布于盆地不同地区。西北缘原油总体相似,碳同位素组成轻(δ~(13)C-29‰),胡萝卜烷、类异戊二烯烷烃、三环萜烷、伽马蜡烷丰富,甾烷以C_(28)、C_(29)为主,基本没有重排甾烷,为第二类原油,来源于二叠系湖相烃源岩。腹部绝大多数原油与西北缘原油相似,但胡萝卜烷、类异戊二烯烷烃、伽马蜡烷等有差异,来源于不同凹陷的二叠系湖相烃源岩;少量原油碳同位素组成重(δ~(13)C-28‰~-26‰),Pr/Ph大于2.5,三环萜烷以C_(19)、C_(20)为主,藿烷丰富而伽马蜡烷极低,以C_(29)规则甾烷及重排甾烷为主,为第四类原油,来源于侏罗系煤系烃源岩。东部存在5种类型原油,第一类原油碳同位素组成特别重(δ~(13)C-26‰),来源于石炭系烃源岩;第二类原油与腹部地区绝大多数原油十分相似,来源于二叠系湖相烃源岩;第三类原油碳同位索组成轻,重排甾烷、Ts、C_(29)Ts及C_(30)重排藿烷异常丰富,来源于中上三叠统湖相烃源岩;第四类原油源于侏罗系煤系烃源岩;混合类原油为二叠系、三叠系、侏罗系原油的混合,各自贡献平均分别为20%、15%和65%。南缘存在4类典型原油,为第二、第四、第五和第六类原油,其中第二、第四类分别源于二叠系和侏罗系;第五类原油碳同位素组成轻(δ~(13)C-29‰)、Pr/Ph1.0、伽马蜡烷丰富且有两个异构体、Ts、C_(29)Ts、C_(30)重排藿烷、C_(27)~C_(29)异胆甾烷及C_(30)甲基甾烷丰富,来源于白垩系湖相烃源岩;第六类原油主要为中低成熟原油,碳同位素组成δ~(13)C~28‰~-26‰,C_(27)、C_(28)、C_(29)甾烷呈"V"型分布,甲藻甾烷异常丰富,来源于古近系湖相烃源岩。准噶尔盆地天然气有油型气、混合气和煤型气,前两类主要来源于二叠系湖相烃源岩和石炭系海相烃源岩,煤型气主要来源于石炭系和侏罗系煤系烃源岩。不同类型油气分布与不同时代烃源灶具有良好对应关系:石炭系油气主要分布于陆东-五彩湾;二叠系油气主要分布于西北缘、腹部与东部;三叠系原油仅分布于东部;侏罗系原油主要分布于东部与南部;白垩系原油仅分布于南缘中部;古近系原油仅分布于南缘西部。按照盆地构造特征及不同时代烃源灶与油气关系,将准噶尔盆地划分为西部、中部、东部、南部及乌伦古5个油气系统及15个子油气系统。     

Curve matching approaches to waveform classification: a case study using ICESat data

Light Detection and Ranging (LiDAR) waveforms are being increasingly used in many forest and urban applications, especially for ground feature classification. However, most studies relied on either discretizing waveforms to multiple returns or extracting shape metrics from waveforms. The direct use of the full waveform, which contains the most comprehensive and accurate information has been scarcely explored. We proposed to utilize the complete waveform to test its ability to differentiate between objects having distinct vertical structures using curve matching approaches. Two groups of curve matching approaches were developed by extending methods originally designed for pixel-based hyperspectral image classification and object-based high spatial image classification. The first group is based on measuring the curve similarity between an unknown waveform and a reference waveform, including curve root sum squared differential area (CRSSDA), curve angle mapper (CAM), and Kullback–Leibler (KL) divergence. The second group assesses the curve similarity between an unknown and reference cumulative distribution functions (CDFs) of their waveforms, including cumulative curve root sum squared differential area (CCRSSDA), cumulative curve angle mapper (CCAM), and Kolmogorov–Smirnov (KS) distance. When employed to classify open space, trees, and buildings using ICESat waveform data, KL provided the highest average classification accuracy (87%), closely followed by CCRSSDA and CCAM, and they all significantly outperformed KS, CRSSDA, and CAM based on 15 randomized sample sets.     

高阶边界元方法求解规则波在三维局部渗透海床上的传播

基于线性势流理论,利用高阶边界元法研究了规则波在三维局部渗透海床上的传播。根据Darcy渗透定律推导出渗透海床的控制方程,利用渗透海床顶部和海底处法向速度和压强连续条件得到渗透海床顶部满足的边界条件。根据绕射理论,利用满足自由水面条件的格林函数建立了求解渗透海床绕射势的边界积分方程,采用高阶边界元方法求解边界积分方程进而得到自由水面的绕射势和波浪在局部渗透海床上传播过程中幅值的变化情况。通过与已发表的波浪对圆柱形暗礁的时域全绕射结果对比,证明了本文建立的频域方法计算波幅的正确性和有效性。利用这一模型研究了三维矩形渗透海床区域上波浪的传播特性,并分析了入射波波长、海床渗透特性系数等参数对波浪传播的影响。     

Comparison of single- and dual-permeability models in simulating the unsaturated hydro-mechanical behavior in a rainfall-triggered landslide

Landslide-prone slopes in earthquake-affected areas commonly feature heterogeneity and high permeability due to the presence of cracks and fissures that were caused by ground shaking. Landslide reactivation in heterogeneous slope may be affected by preferential flow that was commonly occurred under heavy rainfall. Current hydro-mechanical models that are based on a single-permeability model consider soil as a homogeneous continuum, which, however, cannot explicitly represent the hydraulic properties of heterogeneous soil. The present study adopted a dual-permeability model, using two Darcy-Richards equations to simulate the infiltration processes in both matrix and preferential flow domains. The hydrological results were integrated with an infinite slope stability approach, attempting to investigate the hydro-mechanical behavior. A coarse-textured unstable slope in an earthquake-affected area was chosen for conducting artificial rainfall experiment, and in the experiment slope, failure was triggered several times under heavy rainfall. The simulated hydro-mechanical results of both single- and dual-permeability model were compared with the measurements, including soil moisture content, pore water pressure, and slope stability conditions. Under high-intensity rainfall, the measured soil moisture and pore water pressure at 1-m depth showed faster hydrological response than its simulations, which can be regarded as a typical evidence of preferential flow. We found the dual-permeability model substantially improved the quantification of hydro-mechanical processes. Such improvement could assist in obtaining more reliable landslide-triggering predication. In the light of the implementation of a dual-permeability model for slope stability analysis, a more flexible and robust early warning system for shallow landslides hazard in coarse-textured slopes could be provided.     

基于MODIS数据的青藏高原冰川反照率时空分布及变化研究

冰川反照率对冰川融化具有重要影响,以2000-2013年MODIS的MOD10A1逐日积雪反照率数据资料为基础,分析了青藏高原冰川反照率的时空分布及变化。结果表明：冰川年平均反照率变化范围是0.42（枪勇冰川）~0.75（PT5冰川）,其中夏季平均反照率变化范围是0.45（来古冰川）~0.69（东绒布冰川和古里雅冰川）。冰川反照率空间分布并没有明显的规律性,而冰川反照率的变化速率空间分布规律明显——南部较大往北减小,北部反照率出现增大现象。研究区内大部分冰川反照率呈波动降低的趋势,年平均反照率和夏季平均反照率变化速率最大值都出现在枪勇冰川,分别是-0.015 a^-1和-0.019 a^-1。木吉和木孜塔格冰川年平均和夏季平均冰川反照率都增大,木吉冰川是由于2012年的高反照率引起的,而木孜塔格冰川主要与该地区气温降低、降水增多有关。     

克拉玛依地区野外地质实习基地建设研究

野外实践教学在地学人才培养中具有重要作用,稳定的实习基地是开展实践教学的前提和基础。克拉玛依所处的准噶尔盆地西北缘地区位于哈萨克斯坦、塔里木与西伯利亚三大板块的交汇处,自晚古生代以来经历了多期次、多阶段长期而复杂的地质演化,褶皱构造、大型纵向走滑断裂构造发育,广泛发育晚古生代花岗岩侵入体和蛇绿混杂岩带,沉积地层连续、完整,沉积构造典型、特征显著,古生物化石丰富,白杨河深切峡谷、河流阶地地貌以及乌尔禾魔鬼城雅丹风蚀地貌各具特色,西北缘油砂矿、紫砂矿、金丝玉等矿藏储量丰富。区域内的地层、古生物、构造、地貌、矿产资源等为克拉玛依工程教育基地各院校的地学类相关专业的野外实践教学提供了丰富的教学资源,是一个理想的野外地质实习基地。     

顾及邻近点变形因素的高斯过程建模及预测

针对传统的变形监测建模方法一般针对单一监测点的变形预测模型,未考虑到监测点间相互作用的变形特点,该文分析了变形监测点间的相互关联性,通过相关系数法对监测点进行分类,并将邻近监测点的观测序列值作为和时间因素等同的影响因子应用到建模过程中,利用高斯过程算法进行训练,建立预测模型。为提高高斯过程算法的模型预测精度,应选择适合工程案例最优协方差函数。通过实例分析,比较GM(1,1)、多点灰色预测模型和顾及邻近点变形因素的高斯过程等3种模型在基坑围岩、滑坡等变形监测数据处理中的预测精度,表明该文算法考虑到监测点间的变形关联性,充分利用高斯过程在针对小样本、非线性数据建模时的高自适应性等优点,具有较高的预测精度。     

Monotonic and cyclic characteristics of K0-Consolidated saturated soft clay under a stress path involving a variable confining pressure

In certain field conditions such as offshore projects under wave loads or embankments under traffic loads, both the vertical and horizontal stresses are variable. However, previous investigations rarely considered the variation in horizontal stress. To better understand the characteristics of natural saturated soft clay, a series of monotonic and cyclic triaxial tests with a K₀-consolidation state were carried out under a variable confining pressure (VCP) stress path. The development of axial strain, pore water pressure and effective stress path is analysed. The results show that with the increase in η (the ratio of the variation in the mean effective principal stress to that of the deviatoric stress), the undrained shear strength (q_f) decreases continuously. The pore water pressure generation is slightly improved under a stress path with increasing confining pressure. Based on the test results, a unified formula was established to predict the pore water pressure under VCP stress paths. The unique p–q–e relationship of normally consolidated clay in monotonic VCP triaxial tests was also demonstrated. Under VCP stress paths, the amplitude of the pore pressure increases, and the effective stress path tilts more sharply to the right. Moreover, a unified formula was established that can provide a good reference for predicting effective stress paths under cyclic VCP triaxial tests.