Migration and enrichment of trace elements of Lower Palaeozoic carbonate rock strata in Beijing

Analyses of trace elements of the Lower Palaeozoic carbonate rock strata in Beijing show that the contents of As, Hg, F increase from primary carbonate rocks to weathered carbonate rocks and from primary carbonate rocks to the soil coexisting with carbonate rocks, but the distribution regularity of S is not obvious. In the whole weathered stages, the sorption of As is mainly affected by Fe2O3. In soil Fe2O3 is also the main affecting factor of Hg enrichment. The main existing forms of Hg in primary carbonate rocks should simply be physical adsorption, coprecipitation and false isomorphous form between surface of carbonate rock and Hg. In soil the enrichment of F has little relationship with sul-fides and Fe2O3. In primary carbonate rocks, F is mainly absorbed by sulfides and clay minerals, etc. Weathered samples have closer genetic relationships with primary carbonate rocks. This also implies that weathered carbonate rocks have the close existing forms to that of primary carbonate rocks. In primary carbonate rocks FeS2 and FeS are the main forms of S, and sulfides have fixation effect on some heavy metals, whereas in weathered carbonate rocks and soil the fixation effect is weakened.     

陕西省能源消费结构、产业结构演变对碳排放强度的冲击影响分析

基于陕西省1989-2011年能源消费等统计数据,分析能源消费结构、产业结构的演变特征,建立陕西省能源消费结构-产业结构-碳排放强度系统的VAR模型,对该系统的长期和短期动态关系进行实证分析。结果表明:陕西省的发展模式,是能源消费结构长期以高碳能源为主和产业结构长期以高碳产业为主导。能源消费结构与产业结构的变化对陕西省碳排放强度的减小作用初期微弱;从中长期来,两个结构多元化提高的负效应对碳排放强度的增加有长期持久的抑制作用,且能源消费结构演进对碳排放强度的冲击效果始终大于产业结构变化的冲击效果。优化产业结构和调整能源消费结构尤其是提高低碳产业与低碳能源比重是驱动陕西省碳排放强度下降的有效措施。     

Identification of the “source” and “sink” patterns influencing non-point source pollution in the Three Gorges Reservoir Area

Non-point source pollution is one of the primarily ecological issues affecting the Three Gorges Reservoir Area. In this paper, landscape resistance and motivation coefficient, which integrated various landscape elements, such as land use, soil, hydrology, topography, and vegetation, was established based on the effects of large-scale resistance and motivation on the formation of non-point source pollution. In addition, cost models of the landscape resistance and motivation coefficients were constructed based on the distances from the landscape units to the sub-basin outlets in order to identify the “source” and “sink” patterns affecting the formation of non-point source pollution. The results indicated that the changes in the landscape resistance and motivation coefficients of the 16 sub-basins exhibited inverse relationships to their spatial distributions. The landscape resistance and motivation cost curves were more volatile than the landscape resistance and motivation coefficient curves. The landscape resistance and motivation cost trends of the 16 sub-basins became increasingly apparent along the flow of the Yangtze River. The landscape resistance and motivation cost models proposed in this paper could be used to identify large-scale non-point source pollution “source” and “sink” patterns. Moreover, the proposed model could be used to describe the large-scale spatial characteristics of non-point source pollution formation based on “source” and “sink” landscape pattern indices, spatial localization, and landscape resistance and motivation coefficients.     

地理信息系统支持区域土地利用决策的研究

本文以江苏省溧阳县为例,研究地理信息系统技术在区域土地利用多目标规划中的应用,着重探讨地理信息系统支持的区域土地利用决策原理和方法。研究表明,在地理信息系统的支持下,通过单项适宜性评价模型和生产布局决策模型的建立与运行,可以有效地进行研究区合理的土地利用布局和为区域土地管理提供依据。     

准噶尔盆地油气源、油气分布与油气系统

准噶尔盆地是中国西部典型的多旋回叠合盆地,发育有石炭系、二叠系、三叠系、侏罗系、白垩系和古近系6套烃源岩,同时存在6大类原油和3大类天然气,广泛分布于盆地不同地区。西北缘原油总体相似,碳同位素组成轻(δ~(13)C-29‰),胡萝卜烷、类异戊二烯烷烃、三环萜烷、伽马蜡烷丰富,甾烷以C_(28)、C_(29)为主,基本没有重排甾烷,为第二类原油,来源于二叠系湖相烃源岩。腹部绝大多数原油与西北缘原油相似,但胡萝卜烷、类异戊二烯烷烃、伽马蜡烷等有差异,来源于不同凹陷的二叠系湖相烃源岩;少量原油碳同位素组成重(δ~(13)C-28‰~-26‰),Pr/Ph大于2.5,三环萜烷以C_(19)、C_(20)为主,藿烷丰富而伽马蜡烷极低,以C_(29)规则甾烷及重排甾烷为主,为第四类原油,来源于侏罗系煤系烃源岩。东部存在5种类型原油,第一类原油碳同位素组成特别重(δ~(13)C-26‰),来源于石炭系烃源岩;第二类原油与腹部地区绝大多数原油十分相似,来源于二叠系湖相烃源岩;第三类原油碳同位索组成轻,重排甾烷、Ts、C_(29)Ts及C_(30)重排藿烷异常丰富,来源于中上三叠统湖相烃源岩;第四类原油源于侏罗系煤系烃源岩;混合类原油为二叠系、三叠系、侏罗系原油的混合,各自贡献平均分别为20%、15%和65%。南缘存在4类典型原油,为第二、第四、第五和第六类原油,其中第二、第四类分别源于二叠系和侏罗系;第五类原油碳同位素组成轻(δ~(13)C-29‰)、Pr/Ph1.0、伽马蜡烷丰富且有两个异构体、Ts、C_(29)Ts、C_(30)重排藿烷、C_(27)~C_(29)异胆甾烷及C_(30)甲基甾烷丰富,来源于白垩系湖相烃源岩;第六类原油主要为中低成熟原油,碳同位素组成δ~(13)C~28‰~-26‰,C_(27)、C_(28)、C_(29)甾烷呈"V"型分布,甲藻甾烷异常丰富,来源于古近系湖相烃源岩。准噶尔盆地天然气有油型气、混合气和煤型气,前两类主要来源于二叠系湖相烃源岩和石炭系海相烃源岩,煤型气主要来源于石炭系和侏罗系煤系烃源岩。不同类型油气分布与不同时代烃源灶具有良好对应关系:石炭系油气主要分布于陆东-五彩湾;二叠系油气主要分布于西北缘、腹部与东部;三叠系原油仅分布于东部;侏罗系原油主要分布于东部与南部;白垩系原油仅分布于南缘中部;古近系原油仅分布于南缘西部。按照盆地构造特征及不同时代烃源灶与油气关系,将准噶尔盆地划分为西部、中部、东部、南部及乌伦古5个油气系统及15个子油气系统。     

渤海湾盆地北塘凹陷古近系湖相白云岩 地质特征及古环境意义

湖相白云岩是渤海湾盆地北塘凹陷古近系沙河街组三段发现的一种特殊油气储层类型。根据钻井岩心、古生物、薄 片、扫描电镜及电子探针等分析,确定了该套白云岩的主要岩石类型及矿物特征,并通过地球化学特征分析,对白云岩的 形成环境进行了探讨。北塘凹陷白云岩常与泥岩和方沸石岩呈互层状产出,其次为均匀块状;矿物成分主要有白云石、方 沸石、粘土矿物等。通过X射线衍射、主微量元素地球化学分析,对白云岩形成时的古盐度、古温度、水深、氧化还原条 件等进行了研究,认为研究区白云岩沉积于高盐度、较高水体温度和较高PH值的半咸水湖湾还原环境。海水的侵入使湖水 的含盐度增大,提供了有利的物理化学条件,促进了白云岩的形成。     

A multi-scale 3-D crust velocity model in the Hefei-Chao Lake area around the southern segment of Tanlu Fault Zone

Regional high-precision velocity models of the crust are an important foundation for examining seismic activity, seismogenic environments, and disaster distribution characteristics. The Hefei-Chao Lake area contains the main geological units of Hefei Basin, with thick sediments and the Chao Lake depression. Several major concealed faults of the southern NNE-trending Tanlu Fault Zone cross this area. To further explore the underground distribution characteristics of the faults and their tectonic evolutionary relationship with adjacent tectonic units, this study used ambient noise data recorded by a seismic array deployed in Hefei City and Chao Lake, constructing a 3-D velocity model at the depth of 1–8 km. Then a multi-scale high-resolution 3-D velocity model of this area was constructed by this new upper crustal velocity model with the previous middle and lower crustal model. The new model reveals that a high-velocity belt is highly consistent with the strike of the Tanlu Fault Zone, and a low-velocity sedimentary characteristic is consistent with the Hefei Basin and Chao Lake depression. The distribution morphology of high and low velocity bodies shows that the sedimentary pattern of Hefei-Chao Lake area is closely related to the tectonic evolution of the Tanlu Fault Zone since the Mesozoic. This study also identifies multiple low-velocity anomalies in the southeastern Hefei City. We speculate that strong ground motion during the 2009 Feidong earthquake (magnitude of 3.5) was related to amplification by the thick sediments in the Hefei Basin. We also discuss further applications of multi-scale high-resolution models of the shallow layer to strong ground motion simulations in cities and for earthquake disaster assessments.     

Magma underplating and Hannuoba present crust-mantle transitional zone composition: Xenolith petrological and geochemical evidence

Studies on the deep-seated xenoliths from global volcanoes reveal that the present petrological crust-mantle boundary between the lower crust and the upper mantle actually is a transitional layer from mainly mafic granulites to ultramafic spinel lher-zolites[1,2], i.e. a transitional zone distinctive from the seismological Moho[3]. Oceanic lithosphere crust- mantle transitional zone can be established from the study on the exposed ophiolites. However, as for the continental lithosphere, since …     

黄山东镁铁超镁铁杂岩中的辉石化学成分研究

通过对黄山东镁铁超镁铁杂岩的辉石化学成分研究，证明辉石的化学成分受寄主岩石类型的制约，从超镁铁岩相到角闪辉长岩相斜方辉石的化学成分由富ＭｇＯ、ＳｉＯ＿２、Ａｌ＿２Ｏ＿３、Ｃｒ＿２Ｏ＿３到富ＦｅＯ、ＴｉＯ＿２、ＣａＯ、ＭｎＯ；单斜辉石化学成分由富Ａｌ＿２Ｏ＿３、Ｃｒ＿２Ｏ＿３、Ｎａ＿２Ｏ、ＭｇＯ到富ＦｅＯ、ＭｎＯ、ＣｏＯ。在同一寄主岩石中，单斜辉石比斜方辉石富ＴｉＯ＿２、Ａｌ＿２Ｏ＿３、Ｃｒ＿２Ｏ＿３、ＣａＯ和Ｎａ＿２Ｏ，贫ＭｇＯ、ＳｉＯ＿２、ＭｎＯ和ＦｅＯ。根据辉石化学成分特征得出黄山东杂岩形成于岛弧环境，为上地幔石榴二辉檄榄岩部分熔融形成的拉斑玄武岩岩浆结晶分异作用的产物。     

疏浚粘土固结不排水应力-应变归一化特性分析

将疏浚粘土应力一应变关系与粘性土的含水率联系起来,对于实际工程而言具有很大的参考价值。传统重塑土应力一应变归一化特性的研究只是针对某一特定性质的土体而言,这种归一化的研究方法显然具有一定的局限性。采用归一化含水率w／wl作为归一化因子,对主应力差渐进值进行归一化．探讨了双对数坐标系下主应力差渐进值与w／wl的线性关系。在此基础上基于Konder提出的双曲线模型将主应力差渐进值作为归一化因子,对三种不同疏浚粘土的应力一应变特性进行归一化分析,通过与实验资料的对比表明,提出的方法具有很好的归一化效果。