11-deoxyheloside A的合成

首次完成天然胆甾烷型皂苷11-deoxyheloside A的合成。在相转移催化的条件下,葡萄糖溴苷1与膦酸单乙酯2反应以69%的收率得到葡萄糖膦酸酯供体3;以胆甾烷苷元4为原料,经Luche还原和乙酰化反应以及三氟甲磺酸负载硅胶脱除TBDPS基团得到胆甾烷二醇10;在金催化剂的作用下,胆甾二醇10与葡萄糖膦酸酯供体3进行糖苷化反应,然后脱除酰基保护基以97%的产率完成11-deoxyheloside A的合成。     

Petrogenesis of Potassic Basalts from Northeast China: New Constraints from Trace Elements in Olivine

<正>This study used trace elements in olivine as a new petrogenetic indicator to further constrain the petrogenesis of potassic basalts from the Erkeshan-Wudalianchi-KeluoXiaogulihe potassic volcanic field(EWKX for short)in the Songliao Basin of NE China,with a combination of the previous olivine and whole-rock geochemical data.We     

气候变化对阿拉善荒漠植被的影响研究

利用1982—2003年NASA GIMMS归一化植被指数(NDVI)数据集和阿拉善左旗、右旗和额济纳旗气温和降水资料,对阿拉善地区NDVI变化和气候变化特征及其相互关系进行了分析。结果表明：①1982—2003年东部地区(左旗植被指数略有增加,而中部(右旗)和西部地区(额济纳旗)则呈下降趋势。季节变化东、中、西部表现不同。左旗和额济纳旗多年平均NDVI的月变化和右旗相反。②东部地区升温率最大,其次是西部和中部地区。降水表现为东部和西部地区(额济纳旗)稍有增加,而中部地区(右旗)呈缓慢减少趋势。季节变化东、中、西部表现不同。多年平均气温和降水量的月变化趋势东、中、西部一致,呈单峰型曲线。③东部地区和中部地区,降水量与植被指数存在明显的年相关、隔季和当季相关,而西部地区额济纳旗没有明显的相关性。阿拉善地区NDVI同温度的相关性不好。     

Ab initio prediction of 29Si-NMR chemical shifts

The ability of several ab initio models to predict experimental ²⁹Si-NMR chemical shift is examined. The shielding values of trimethylsilyl chloride (A), t-butyldimethylsilyl chloride (B) and allytrimethylsilane (C) are calculated by GIAO, CSGT and IGAIM methods, using HF/6–31G^*, B3LYP/6-31G^*, HF/6–311+G^**, B3LYP/6–311+G^** and MPW1PW91/6–311+G^** models respectively. The ²⁹Si chemical shifts calculated by GIAO method using HF/6–311+G^** model are highly in agreement with those obtained experimentally. All of the models above reproduce the trends of chemical shifts in all cases studied, suggesting that the models are of practical value.     

桃花拉山一带遥感成矿环境浅析

本区位于龙首山山系西部,属甘肃省重要的铜、镍金属矿远景成矿带。利用大比例尺航天、航空像片及计算机功能处理片对桃花拉山一带地质构造作了详细解译,首次圈出青龙山菱块构造和环形构造,结合已有地质、矿产、物化探成果进行综合研究,提出了桃花拉山,青龙山遥感找矿模式,为开展矿产普查工作提供了有效地质信息。     

Lg amplitude ratios H/Z and station terms in the six eastern provinces of China

Using the data set of about 1 Hz Lg amplitudes from 80 stations in the six eastern provinces of China, the ratios of horizontal to vertical amplitude of Lg waves,H/Z are determined. The mean lg(H/Z)-value is equal to 0.13. For the station bases of soft deposit,granite and sedimentary rock, lg(H/Z)-values average 0.55, 0.04 and 0.10, respectively. For the three kinds of station bases, the station terms of horizontal amplitude,C _h average 0.65, −0.09 and 0.00; that of vertical amplitude,C _z average 0.32, −0.04 and 0.00, respectively. There are the relations betweenC _h ,C _z and lg(H/Z):C _h =0.01+2.10C _z andC _h =−0.15+1.46 lg(H/Z). The Chinese version of this paper appeared in the Chinese edition ofActa Seismologica Sinica,13, 281–286, 1991. Project sponsored by the Chinese Joint Seismological Science Foundation.     

DIAGNOSIS ON LOW FREQUENCY COMPONENT OF ENSO VARIABILITY—PART Ⅱ:ORIGIN OF THE COMPONENT

Diagnosis is undertaken on the origin for the low-frequency component (LFC) of ENSOvariability in the context of 1979—1990 OLR and u-wind datasets.Evidence suggests that ① apower spectrum-yielded maximum,significant statistically,is derived from the OLR monthlyanomalies in a 3—5-year period range over the tropical central/western Pacific;②compositeanalysis of the signals of the monthly anomaly low frequency component (period>3 years)confirms further the dynamic features of the component as documented in Part Ⅰ:③serving asforcing on ENSO,the related monsoon region represents the source area of the component;④theone-point correlation maps of unfiltered OLR monthly anomalies with zonal wind on a lagged,asimultaneous and a leading basis show clearly the close relation between the u wind-associatedeastward travelling low-frequency wave and the low-frequency oscillation of low-latitude central/western Pacific large-scale convection and the east-moving mode is likely to be excited by theoscillation at a 3—5-year period range.It follows that the large-scale convection oscillation showsup as the origin of the eastward waves,i.e.,ENSO LFC.     

沙漠绿洲多功能高分子植物生长调节剂籽瓜增产和品质改善研究

选择适合当地土壤和生态环境特点的优质高产籽瓜品种——新籽瓜1号,进行甘肃省武威市民勤沙漠绿洲多功能高分子植物生长调节剂籽瓜根部追施增产和品质改善试验研究。结果显示,施用产品不但有利于籽瓜的营养和生殖生长,增加瓜径3%~5%、提高产量11.5%,而且显著改善籽瓜的品质,提高其粗蛋白和维生素B1、B2含量,分别比对照增加1.80%和29.41%、14.29%,因而产生较好的经济效益,净增产值358.95~580.95元·hm-2。     

MODIS沙尘暴判识方法与业务系统

为了利用MODIS资料对沙尘暴的范围和强度进行定量判识,应用2002--2004年多次MODIS资料,通过对沙尘暴、云、雪和沙漠光谱特征的分析,构建了定量判识沙尘暴范围和强度的两个沙尘指数.利用2002-2007年数次沙尘暴过程对沙尘指数的判别效果进行检验,表明构建的两个M()DIS沙尘指数能够有效地监测沙尘暴的范围和强度,且方法简单,适用于业务应用.针对目前西北沙尘暴遥感监测业务服务以定性图像为主,服务产品较为单一的问题,对MODIS沙尘暴判识方法进行业务化,并结合GIS进行沙尘暴影响范围的分析,开发研制了自动运行的MODIS沙尘暴监测和影响评估业务系统.系统具生成沙尘暴MODIS影像图、沙尘暴范围和强度遥感监测图、沙尘暴影响土地类型图、全国各省(直辖市)沙尘面积统计表、全国不同土地类型沙尘暴影响面积统计表、甘肃省各县沙尘暴的影响面积统计表和甘肃省不同土地类型沙尘影响面积统计表等功能,为沙尘暴定量和精细服务提供了丰富的产品.