The assemblage stilpnomelane–chlorite–phengitic mica: a geothermobarometer for blueschist and associated greenschist terranes

Two anhydrous equilibria can be written among the components of stilpnomelane, chlorite, white mica and quartz, namely 89 daphnite+131 Fe-celadonite+190 quartz=96 stilpnomelane+71 muscovite, and amesite+Mg-celadonite=muscovite+clinochlore. We assume that the free energy change of reaction, ΔG=ΔG^o+ΣRT lna_i^j, is approximated by ΔG=A?BT +C(P?1)+ΣRT lna_i^j, where ΔG^o is the free energy change of the end-member components at temperature T and pressure P, a_i is the activity of component i whose coefficient in the equilibrium is j, and A, B and C are constants to be determined. Values of C can be approximated by the change in volume on reaction, namely C=406.517 J/bar for the first reaction and C=0.613 J/bar for the second reaction. Constants A and B were determined by using six occurrences of the assemblage stilpnomelane–chlorite–white mica for which P–T have been otherwise estimated. Using solution models from the literature, linear regression gives for the first equation A=?6118.269 kJ, B=?4584.09 J/K, and for the second equation A=19.397 kJ, B=66.72 J/K. These values predict P–T within 0.5 kbar and 25 K for all occurrences, and appear reasonably robust relative to probable analytical errors. P–T are determined by intersection of the curves generated by given compositions in P–T space. Fine-grained and/or zoned chlorite and white mica make application of the geothermobarometer difficult in some instances, but our work in the Bathurst region of New Brunswick suggests that, with patience and care, useful analyses can be obtained, and the database for the geothermobarometer greatly expanded.     

Peat bank growth,Holocene palaeoecology and climate history of South Georgia (sub-Antarctica), based on a botanical macrofossil record

Botanical macrofossil analysis of a more than 9000 years old, radiocarbon dated peat sequence of a moss peat bank from South Georgia, shows a clear evolution in the vegetation. Seven ecological phases could be distinguished and they can be interpreted in terms of climate development during the Holocene. Until 2200 years ago, Warnstorfia fontinaliopsis was the dominant moss species pointing to a wet environment. Lower numbers of this species in association with the presence of drier species are assumed to indicate drier periods, such as occurring between ca 6000–5200 and 4400–3400 cal yr BP. The most prominent and definitive vegetation change took place around 2200 cal yr BP. A Polytrichum–Chorisodontium moss peat bank was formed, which is still growing there today. The forcing mechanism for this vegetation change is thought to be a temperature decrease, rather than a precipitation decrease. This conclusion is mainly based on the fact that, today, moss peat banks have their optimal occurrence range in the maritime Antarctic, a region were the mean annual temperature is ca 4 °C lower than on South Georgia. The remarkable change in the moss bank vegetation at 2200 cal yr BP raises the question whether this moment was only a short climatic deterioration, or a definitive change to a cooler and wetter climate after a Holocene climatic optimum period.     

The variability of the large-amplitude internal wave field on the Australian North West Shelf

Observations are presented of large-amplitude internal waves (LAIWs) generated by the steepening of the internal tide on the Australian North West Shelf (NWS) over a 4-month period extending from strongly stratified summer conditions to weakly stratified winter conditions. The observations are from a site in water depth of 124 m where current and temperature measurements were made from a fixed vertical mooring and a benthic L-shaped spatial array. The observations show the LAIWs at this site to be characterized by strong seasonal variability, with energetic LAIWs of depression being dominant during summer and weaker LAIWs of elevation being dominant during the winter months as the stratification weakens, the upper mixed layer deepens, and the thermocline is close to the bottom. Waves were also seen to propagate from a range of directions towards the observation site. Modeling using the Regional Ocean Modeling System (ROMS v2.1) revealed that internal tide generation in the area occurred at water depths of between 400 and 600 m along an arc of approximately 120 km in length, some 70 km to the northwest of our experimental site. The results demonstrate both the 3D nature as well as the seasonal variation of the LAIW field.     

Non‐local damage modelling of concrete: a procedure for the determination of model parameters

This paper presents a procedure for the determination of parameters of non‐local damage models. This is to assure a consistent response of a non‐local damage model, as choice of the internal length and other parameters of the model are varied. Correlations between the internal length and other parameters governing the local constitutive behaviour of the model are addressed and exploited. Focus is put on the relationship between the internal length of the non‐local model and the width of the fracture process zone. Numerical examples are used to demonstrate the rigour of the proposed method. Copyright © 2006 John Wiley & Sons, Ltd.     

A study of surges and flares within an active region

Active region 2684 was observed by the Solar Maximum Mission and ground-based observatories simultaneously for over 12 hours on September 23, 1980. During these observations, recurrent surges were detected above an area with complex parasitic magnetic polarity located at the periphery of the active region. The time evolution of the H surges, Civ brightenings and X-ray spikes leads to the conclusion that the energy source is in the corona, from magnetic reconnection. The energy is transported by energetic charged particles along the loops, thereby heating the chromosphere as the particles lose their energy. The divergent motion of the spots corresponding to small dipoles at the base of the surge indicates that there is important magnetic reorganisation. According to the magnetic field-line configuration (large loop or open structures), X-rays can (or cannot) be associated with surges.     

Biogenic carbon flows through the planktonic food web of the Amundsen Gulf (Arctic Ocean): A synthesis of field measurements and inverse modeling analyses

Major pathways of biogenic carbon (C) flow are resolved for the planktonic food web of the flaw lead polynya system of the Amundsen Gulf (southeast Beaufort Sea, Arctic Ocean) in spring-summer 2008. This period was relevant to study the effect of climate change on Arctic marine ecosystems as it was characterized by unusually low ice cover and warm sea surface temperature. Our synthesis relied on a mass balance estimate of gross primary production (GPP) of 52.5 ± 12.5 g C m⁻² calculated using the drawdown of nitrate and dissolved inorganic C, and a seasonal f-ratio of 0.64. Based on chlorophyll a biomass, we estimated that GPP was dominated by phytoplankton (93.6%) over ice algae (6.4%) and by large cells (>5 μm, 67.6%) over small cells (<5 μm, 32.4%). Ancillary in situ data on bacterial production, zooplankton biomass and respiration, herbivory, bacterivory, vertical particle fluxes, pools of particulate and dissolved organic carbon (POC, DOC), net community production (NCP), as well as selected variables from the literature were used to evaluate the fate of size-fractionated GPP in the ecosystem. The structure and functioning of the planktonic food web was elucidated through inverse analysis using the mean GPP and the 95% confidence limits of every other field measurement as lower and upper constraints. The model computed a net primary production of 49.2 g C m⁻², which was directly channeled toward dominant calanoid copepods (i.e. Calanus hyperboreus 20%, Calanus glacialis 10%, and Metridia longa 10%), other mesozooplankton (12%), microzooplankton (14%), detrital POC (18%), and DOC (16%). Bacteria required 29.9 g C m⁻², a demand met entirely by the DOC derived from local biological activities. The ultimate C outflow comprised respiration fluxes (82% of the initial GPP), a small sedimentation (3%), and a modest residual C flow (15%) resulting from NCP, dilution and accumulation. The sinking C flux at the model limit depth (395 m) supplied 60% of the estimated benthic C demand (2.8 g C m⁻²), suggesting that the benthos relied partly on other C sources within the bottom boundary layer to fuel its activity. In summary, our results illustrate that the ongoing decline in Arctic sea ice promotes the growth of pelagic communities in the Amundsen Gulf, which benefited from a ∼80% increase in GPP in spring-summer 2008 when compared to 2004 – a year of average ice conditions and relatively low GPP. However, 53% of the secondary production was generated within the microbial food web, the net ecological efficiency of zooplankton populations was not particularly high (13.4%), and the quantity of biogenic C available for trophic export remained low (6.6 g C m⁻²). Hence it is unlikely that the increase in lower food web productivity, such as the one observed in our study, could support new harvestable fishery resources in the offshore Beaufort Sea domain.     

From water to tillage erosion dominated landform evolution

While water and wind erosion are still considered to be the dominant soil erosion processes on agricultural land, there is growing recognition that tillage erosion plays an important role in the redistribution of soil on agricultural land. In this study, we examined soil redistribution rates and patterns for an agricultural field in the Belgian loess belt. ¹³⁷Cs derived soil erosion rates have been confronted with historical patterns of soil erosion based on soil profile truncation. This allowed an assessment of historical and contemporary landform evolution on agricultural land and its interpretation in relation to the dominant geomorphic process. The results clearly show that an important shift in the relative contribution of tillage and water erosion to total soil redistribution on agricultural land has occurred during recent decades. Historical soil redistribution is dominated by high losses on steep midslope positions and concavities as a result of water erosion, leading to landscape incision and steepening of the topography. In contrast, contemporary soil redistribution is dominated by high losses on convex upperslopes and infilling of slope and valley concavities as a result of tillage, resulting in topographic flattening. This shift must be attributed to the increased mechanization of agriculture during recent decades. This study shows that the typical topographical dependency of soil redistribution processes and their spatial interactions must be accounted for when assessing landform and soil profile evolution.     

Thermochronological evidence for Mio‐Pliocene late orogenic extension in the north‐eastern Albanides (Albania)

New apatite and zircon (U–Th)/He and apatite fission‐track (FT) data allow constraining the timing of Miocene–Pliocene extensional exhumation that affected the central part of the Dinarides‐Albanides‐Hellenides orogen. Apatite (U–Th)/He ages in the northern and western Internal Albanides range from 57 to 17 Ma, contrasting to younger ages of 5.2–9.3 Ma in the eastern Internal Albanides. Eastward younging is also reflected in zircon (U–Th)/He ages varying from 101 Ma in the north‐western Internal Albanides to 19–50 Ma in the east, as well as in recently published apatite FT ages. Thermal history predictions with the new data point to a phase of rapid exhumation of the eastern Internal Albanides around 6–4 Ma, while the western Internal Albanides record slower continuous exhumation since the Eocene. This asymmetric exhumation pattern is most likely linked to extensional reactivation of NE–SW‐trending thrusts east of the Mirdita zone and within the Korabi zone of the eastern Internal Albanides.     

Late Glacial fluvial response of the Niers‐Rhine (western Germany) to climate and vegetation change

The Niers valley was part of the Rhine system that came into existence during the maximum Saalian glaciation and was abandoned at the end of the Weichselian. The aim of the study was to explain the Late Pleniglacial and Late Glacial fluvial dynamics and to explore the external forcing factors: climate change, tectonics and sea level. The sedimentary units have been investigated by large‐scale coring transects and detailed cross‐sections over abandoned channels. The temporal fluvial development has been reconstructed by means of geomorphological relationships, pollen analysis and ¹⁴C dating. The Niers‐Rhine experienced a channel pattern change from braided, via a transformational phase, to meandering in the early Late Glacial. This change in fluvial style is explained by climate amelioration at the Late Pleniglacial to Late Glacial transition (at ca. 12.5 k ¹⁴C yr BP) and climate‐related hydrological, lithological and vegetation changes. A delayed fluvial response of ca. 400 ¹⁴C yr (transitional phase) was established. The channel transformations are not related to tectonic effects and sea‐level changes. Successive river systems have similar gradients of ca. 35–40 cm km^?1. A meandering river system dominated the Allerød and Younger Dryas periods. The threshold towards braiding was not crossed during the Younger Dryas, but increased aeolian activity has been observed on the Younger Dryas point bars. The final abandonment of the Niers‐Rhine was dated shortly after the Younger Dryas to Holocene transition. Traces of Laacher See pumice have been found in the Niers valley, indicating that the Niers‐Rhine was still in use during the Younger Dryas. Copyright © 2005 John Wiley & Sons, Ltd.