Discussion on Tunis Soft Soil Sensitivity

In Tunis City, the sensitivity of the marine deposits at shallow depth (z = 0–20 m) varies significantly. The influence of the process of the leaching out of Tunis soft soil on its geotechnical parameters is a focal point in this research. This process leads finally to moderate levels of sensitivity for Tunis clays since it appears to happen in a two steps with increasing sensitivity. The “hard water” leaching out and the dispersive action of organic matter (humus) lead unexpectedly to higher but still moderate level of sensitivity as measured on many Tunis sites. These sensitivity variations result from the combination of leaching out with hard ground water and high content of organic matter. This sensitivity attracted our attention and remains of high interest for the study of the behaviour of the Tunis soft clay.     

A surface structural model for ferrihydrite I: Sites related to primary charge, molar mass, and mass density

A multisite surface complexation (MUSIC) model for ferrihydrite (Fh) has been developed. The surface structure and composition of Fh nanoparticles are described in relation to ion binding and surface charge development. The site densities of the various reactive surface groups, the molar mass, the mass density, the specific surface area, and the particle size are quantified. As derived theoretically, molecular mass and mass density of nanoparticles will depend on the types of surface groups and the corresponding site densities and will vary with particle size and surface area because of a relatively large contribution of the surface groups in comparison to the mineral core of nanoparticles. The nano-sized (∼2.6 nm) particles of freshly prepared 2-line Fh as a whole have an increased molar mass of M ∼ 101 ± 2 g/mol Fe, a reduced mass density of ∼3.5 ± 0.1 g/cm³, both relatively to the mineral core. The specific surface area is ∼650 m²/g. Six-line Fh (5-6 nm) has a molar mass of M ∼ 94 ± 2 g/mol, a mass density of ∼3.9 ± 0.1 g/cm³, and a surface area of ∼280 ± 30 m²/g. Data analysis shows that the mineral core of Fh has an average chemical composition very close to FeOOH with M ∼ 89 g/mol. The mineral core has a mass density around ∼4.15 ± 0.1 g/cm³, which is between that of feroxyhyte, goethite, and lepidocrocite. These results can be used to constrain structural models for Fh. Singly-coordinated surface groups dominate the surface of ferrihydrite (∼6.0 ± 0.5 nm⁻²). These groups can be present in two structural configurations. In pairs, the groups either form the edge of a single Fe-octahedron (∼2.5 nm⁻²) or are present at a single corner (∼3.5 nm⁻²) of two adjacent Fe octahedra. These configurations can form bidentate surface complexes by edge- and double-corner sharing, respectively, and may therefore respond differently to the binding of ions such as uranyl, carbonate, arsenite, phosphate, and others. The relatively low PZC of ferrihydrite can be rationalized based on the estimated proton affinity constant for singly-coordinated surface groups. Nanoparticles have an enhanced surface charge. The charging behavior of Fh nanoparticles can be described satisfactory using the capacitance of a spherical Stern layer condenser in combination with a diffuse double layer for flat plates.     

Solubility and dissimilatory reduction kinetics of iron(III) oxyhydroxides: A linear free energy relationship

Rates of reduction of Fe(III) oxyhydroxides by the bacterium Shewanella putrefaciens were measured as a function of the bacterial density and the Fe(III) substrate concentration. The results show that an earlier reported positive correlation between the solubility products (^*K_so) and the maximum cell-specific reduction rates (v_max) of predominantly poorly crystalline Fe(III) oxyhydroxides also applies to insoluble and crystalline Fe(III) oxyhydroxides. The mineral solubilities were measured by a dialysis bag technique under acidic conditions (pH 1 up to 2.5) at 25 °C. Initial iron reduction rates by S. putrefaciens were determined in the presence of excess lactate as electron donor. In all cases, the microbial reduction rate exhibited saturation behavior with respect to the Fe(III) oxyhydroxide concentration. On a double logarithmic scale, the maximum rates v_max and the solubility products defined a single linear free energy relationship (LFER) for all the Fe(III) oxyhydroxides considered. The solubility provided a better predictor of v_max than the specific surface area of the mineral phase. A rate limitation by the electron transfer between an iron reductase and a Fe(III) center, or by the subsequent desorption of Fe²⁺ from the iron oxide mineral surface, are both consistent with the observed LFER.     

Spatiotemporal variations of extreme sea levels around the South China Sea: assessing the influence of tropical cyclones,monsoons and major climate modes

With sea levels projected to rise as a result of climate change, it is imperative to understand not only long-term average trends, but also the spatial and temporal patterns of extreme sea level. In this study, we use a comprehensive set of 30 tide gauges spanning 1954–2014 to characterize the spatial and temporal variations of extreme sea level around the low-lying and densely populated margins of the South China Sea. We also explore the long-term evolution of extreme sea level by applying a dynamic linear model for the generalized extreme value distribution (DLM-GEV), which can be used for assessing the changes in extreme sea levels with time. Our results show that the sea-level maxima distributions range from ~?90 to 400 cm and occur seasonally across the South China Sea. In general, the sea-level maxima at northern tide gauges are approximately 25–30% higher than those in the south and are highest in summer as tropical cyclone-induced surges dominate the northern signal. In contrast, the smaller signal in the south is dominated by monsoonal winds in the winter. The trends of extreme high percentiles of sea-level values are broadly consistent with the changes in mean sea level. The DLM-GEV model characterizes the interannual variability of extreme sea level, and hence, the 50-year return levels at most tide gauges. We find small but statistically significant correlations between extreme sea level and both the Pacific Decadal Oscillation and El Niño/Southern Oscillation. Our study provides new insight into the dynamic relationships between extreme sea level, mean sea level and the tidal cycle in the South China Sea, which can contribute to preparing for coastal risks at multi-decadal timescales.

     

Nd Isotopic Characteristics of Granitoids from the New foundland Appalachians

正The Appalachian orogen in North America is currently considered to be a Paleozoic accretion-type orogenic belt,or a collage,formed by collision of many ancient blocks between Laurentian and Gondwanan margins (Williams,1979;Williams et al.,1988;van Staal et al.,2007).Recently,major progress has been made in understanding the characteristics and tectonic evolution of the outboard peri-Laurentian and peri-Gondwanan terranes of the Iapetus Ocean (van Staal et al.,2009,2012).     

Sediment distribution and depositional processes along the fluvial to marine transition zone of the Mekong River delta,Vietnam

The area of coastal rivers with a combination of fluvial, tidal and wave processes is defined as the fluvial to marine transition zone and can extend up to several hundreds of kilometres upstream of the river mouth. The aim of this study is to improve the understanding of sediment distribution and depositional processes along the fluvial to marine transition zone using a comprehensive dataset of channel bed sediment samples collected from the Mekong River delta. Six sediment types were identified and were interpreted to reflect the combined action of fluvial and marine processes. Based on sediment‐type associations, the Mekong fluvial to marine transition zone could be subdivided into an upstream tract and a downstream tract; the boundary between these two tracts is identified 80 to 100 km upstream of the river mouth. The upstream tract is characterized by gravelly sand and sand and occasional heterolithic rhythmites, suggesting bed‐load supply and deposition mainly controlled by fluvial processes with subordinate tidal influence. The downstream tract is characterized by heterolithic rhythmites with subordinate sand and mud, suggesting suspended‐load supply and deposition mainly controlled by tidal processes with subordinate fluvial influence. Sediment distributions during wet and dry seasons suggest significant seasonal changes in sediment dynamic and depositional processes along the fluvial to marine transition zone. The upstream tract shows strong fluvial depositional processes with subordinate tidal influence during the wet season and no deposition with weak fluvial and tidal processes during the dry season. The downstream tract shows strong coexisting fluvial and tidal depositional processes during the wet season and strong tidal depositional processes with negligible fluvial influence during the dry season. Turbidity maxima are present along the downstream tract of the fluvial to marine transition zone during both wet and dry seasons and are driven by a combination of fluvial, tidal and wave processes.     

Metre‐scale cycles in shallow water carbonate successions: Milankovitch and stochastic origins

Metre‐scale cycles are a common feature in Precambrian and Phanerozoic shallow water carbonate successions, and astronomically forced changes in sea‐level (Milankovitch cycles) may have been an important driver controlling their deposition. Nevertheless, the degree to which potentially low amplitude astronomically paced sea‐level oscillations may have controlled carbonate accumulation in deep time is unclear. In this study, a stochastic model of carbonate accumulation demonstrates how metre‐scale exposure‐bound sequences can be generated under conditions of random sea‐level change. These sequences have characteristic durations close to Milankovitch cycles, despite the absence of any astronomical control on their formation. Metre‐scale sequences with sub‐Milankovitch (millennial‐scale) durations can also be generated by the model, potentially shedding light on the origin of sub‐Milankovitch sequences such as those recorded on the Middle Triassic Latemar platform of Northern Italy. Sensitivity tests demonstrate how shallow water carbonates may be very sensitive to weak (i.e. low amplitude) astronomically forced sea‐level oscillations. Notably, strong statistical evidence (P < 0·01) for astronomical cycles can be preserved in modelled successions even when astronomical forcing contributes <1% of the sea‐level variance on million year timescales. Taken together, metre‐scale cycles with Milankovitch‐scale durations in ancient carbonate successions may reveal very little about the amplitude, or even the existence, of astronomical forcing as a sea‐level driver.     

The 1905 Chamonix earthquakes: active tectonics in the Mont Blanc and Aiguilles Rouges massifs

Linking earthquakes of moderate size to known tectonic sources is a challenge for seismic hazard studies in northwestern Europe because of overall low strain rates. Here we present a combined study of macroseismic information, tectonic observations, and seismic waveform modelling to document the largest instrumentally known event in the French northern Alps, the April 29, 1905, Chamonix earthquake. The moment magnitude of this event is estimated at M_w 5.3 ± 0.3 from records in Göttingen (Germany) and Uppsala (Sweden). The event of April 29 was followed by several afterschocks and in particular a second broadly felt earthquake on August 13, 1905. Macroseismic investigations allow us to favour a location of the epicentres 5–10 km N–NE of Chamonix. Tectonic analysis shows that potentially one amongst several faults might have been activated in 1905. Among them the right lateral strike-slip fault responsible for the recent 2005 M_w = 4.4 Vallorcine earthquake and a quasi-normal fault northeast of the Aiguilles Rouges massif are the most likely candidates. Discussion of tectonic, macroseismic, and instrumental data favour the normal fault hypothesis for the 1905 Chamonix earthquake sequence.     

Measurements of Rare Earth Element and Other Element Mass Fractions in Environmental Reference Materials (NIST SRM 1646a,NIST SRM 1400, IAEA‐395 and IAEA‐450) by INAA,ICP‐AES and ICP‐MS

INAA, ICP‐AES and ICP‐MS were used to elementally characterise four environmental reference materials – NIST SRM 1646a (Estuarine Sediment), NIST SRM 1400 (Bone Ash), IAEA‐395 (Urban Dust) and IAEA‐450 (Algae). An analytical scheme consisting of the three methods was first applied to NIST SRM 1646a to validate the methodology because it has been extensively analysed and has certified values for many elements. With repeated analyses of NIST SRM 1646a, the accuracy and measurement repeatability of the data obtained were evaluated based on two statistical calculations (zeta‐score and Horwitz ratio) and were observed to be good enough for the analytical scheme to be applied to similar sorts of environmental/geochemical samples. Applying the same approach to NIST SRM 1400, IAEA‐395 and IAEA‐450, enabled mass fractions of 29, 38 and 28 elements to be determined, respectively. Among these results, the data for rare earth elements are of particular interest, not only for IAEA‐450 but also for the other three reference samples. The data for Pr, Gd, Dy, Ho, Er and Tm in NIST SRM 1646a are newly reported in this study. By using small test portions (< 100 mg) for NIST SRM 1646a and IAEA‐395, and recommended minimum amounts for NIST SRM 1400 and IAEA‐450, sample homogeneity was evaluated.