Covariations in oceanic dimethyl sulfide,its oxidation products and rain acidity at Amsterdam Island in the Southern Indian Ocean

Simultaneous measurements of rain acidity and dimethyl sulfide (DMS) at the ocean surface and in the atmosphere were performed at Amsterdam Island over a 4 year period. During the last 2 years, measurements of sulfur dioxide (SO₂) in the atmosphere and of methane sulfonic acid (MSA) and non-sea-salt-sulfate (nss-SO₄ ^2-) in rainwater were also performed. Covariations are observed between the oceanic and atmospheric DMS concentrations, atmospheric SO₂ concentrations, wet deposition of MSA, nss-SO₄ ^2-, and rain acidity. A comparable summer to winter ratio of DMS and SO₂ in the atmosphere and MSA in precipitation were also observed. From the chemical composition of precipitation we estimate that DMS oxidation products contribute approximately 40% of the rain acidity. If we consider the acidity in excess, then DMS oxidation products contribute about 55%.     

Detection of PAHs in seawater using surface-enhanced Raman scattering (SERS)

The laboratory characterization of a field-operable surface-enhanced Raman scattering sensor (SERS optode) is presented for the detection of aromatic hydrocarbons in seawater. The sensor has been developed for deployment with a robust underwater spectrograph. To meet the demands of the harsh seawater application, sol-gel derived SERS substrates were used. The calibration curves of six PAHs were determined to be of Langmuir adsorption isotherm type with limits of detection ranging from the microg l(-1) to ng l(-1) level. The experimentally determined adsorption constants varied strongly with the molecular weight of the analytes and correlated with their solubility. A mixture of five PAHs dissolved in seawater was investigated to demonstrate the utility of this method for screening. Emphasis was put on the interference from suspended particulate matter (SPM). The Raman measurement with backscattering configuration was shown to be immune against turbidities up to 1000 NTU. The physico-chemical interference arising from adsorption by the sediment was measured on-line by adding sediment to a PAH-spiked solution. According to the calibration curve, the PAH concentration decrease corresponded to more than 98% of the analyte being scavenged by the sediment.     

Floodplain hydrology of the Mekong Delta,Vietnam

The Mekong Delta is one of the largest and most intensively used estuaries in the world. Each year it witnesses widespread flooding which is both the basis of the livelihood for more than 17 million people but also the major hazard. Therefore, a thorough understanding of the hydrologic and hydraulic features is urgently required for various planning purposes. While the general causes and characteristics of the annual floods are understood, the inundation dynamics in the floodplains in Vietnam which are highly controlled by dikes and other control structures have not been investigated in depth. Especially, quantitative analyses are lacking, mainly due to scarce data about the inundation processes in the floodplains. Therefore, a comprehensive monitoring scheme for channel and floodplain inundation was established in a study area in the Plain of Reeds in the northeastern part of the Vietnamese Delta. This in situ data collection was complemented by a series of high‐resolution inundation maps derived from the TerraSAR‐X satellite for the flood seasons 2008 and 2009. Hence, the inundation dynamics in the channels and floodplains, and the interaction between channels and floodplains, could be quantified for the first time. The study identifies the strong human interference which is governed by flood protection levels, cropping patterns and communal water management. In addition, we examine the tidal influence on the inundation in various parts of the Delta, since it is expected that climate change‐induced sea level rise will increase the tidal contribution to floodplain inundation. Copyright © 2011 John Wiley & Sons, Ltd.     

FEM × DEM modelling of cohesive granular materials: Numerical homogenisation and multi-scale simulations

The article presents a multi-scale modelling approach of cohesive granular materials, its numerical implementation and its results. At microscopic level, Discrete Element Method (DEM) is used to model dense grains packing. At the macroscopic level, the numerical solution is obtained by a Finite Element Method (FEM). In order to bridge the micro- and macro-scales, the concept of Representative Elementary Volume (REV) is applied, in which the average REV stress and the consistent tangent operators are obtained in each macroscopic integration point as the results of DEM’s simulation. In this way, the numerical constitutive law is determined through the detailed modelling of the microstructure, taking into account the nature of granular materials. We first elaborate the principle of the computation homogenisation (FEM × DEM), then demonstrate the features of our multiscale computation in terms of a biaxial compression test. Macroscopic strain location is observed and discussed.     

Geophysical techniques to aquifer locating and monitoring for industrial zones in North Hanoi, Vietnam

Geophysical methods were applied for hydrogeological targets in many countries including Vietnam. This paper presents results of using complex geophysical techniques as well as 2D electrical resistivity imaging (ERI), vertical electrical sounding (VES), very low frequency (VLF), and seismic refraction for geological structure investigation for locating the aquifers and assessing the hydrogeological conditions for groundwater potential in industrial zones of North Hanoi, Vietnam. The locations of two aquifers are determined by their depth and thickness on the basis of resistivity and seismic velocity values which were proved by stratifications of three boreholes to 40–60 m of depth on the study area. There are connections from surface water to shallow aquifer by hydraulic windows, as follows from VLF data. The deeper aquifer can be considered as a potential groundwater supply, but the water level is descending in time, as shown by hydrological monitoring. However, with careful use and by reducing sources of pollution, groundwater can continue to be an important natural resource for future.