Hydrological characteristics of karstic groundwater in the northeast Viet Nam as studied by isotopic techniques

The stable water isotopic composition (δ²H and δ¹⁸Ο), tritium (³H) activity, dissolved organic carbon, alkalinity, as well as the composition of carbon 13 (δ¹³C) in dissolved inorganic carbon (DIC) of 36 water samples taken from 16 resurgences in the northeast provinces of Viet Nam in the dry (Mar 2008) and rainy (June 2008) seasons were analyzed to elucidate hydrological characteristics of the karstic aquifers in the area. The stable water isotopic composition of the water samples collected clearly demonstrated that the karstic groundwater in the region was recharged from the local meteorological water. The tritium activity in the samples was found to be in between 3 and 4 TU, falling in the range of the ³H activity in the local precipitation and thus meaning that the traveling of recharge water to the resurgences was very short. Concentrated and diffuse allogenic recharges seem to be important sources of karstic groundwater in the study region. Water in the karstic aquifers could be classified into three types as: (a) water from karstic areas with dense vegetation cover that causes DIC be depleted in carbon 13 (¹³δ<?12‰ vs. Pee Dee Belemnite standard of Vienna, VPDB); (b) water from karstic areas with poor vegetation cover that originates DIC with carbon 13 composition ranging from ?11 to ?12‰; and (c) surface water from lakes, springs and rivers that has DIC with enriched carbon 13 (δ¹³C >?10‰). This implies that there are several sources of carbon dioxide contributing to the DIC in water of the karstic aquifers in the study region. Among other potential sources, the atmospheric CO₂, CO₂ from carbonate rock dissolution, biomineralization of soil organic matters and plant roots respiration seem to be important sources of the DIC in the waters of this region. The results show high vulnerability towards anthropogenic contaminants of karstic groundwater in the study region.     

The Potential of Eleocharis acicularis for Phytoremediation: Case Study at an Abandoned Mine Site

Phytoremediation, a plant‐based and cost‐effective technology for the cleanup of contaminated soil and water, is receiving increasing attention. In this study, the aquatic macrophyte Eleocharis acicularis was examined for its ability to take up multiple heavy metals and its potential application for phytoremediation at an abandoned mining area in Hokkaido, Japan. Elemental concentrations were measured in samples of E. acicularis, water, and soil collected from areas of mine tailing and drainage. The results reveal that Pb, Fe, Cr, Cu, Ni, and Mn accumulation in the plants increased over the course of the experiment, exceeding their initial concentrations by factors of 930, 430, 60, 25, 10, and 6, respectively. The highest concentrations of Fe, Pb, Zn, Mn, Cr, Cu, and Ni within the plants were 59500, 1120, 964, 388, 265, 235, and 47.4 mg/kg dry wt., respectively, for plants growing in mine drainage after 11 months of the experiment. These results indicate that E. acicularis is a hyperaccumulator of Pb. We also found high Si concentrations in E. acicularis (2.08%). It is likely that heavy metals exist in opal‐A within cells of the plant. The bioconcentration factors (BCF: ratio of metal concentration in the plant shoots to that in the soil) obtained for Cr, Cu, Zn, Ni, Mn, and Pb were 3.27, 1.65, 1.29, 1.26, 1.11, and 0.82, respectively. The existence of heavy metals as sulphides is thought to have restricted the metal‐uptake efficiency of E. acicularis at the mine site. The results of this study indicate that E. acicularis shows great potential in the phytoremediation of mine tailing and drainage rich in heavy metals.     

Prediction of Rock Size Distribution in Mine Bench Blasting Using a Novel Ant Colony Optimization-Based Boosted Regression Tree Technique

Natural Resources Research - In this paper, we used artificial intelligence (AI) techniques to investigate the relation between the rock size distribution (RSD) and blasting parameters for rock...     

Geological and geophysical studies of the Agoudal impact structure (Central High Atlas,Morocco): New evidence for crater size and age

Since the discovery of shatter cones (SCs) near the village of Agoudal (Morocco, Central High Atlas Mountains) in 2013, the absence of one or several associated circular structures led to speculation about the age of the impact event, the number, and the size of the impact crater or craters. Additional constraints on the crater size, age, and erosion rates are obtained here from geological, structural, and geophysical mapping and from cosmogenic nuclide data. Our geological maps of the Agoudal impact site at the scales of 1:30,000 (6 km²) and 1:15,000 (2.25 km²) include all known occurrences of SCs in target rocks, breccias, and vertical to overturned strata. Considering that strata surrounding the impact site are subhorizontal, we argue that disturbed strata are related to the impact event. Three types of breccias have been observed. Two of them (br1‐2 and br2) could be produced by erosion–sedimentation–consolidation processes, with no evidence for impact breccias, while breccia (br1) might be impact related. The most probable center of the structure is estimated at 31°59′13.73?N, 5°30′55.14?W using the concentric deviation method applied to the orientation of strata over the disturbed area. Despite the absence of a morphological expression, the ground magnetic and electromagnetic surveys reveal anomalies spatially associated with disturbed strata and SC occurrences. The geophysical data, the structural observations, and the area of occurrence of SCs in target rocks are all consistent with an original size of 1.4–4.2 km in diameter. Cosmogenic nuclide data (³⁶Cl) constrain the local erosion rates between 220 ± 22 m Ma^?1 and 430 ± 43 m Ma^?1. These erosion rates may remove the topographic expression of such a crater and its ejecta in a time period of about 0.3–1.9 Ma. This age is older than the Agoudal iron meteorite age (105 ± 40 kyr). This new age constraint excludes the possibility of a genetic relationship between the Agoudal iron meteorite fall and the formation of the Agoudal impact site. A chronolgy chart including the Atlas orogeny, the alternation of sedimentation and erosion periods, and the meteoritic impacts is presented based on all obtained and combined data.     

ALMA observations of the circumstellar envelope around EP Aqr

Atacama Large Millimetre/sub-millimetre Array(ALMA) observations of CO(1–0) and CO(2–1) emissions from the circumstellar envelope of the asymptotic giant branch(AGB) star EP Aqr have been made with four times better spatial resolution than previously available. They are analysed with emphasis on the de-projection in space of the effective emissivity and flux of matter using as input a prescribed configuration of the velocity field, assumed to be radial. The data are found to display an intrinsic axisymmetry with respect to an axis making a small angle with respect to the line of sight. A broad range of wind configurations, from prolate(bipolar) to oblate(equatorial) has been studied and found to be accompanied by significant equatorial emission. Qualitatively, the effective emissivity is enhanced near the equator to produce the central narrow component observed in the Doppler velocity spectra and its dependence on star latitude generally follows that of the wind velocity with the exception of an omni-present depression near the poles. In particular, large equatorial expansion velocities produce a flared disc or a ring of effective emissivity and mass loss. The effect on the determination of the orientation of the star axis of radial velocity gradients, and possibly competing rotation and expansion in the equatorial disc, is discussed. In general,the flux of matter is found to reach a broad maximum at distances of the order of 500 AU from the star.Arguments are given that may be used to favour one wind velocity distribution over another. As a result of the improved quality of the data, a deeper understanding of the constraints imposed on morphology and kinematics has been obtained.     

A history of breaking laws—Social dynamics of non-compliance in Vietnamese marine fisheries

Whether or not fishers comply with regulation depends on the economic and social context in which they operate their vessels. This is how conventional theory explains the phenomenon of non-compliance. It treats state–community interaction processes not as direct causes for non-compliance but rather as background conditions shaping individual fishers’ perception and decisions for action. This paper argues that conventional theory fails to include the dynamics of tempo-relational processes between state and communities, which explains collective patterns of non-compliance in fisheries. The paper addresses this hiatus in the literature, using a process-sociological approach to analyse non-compliance in Vietnamese marine fisheries. The analysis highlights that Vietnamese marine fisheries are mainly regulated through informal networks of trust and mistrust, which function through their interplay with the highly centralised and formalised Vietnamese state. Based on this assessment, the paper concludes that outcomes of processes of the dynamic social interplay between state and communities are semi-dependent on individual perception and action, and as such have a causal effect of their own on patterns of non-compliance in fisheries.     

Small-scale marine fisheries policy in Vietnam

Vietnam's marine fisheries are considered to be small scale and are concentrated in coastal near-shore waters. This has resulted in heavy pressure on near-shore fisheries resources. Near-shore fisheries are considered by fishers and the government to be over-exploited, causing hardship for many coastal communities. This paper reviews and analyzes changes in policy towards small-scale fisheries in Vietnam over the last two decades. The primary issues facing the small-scale fisheries in Vietnam are to restructure the near-shore fisheries and to address over-capacity. Recommended actions include improved fisheries statistics, resources for provincial fisheries staff, and a coordinated and integrated approach involving a mixed strategy of resource management; resource restoration; economic and community development; and new governance arrangements.     

Petroleum composition in the Cuu Long Basin (Mekong Basin) offshore southern Vietnam

The Cuu Long Basin (Mekong Basin) is a rift basin off southern Vietnam, and the most important petroleum producing basin in the country. However, information on petroleum type and characteristics has hitherto been largely unavailable to the public. This paper presents petroleum geochemical data on nine oil samples from four different producing fields in the Cuu Long Basin: the Dragon (Rong), Black Lion (Sutu-Den), Sunrise (Rang ?ong) and White Tiger (Bach Ho) Fields. The oils are highly paraffinic with bimodal normal alkane distributions and show moderate pristane to phytane ratios and a conspicuous hyperbolic decrease in abundance with increasing carbon number of hopane homologues from C₃₀ to C₃₅. The TPP-index of Holba et al. (Holba, A.G., Dzou, L.I., Wood, G.D., Ellis, L., Adam, P., Schaeffer, P., Albrecht, P., Greene, T., Hughes, W.B., 2003. Application of tetracyclic polyprenoids as indicators of input from fresh–brackish water environments. Organic Geochemistry 34, 441–469) is equal to 1 in all samples which in combination with tricyclic triperpane T26/T25 ratios >1 and the n-alkane and hopane distributions mentioned above provide a strong indication of an origin from lacustrine source rocks. This is supported by the absence of marine C₃₀ desmethyl steranes (i.e. 24-n-propylcholestanes) and marine diatom-derived norcholestanes. Based on the overall biological marker distributions, the lakes probably belonged to the overfilled or balanced-fill types defined by Bohacs et al. (Bohacs, K.M., Carroll, A.R., Neal, J.E., Mankiewicz, P.J., 2000. Lake-basin type, source potential, and hydrocarbon character. An integrated sequence-stratigraphic–geochemical framework. AAPG Studies in Geology 46, 3–34). The oils were generated from source rocks at early- to mid-oil-window maturity, presumably Oligocene lacustrine shales that are present in the syn-rift succession. Oils from individual fields may, however, be distinguished by a combination of biological marker parameters, such as the oleanane index, the gammacerane index, the relative abundance of tricyclic terpanes, the proportions of diasteranes and 28-norspergulane, complemented by other parameters. The oils of the Cuu Long Basin show an overall similarity to the B-10 oil from the Song Hong Basin off northern Vietnam, but are markedly different from the seepage oils known from Dam Thi Nai on the coast of central Vietnam.     

Effect of open gap in coastal forest on tsunami run-up—investigations by experiment and numerical simulation

The objective of this study is to investigate the effects of an open gap, such as a road, in a coastal forest on tsunami run-up. A numerical model based on two-dimensional nonlinear long-wave equations was developed to account for the effects of drag and turbulence induced shear forces due to the presence of vegetation. Experiments were conducted on a forest simulated with vertical cylinders by changing the gap width. The numerical model was validated in good agreement with the experimental results. The numerical model was then applied to a wide forest of Pandanus odoratissimus, a tree species that is a dominant coastal vegetation on a sand dune in South and Southeast Asia. The effect of vertical stand characteristics of P. odoratissimus with aerial roots was considered on the drag resistance. A straight open gap perpendicular to the shoreline was used to investigate the effect of gap width. As the gap width increases, the flow velocity at the end of the open gap first increases, reaches a maximum, and then decreases, while the run-up height increases monotonously. The maximum velocity in the present condition is 1.7 times the maximum velocity without a coastal forest. The effects of different gap arrangements in the forest on tsunami run-up were also investigated in this paper. The flow velocity at the end of an open gap can be reduced by a staggered arrangement.