Evidence for high‐temperature fractionation of lithium isotopes during differentiation of the Moon

Lithium isotope and abundance data are reported for Apollo 15 and 17 mare basalts and the LaPaz low‐Ti mare basalt meteorites, along with lithium isotope data for carbonaceous, ordinary, and enstatite chondrites, and chondrules from the Allende CV3 meteorite. Apollo 15 low‐Ti mare basalts have lower Li contents and lower δ⁷Li (3.8 ± 1.2‰; all uncertainties are 2 standard deviations) than Apollo 17 high‐Ti mare basalts (δ⁷Li = 5.2 ± 1.2‰), with evolved LaPaz mare basalts having high Li contents, but similar low δ⁷Li (3.7 ± 0.5‰) to Apollo 15 mare basalts. In low‐Ti mare basalt 15555, the highest concentrations of Li occur in late‐stage tridymite (>20 ppm) and plagioclase (11 ± 3 ppm), with olivine (6.1 ± 3.8 ppm), pyroxene (4.2 ± 1.6 ppm), and ilmenite (0.8 ± 0.7 ppm) having lower Li concentrations. Values of δ⁷Li in low‐ and high‐Ti mare basalt sources broadly correlate negatively with ¹⁸O/¹⁶O and positively with ⁵⁶Fe/⁵⁴Fe (low‐Ti: δ⁷Li ≤4‰; δ⁵⁶Fe ≤0.04‰; δ¹⁸O ≥5.7‰; high‐Ti: δ⁷Li >6‰; δ⁵⁶Fe >0.18‰; δ¹⁸O <5.4‰). Lithium does not appear to have acted as a volatile element during planetary formation, with subequal Li contents in mare basalts compared with terrestrial, martian, or vestan basaltic rocks. Observed Li isotopic fractionations in mare basalts can potentially be explained through large‐degree, high‐temperature igneous differentiation of their source regions. Progressive magma ocean crystallization led to enrichment in Li and δ⁷Li in late‐stage liquids, probably as a consequence of preferential retention of ⁷Li and Li in the melt relative to crystallizing solids. Lithium isotopic fractionation has not been observed during extensive differentiation in terrestrial magmatic systems and may only be recognizable during extensive planetary magmatic differentiation under volatile‐poor conditions, as expected for the lunar magma ocean. Our new analyses of chondrites show that they have δ⁷Li ranging between ?2.5‰ and 4‰. The higher δ⁷Li in planetary basalts than in the compilation of chondrites (2.1 ± 1.3‰) demonstrates that differentiated planetary basalts are, on average, isotopically heavier than most chondrites.     

The “suevite” conundrum,Part 1: The Ries suevite and Sudbury Onaping Formation compared

The term “suevite” has been applied to various impact melt‐bearing breccias found in different stratigraphic settings within terrestrial impact craters. Suevite was coined initially for impact glass‐bearing breccias from the Ries impact structure, Germany, which is the type locality. Various working hypotheses have been proposed to account for the formation of the Ries suevite deposits over the past several decades, with the most recent being molten‐fuel‐coolant interaction (MFCI) between an impact melt pool and water. This mechanism is also the working hypothesis for the origin of the bulk of the Onaping Formation at the Sudbury impact structure, Canada. In this study, the key characteristics of the Ries suevite, the Onaping Formation and MFCI deposits from phreatomagmatic volcanic eruptions are compared. The conclusion is that there are clear and significant lithological, stratigraphic, and petrographic observational differences between the Onaping Formation and the Ries suevite. The Onaping Formation, however, shares many key similarities with MFCI deposits, including the presence of layering, their well‐sorted and fine‐grained nature, and the predominance of vitric particles with similar shapes and lacking included mineral and lithic clasts. These differences argue against the viability of MFCI as a working hypothesis for genesis of the Ries suevite and for a required alternative mechanism for its formation.     

The Mars oxidant experiment (MOx) for Mars '96

The MOx instrument was developed to characterize the reactive nature of the martian soil. The objectives of MOx were: (1) to measure the rate of degradation of organics in the martian environment; (2) to determine if the reactions seen by the Viking biology experiments were caused by a soil oxidant and measure the reactivity of the soil and atmosphere: (3) to monitor the degradation, when exposed to the martian environment, of materials of potential use in future missions; and, finally, (4) to develop technologies and approaches that can be part of future soil analysis instrumentation. The basic approach taken in the MOx instrument was to place a variety of materials composed as thin films in contact with the soil and monitor the physical and chemical changes that result. The optical reflectance of the thin films was the primary sensing-mode. Thin films of organic materials, metals, and semiconductors were prepared. Laboratory simulations demonstrated the response of thin films to active oxidants.     

HST Planetary Camera images of quasar host galaxies

We present Hubble Space Telescope ( HST ) images of seven low-redshift quasars (six taken with the Planetary Camera, one with the Wide Field Camera). These complete the sample of 14 quasars observed by the Faint Object Camera Investigation Definition Team (FOC IDT). Following subtraction of the quasar nuclear light, host galaxies can be seen in all seven cases. A combination of the optical morphology and luminosity profiles of the residual host galaxies and the results of 2D cross-correlation model fitting implies that five of the objects have elliptical host galaxies and two have disc host galaxies. The luminosities vary from slightly fainter than L ^* to about 1.3 mag brighter than L ^*.   We discuss the properties of the complete sample of 14 quasars. Nine of the objects appear to have elliptical host galaxies (all six of the radio-loud quasars in the sample as well as three radio-quiet quasars). Two further radio-quiet quasars appear to lie in disc galaxies. The other three objects (radio-quiet, ultraluminous infrared quasars) all lie in violently interacting systems. The sample as a whole has an average luminosity about 0.8 mag brighter than L ^*, although the radio-loud objects have hosts on average 0.7 mag brighter than the radio-quiet objects.   We compare our results with those from HST imaging of quasars by other authors. Taken together, our observations are in broad agreement with those of Bahcall et al. Radio-loud quasars appear to lie in luminous elliptical galaxies whereas radio-quiet quasars are found to lie in either elliptical or spiral hosts. Host galaxy luminosities (of radio-quiet and radio-loud quasars) are much brighter than would be expected if they followed a Schechter luminosity function.     

Polarization observations of the radio cores of AGN — I. A sample of quasars

We present total-intensity and linear-polarization observations at a single epoch for a sample of 11 quasars and one BL Lac object. The data were taken with the VLA A array at λλ 20, 18, 6 and 2 cm. We examine the variation of the degree of polarization, p , and polarization position angle, PA, with wavelength, and attempt to determine the rotation measure, RM, of the cores in these sources. The degree of polarization does not exhibit any systematic variation with wavelength, the median values ranging from 2.3 to 3.5 per cent at the different wavelengths. The variation of PA with λ² is not linear over the entire wavelength range. However, for most sources the λλ 20-, 18- and 6-cm PAs do follow such a linear relationship, yielding a median |RM| of about 15 rad m⁻². In contrast, the λλ 6- and 2-cm observations give a median |RM| of about 129 rad m⁻². The long-wavelength emission is likely to originate from a spatially different part of the milliarcsec-scale jet from the λ 2-cm emission, which could turn over at a higher frequency and is likely to be more compact and located closer to the quasar nucleus. We have attempted to obtain linear fits over the entire wavelength range allowing for n  π ambiguities in the PAs, but the fits are not statistically significant. The low values of RM for these core-dominated sources suggest that either the radio emission from the jet intercepts few of the emission-line clouds and their confining medium, or the clouds have a small filling factor and are possibly magnetically confined.     

Foreground separation methods for satellite observations of the cosmic microwave background

A maximum entropy method (MEM) is presented for separating the emission resulting from different foreground components from simulated satellite observations of the cosmic microwave background radiation (CMBR). In particular, the method is applied to simulated observations by the proposed Planck Surveyor satellite. The simulations, performed by Bouchet &38; Gispert, include emission from the CMBR and the kinetic and thermal Sunyaev–Zel'dovich (SZ) effects from galaxy clusters, as well as Galactic dust, free–free and synchrotron emission. We find that the MEM technique performs well and produces faithful reconstructions of the main input components. The method is also compared with traditional Wiener filtering and is shown to produce consistently better results, particularly in the recovery of the thermal SZ effect.     

Neutral hydrogen absorption observations of the central region of NGC 5929

We present 0.15-arcsec (25-pc) resolution MERLIN observations of neutral hydrogen absorption detected towards the nuclear region of the type 2 Seyfert galaxy NGC 5929. Absorption is detected only towards the north-eastern radio component with a column density of (6.5 ± 0.6) × 10²¹ cm⁻². Based on comparison with an HST WFPC2 continuum image, we propose that the absorption is caused by a 1.5-arcsec structure of neutral gas and dust offset 0.3 arcsec south-east of the nucleus and running NE–SW. A separate cloud of dust is apparent 1.5 arcsec to the south-west of the nucleus in the HST image. A comparison of the centroid velocity (2358 ± 5 km s⁻¹) and full width at half-maximum (43 ± 6 km s⁻¹) of the absorbing gas with previous [O  III ] observations suggests that both the neutral and ionized gas are undergoing galactic rotation towards the observer in the north-east and away from the observer in the south-west. The main structure is consistent with an inclined ring of gas and dust encircling the active galactic nucleus (AGN); alternatively it may be a bar or inner spiral arm. We do not detect neutral hydrogen absorption or dust obscuration against the radio nucleus (column density < 3.1 × 10²¹ cm⁻²) expected by a torus of neutral gas and dust in unified models of AGNs for a type 2 Seyfert galaxy.     

The Jet Driven Motions in the Narrow Line Region of NGC 1068

We have obtained HST FOC f/48 long-slit spectroscopy of the central 2 arcseconds of the Narrow Line Region of NGC 1068 between 3500-5400\OA with a spectral resolution of 1.78\OA/pixel. At a spatial scale of 0″.0287 per pixel these data provide an order of magnitude improvement in resolution over previous ground based spectra and allow us to trace the interaction between the radio jet and the gas in the NLR. Our results show that, within ±0″.5 of the radio-jet the emission lines are split into two components whose velocity separation is 1500 km s-1. The emission line structure is reminiscent of that seen previously around the jet of 3C120. Furthermore, this material enveloping the radio-jet is in a much higher ionization state than that of the surrounding NLR gas. The highest excitation is coincident with the jet axis where emission in the coronal line of [FeVII] λ3769\OA is detected but where [OII] λ3727 \OA is depressed. These results imply that we are witnessing a cocoon of hot gas in expansion around the radio-jet created by its interaction with the gas, and that these shocks are sufficiently fast, at least ± km s-1, that they are creating localized ionization effects. This revised version was published online in July 2006 with corrections to the Cover Date.     

TiN PRODUCTION IN A GLOW DISCHARGE

We have been studying direct current glow discharges aiming at the production of different paint of coatings on steel substrates. In a set of preliminary experiments, long lasting (hours) discharges performed in a Nitrogen atmosphere between a stell anode (holding the substrates) and a titanium cathode separated by a small gap (few mm) produced very thin coatings of the substrates whose colour depend on the parameter of (interelectrodes gap, gas pressure, discharge current and time duration). In some conditions, the coatings showed a golden colour, typical of the Nti compound. A discussion of the results is given.