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111.
112.
Victor L. Vinograd Benjamin P. Burton Neil L. Allan 《Geochimica et cosmochimica acta》2007,71(4):974-983
Thermodynamic mixing properties and subsolidus phase relations of the rhombohedral carbonate system, (1 − x) · CaCO3 − x · MgCO3, were modelled in the temperature range of 623-2023 K with static structure energy calculations based on well-parameterised empirical interatomic potentials. Relaxed static structure energies of a large set of randomly varied structures in a 4 × 4 × 1 supercell of calcite (a = 19.952 Å, c = 17.061 Å) were calculated with the General Utility Lattice Program (GULP). These energies were cluster expanded in a basis set of 12 pair-wise effective interactions. Temperature-dependent enthalpies of mixing were calculated by the Monte Carlo method. Free energies of mixing were obtained by thermodynamic integration of the Monte Carlo results. The calculated phase diagram is in good agreement with experimental phase boundaries. 相似文献
113.
Joanna K. Barstow Neil E. Bowles Suzanne Aigrain Leigh N. Fletcher Patrick G. J. Irwin Ryan Varley Enzo Pascale 《Experimental Astronomy》2015,40(2-3):545-561
We demonstrate the effectiveness of the Exoplanet Characterisation Observatory mission concept for constraining the atmospheric properties of hot and warm gas giants and super Earths. Synthetic primary and secondary transit spectra for a range of planets are passed through EChOSim [13] to obtain the expected level of noise for different observational scenarios; these are then used as inputs for the NEMESIS atmospheric retrieval code and the retrieved atmospheric properties (temperature structure, composition and cloud properties) compared with the known input values, following the method of [1]. To correctly retrieve the temperature structure and composition of the atmosphere to within 2 σ, we find that we require: a single transit or eclipse of a hot Jupiter orbiting a sun-like (G2) star at 35 pc to constrain the terminator and dayside atmospheres; 20 transits or eclipses of a warm Jupiter orbiting a similar star; 10 transits/eclipses of a hot Neptune orbiting an M dwarf at 6 pc; and 30 transits or eclipses of a GJ1214b-like planet. 相似文献
114.
Analysis of the surface temperature and wind forecast errors of the NCAR-AirDat operational CONUS 4-km WRF forecasting system 总被引:1,自引:0,他引:1
Andrzej A. Wyszogrodzki Yubao Liu Neil Jacobs Peter Childs Yongxin Zhang Gregory Roux Thomas T. Warner 《Meteorology and Atmospheric Physics》2013,122(3-4):125-143
Investigating the characteristics of model-forecast errors using various statistical and object-oriented methods is necessary for providing useful guidance to end-users and model developers as well. To this end, the random and systematic errors (i.e., biases) of the 2-m temperature and 10-m wind predictions of the NCAR-AirDat weather research and forecasting (WRF)-based real-time four-dimensional data assimilation (RTFDDA) and forecasting system are analyzed. This system has been running operationally over a contiguous United States (CONUS) domain at a 4-km grid spacing with four forecast cycles daily from June 2009 to September 2010. In the result an exceptionally useful forecast dataset was generated and used for studying the error properties of the model forecasts, in terms of both a longer time period and a broader coverage of geographic regions than previously studied. Spatiotemporal characteristics of the errors are investigated based on the 24-h forecasts between June 2009 and April 2010, and the 72-h forecasts between May and September 2010. It was found that the biases of both wind and temperature forecasts vary greatly seasonally and diurnally, with dependency on the forecast length, station elevation, geographical location, and meteorological conditions. The temperature showed systematic cold biases during the daytime at all station elevations and warm biases during the nighttime above 1,000 m above sea level (ASL), while below 600 m ASL cold biases occurred during the nighttime. The forecasts of surface wind speed exhibited strong positive biases during the nighttime, while the negative biases were observed in the spring and summer afternoons. The surface wind speed was mostly over-predicted except for the stations located between 1,000 and 2,100 m ASL, for which negative biases were identified for most forecast cycles. The highest wind-speed errors were found over the high terrain and near sea-level stations. The wind-direction errors were relatively large at the high-terrain elevation in the Rocky and Appalachian mountain ranges and the western coastal areas and the error structure exhibited notable diurnal variability. 相似文献
115.
Neil Gunningham 《Climate Policy》2013,13(2):302-320
The question of whether China is on the verge of a ‘shale gas revolution’ is examined. This has potentially significant consequences for energy policy and climate change mitigation. Contrary to the optimistic reading of some commentators, it argues that various technological, environmental, political, regulatory and institutional factors will constrain the growth of China's shale gas market and that such a revolution might in any event have consequences that are at best mixed, at worst antithetical to climate change mitigation.Policy relevanceChina's reserves of unconventional gas have the potential to transform energy policy, as has occurred in the US, resulting in the substitution of shale gas for coal in the energy mix. Because gas emits only approximately half the GHG per unit as coal, such a move would have important implications for climate policy. However, substantial obstacles stand in the way of the ‘energy revolution’ that some policy analysts see China as embarking upon. The need to acknowledge these obstacles, particularly those relating to regulation and governance (and whether or to what extent they can be overcome), is an issue of profound importance to the future of climate and energy policy. 相似文献
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117.
Neil Dello Russo Michael J. Mumma Karen Magee-Sauer Boncho P. Bonev I.S. McLean 《Icarus》2006,184(1):255-276
We obtained high-resolution (λ/Δλ∼25,000) spectra of Comet C/1999 H1 (Lee) on UT 1999 August 19.6 and 21.6 using the cross-dispersed Near InfraRed SPECtrometer (NIRSPEC) at the Keck Observatory atop Mauna Kea, HI. Here we present spectra of Comet Lee between 2.874 and 3.701 μm (3479-2702 cm−1) representing the most complete high-resolution infrared survey of a comet to date in this wavelength region. Using published line lists and laboratory spectra we have identified 444 of the 545 distinct emission features present in these spectra. We have tabulated the rest frequencies, assignments, relative intensities, and signal-to-noise ratios of all detected emissions. In addition to gaining insights into the chemistry of Comet Lee, this survey provides a valuable tool for planning future high-resolution infrared observations of comets and other astronomical targets, and for retrospective comparison to existing high-resolution infrared datasets. 相似文献
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120.
The dates of recession of eleven outlet glaciers of the Hielo Patagónico Norte (Northern Patagonian Icefield) from their recent maximum positions have been inferred from dendrochronology, lichenometry, radiocarbon dating and historical sources. We have refined the dating for part of the Little Ice Age period in this area placing a glacial advance to between AD 1650 and 1766 with the latter date favoured as conformable with historical records and an uncalibrated radiocarbon determination. Glacier recession from maximal positions began in the early 1860s–1870s. Recession was largely synchronous on the western and eastern sides of the Icefield. This synchronicity suggests that climate forcing over-rides second-order controls on glacier behaviour such as the nature of the terminal environment (e.g. calving/non-calving) or differences in glacier drainage basin area. We argue that this icefield-wide glacier recession represents a response to post-Little Ice Age warming, and provides further evidence for the global extent and near synchronous termination of the Little Ice Age. 相似文献