An experimental study of spinel clinopyroxenite xenoliths from the Duncansby Ness vent,Caithness, Scotland

Xenoliths of coarse-grained spinel-clinopyroxenite up to 15 cm in size occur in tuff in an isolated Permian vent on the Caithness coast at Duncansby Ness. Highly altered fragments of chrome-spinel lherzolite and wehrlite are also found in the tuff and in a body of monchiquite within the vent. The spinel-clinopyroxenites consist of aluminous augite and aluminous pleonaste spinel (FeO/MgO = 0.9) and their texture suggests the spinel to have exsolved from the augite. Experiments on representative natural xenolith compositions at 18 kb (dry) indicate that all the spinel in the estimated average bulk composition (Sp_4.9Px_95.1) could have exsolved from an original homogeneous pyroxene. Initial fractionation of such a pyroxene from an alkali basaltic magma at P≥18 kb, 1450-1350 °C, would be followed by spinel exsolution at T< 1290 ° C. A similar origin by fractionation of a highly aluminous augite (± aluminous spinel) at high pressure, with subsequent spinel exsolution is proposed for spinel-clinopyroxenites from alkali basalts elsewhere in the world. The similarity of these xenoliths suggests that such a process may form an important stage in the evolution of some undersaturated basaltic rocks.     

Lamb's problem and comments on the paper ‘on leaking modes’ byUsha Gupta

Summary In a recent paper,Gupta [5]²⁾ re-examined the significance of leaking modes in Lamb's problem (Lamb [7]). In this paper, we present a brief review of the exact Cagniard-de Hoop solution to this problem, and use these results to examine the question of the leaking mode in more detail. The leaking mode may either cause a separate arrival,P, or influence the shape of other arrivals e.g.SpS. We have attempted to clarify and extend previous results and correct misconceptions which have appeared elsewhere and, therefore, most of this discussion is tutorial in nature.     

Processes controlling metal ion attenuation in acid mine drainage streams

Two acid mine drainage streams have been investigated by detailed analysis of their sediments and waters, to obtain an understanding of the dominant processes which control the transport and attenuation of heavy metals under conditions of chronic high-level pollutant input. One of the water-courses has a thick hydrous iron oxide crust on its bed, where biotically mediated oxidation of ferrous iron resulted in precipitation of amorphous ferric hydroxide, along with substantial quantities of adsorbed silica, sulphate and Al and lesser quantities of As. Small amounts of K and Pb (and possibly hydronium) jarosites were also present in the sediments. Changes in pH and in the concentrations of Cu, Zn, and Cd appear to be mainly the result of dilution by seeps and tributaries.Although no sediment was recovered during collection of water samples from the second stream, saturation index calculations imply that precipitation should have been occurring. The observed down-stream loss of a number of elements supported this conclusion. The solids predicted to be precipitating were A1(OH)₃, Cu₂(OH)₂CO₃, and Fe(OH)₃. Observed decreases in the concentrations of Cd, Zn and Mn can be accounted for on the basis of dilution alone. However, the additional mechanism of neutralization by higher pH inflows is required to account for the decrease in hydrogen ion concentration downstream.The basis for a potentially useful new technique (congruent element analysis) which enables the identification of conservative components in streams is presented. Comparison of logarithmic concentration versus distance plots delineates the point where chemical removal mechanisms become important for each element.     

Relative contributions of silicate and carbonate rocks to riverine Sr fluxes in the headwaters of the Ganges

Exhumation of the Himalayan-Tibetan orogen is implicated in the marked rise in seawater ⁸⁷Sr/⁸⁶Sr ratios since 40 Ma. However both silicate and carbonate rocks in the Himalaya have elevated ⁸⁷Sr/⁸⁶Sr ratios and there is disagreement as to how much of the ⁸⁷Sr flux is derived from silicate weathering. Most previous studies have used element ratios from bedrock to constrain the proportions of silicate- and carbonate-derived Sr in river waters. Here we use arrays of water compositions sampled from the head waters of the Ganges in the Indian and Nepalese Himalaya to constrain the end-member element ratios. The compositions of tributaries draining catchments restricted to a limited range of geological units can be described by two-component mixing of silicate and carbonate-derived components and lie on a plane in multicomponent composition space. Key elemental ratios of the carbonate and silicate components are determined by the intersection of the tributary mixing plane with the planes Na = 0 for carbonate and constant Ca/Na for silicate. The fractions of Sr derived from silicate and carbonate sources are then calculated by mass-balance in Sr-Ca-Mg-Na composition space. Comparison of end-member compositions with bedrock implies that secondary calcite deposition may be important in some catchments and that dissolution of low-Mg trace calcite in silicate rocks may explain discrepancies in Sr-Ca-Na-Mg covariation. Alternatively, composition-dependent precipitation or incongruent dissolution reactions may rotate mixing trends on cation-ratio diagrams. However the calculations are not sensitive to transformations of the compositions by incongruent dissolution or precipitation processes provided that the transformed silicate and carbonate component vectors are constrained. Silicates are calculated to provide ∼50% of the dissolved Sr flux from the head waters of the Ganges assuming that discrepancies between Ca-Mg-Na covariation and the silicate rock compositions arise from addition of trace calcite. If the Ca-Mg-Na mixing plane is rotated by composition-dependent secondary calcite deposition, this estimate would be increased. Moreover, when ⁸⁷Sr/⁸⁶Sr ratios of the Sr inputs are considered, silicate Sr is responsible for 70 ± 16% (1σ) of the ⁸⁷Sr flux forcing changes in seawater Sr-isotopic composition. Since earlier studies predict that silicate weathering generates as little as 20% of the total Sr flux in Himalayan river systems, this study demonstrates that the significance of silicate weathering can be greatly underestimated if the processes that decouple the water cation ratios from those of the source rocks are not properly evaluated.     

Environmental changes in an alpine lake (Gossenköllesee, austria) over the last two centuries – the influence of air temperature on biological parameters

Changes in microfossils (diatoms, chrysophytes, chironomids and cladocera remains), geochemistry and deposition of atmospheric pollutants have been investigated in the sediment records of the alpine lake Gossenköllesee (Tyrol, Austria) spanning the last two centuries. The sediment records were compared with seasonal and annual air temperature trends calculated for the elevation (2417 m a.s.l.) and the geographical position (47° 1346N, 11° 0051E) of the lake, and with precipitation records available since 1866 from Innsbruck. Temperature trends followed a 20–30 year oscillation between cold and warm periods. Regarding long-term changes, temperature trends showed a U-shaped trend between 1780 and 1950, followed by a steep increase since 1975.Physical, geochemical, and organic parameters were not controlled by air temperature. Among the biological records only diatoms and chrysophytes reacted to air temperature changes: the relative abundance of planktonic diatoms increased during warm periods and changes in mean annual alpine air temperature explained 36.5% of their variation. The relation between abundance of seasonal stomatocyst types and air temperature varied on two different time scales: while summer stomatocysts were influenced by short term temperature fluctuations, the autumn stomatocysts were affected only by the long term changes. Other biological parameters exhibited a constant species composition (chironomids, pigments) or changes were small and independent of temperature (cladocera). Spheroidal carbonaceous fly-ash particles, and trends in Pb and Cr indicated increasing deposition of atmospheric pollutants but had no detectable effects on the biological parameters either. In respect to temperature variations over the last 200 years, this alpine lake is much less sensitive than expected and has thus to be regarded as a well buffered site. However, temperature alone is not sufficient to understand changes in species composition and other biogeochemical processes with unknown historical patterns might have affected species composition more strongly.     

Pore water testing and analysis: the good,the bad,and the ugly

The increasingly common practice of collecting and assessing sediment pore water as a primary measure of sediment quality is reviewed. Good features of this practice include: pore water is a key exposure route for some organisms associated with sediments; pore water testing eliminates particle size effects; pore water analyses and tests can provide useful information regarding contamination and pollution. Bad features include: pore water is not the only exposure route; pore water tests lack chemical or biological realism: their "sensitivity" relative to other tests may be meaningless due to manipulation and laboratory artifacts; many sediment and surface dwelling organisms are not directly influenced by pore water. Bad features can become ugly if: other exposure pathways are not considered (for toxicity or bioaccumulation); manipulation techniques are not appropriate; pore water tests are inappropriately linked to population-level effects. Pore water testing and analyses can be effective tools provided their limitations are well understood by researchers and managers.     

CO2 Mitigation by Agriculture: An Overview

Agriculture currently contributes significantly to the increase of CO2 in the atmosphere, primarily through the conversion of native ecosystems to agricultural uses in the tropics. Yet there are major opportunities for mitigation of CO2 and other greenhouse gas emissions through changes in the use and management of agricultural lands. Agricultural mitigation options can be broadly divided into two categories: (I) strategies to maintain and increase stocks of organic C in soils (and biomass), and (ii) reductions in fossil C consumption, including reduced emissions by the agricultural sector itself and through agricultural production of biofuels to substitute for fossil fuels.Reducing the conversion of new land to agriculture in the tropics could substantially reduce CO2 emissions, but this option faces several difficult issues including population increase, land tenure and other socio-political factors in developing countries. The most significant opportunities for reducing tropical land conversions are in the humid tropics and in tropical wetlands. An important linkage is to improve the productivity and sustainability of existing agricultural lands in these regions.Globally, we estimate potential agricultural CO2 mitigation through soil C sequestration to be 0.4-0.9 Pg C y-1, through better management of existing agricultural soils, restoration of degraded lands, permanent "set-asides" of surplus agricultural lands in temperate developed countries and restoration of 10-20% of former wetlands now being used for agriculture. However, soils have a finite capacity to store additional C and therefore any increases in C stocks following changes in management would be largely realized within 50-100 years.Mitigation potential through reducing direct agricultural emissions is modest, 0.01-0.05 Pg C y-1. However, the potential to offset fossil C consumption through the use of biofuels produced by agriculture is substantial, 0.5-1.6 Pg C y-1, mainly through the production of dedicated biofuel crops with a smaller contribution (0.2-0.3 Pg C y-1) from crop residues.Many agricultural mitigation options represent "win-win" situations, in that there are important side benefits, in addition to CO2 mitigation, that could be achieved, e.g. improved soil fertility with higher soil organic matter, protection of lands poorly suited for permanent agriculture, cost saving for fossil fuel inputs and diversification of agricultural production (e.g. biofuels). However, the needs for global food production and farmer/societal acceptability suggest that mitigation technologies should conform to: (I) the enhancement of agricultural production levels in parts of the world where food production and population demand are in delicate balance and (ii) the accrual of additional benefits to the farmer (e.g., reduced labor, reduced or more efficient use of inputs) and society at large.     

Yandal greenstone belt, Western Australia: 12 million ounces of gold in the 1990s

After a century of virtual neglect, exploration in the Yandal greenstone belt of the Yilgarn Craton of Western Australia has yielded resources of 12 Moz Au during the 1990s. Success has come from a combination of conceptual geological models, surface prospecting, understanding the weathering environment, and systematic drilling. The Archaean Yandal greenstone belt comprises a lowermost banded iron formation, extensive basalt and dolerite sills, ultramafic rocks, intermediate to felsic volcanic rocks, and variable clastic sedimentary rocks. Early shear zones trend NNW and form the greenstone belt margins, or trend N–S within the belt. Later brittle cross-faults are critical in gold localization. Gold resources and past production at major deposits include Bronzewing (4 Moz Au), Jundee (5 Moz) Mt.␣McClure (1 Moz) and Darlot (3␣Moz, some of which was produced before 1990). All major deposits are hosted by Fe-rich mafic rocks, and mineralization displays a combination of different orientations and morphologies. Quartz veins are surrounded by broad carbonate alteration with proximal K-mica and Fe-sulphides. The recognition of a critical role for the late brittle structures in localizing gold implicates mid-crustal processes within the greenstone belt for fluid generation, and with the host rock control, supports the model in which fluid was derived by metamorphic devolatilization. Received: 19 September 1997 / Accepted: 7 January 1998