Origin of the 3500-3300 Ma calc-alkaline rocks in the Pilbara Archaean: isotopic and geochemical constraints from the Shaw Batholith

Calc-alkaline plutonic rocks, intruded at 3450Ma, comprise a major component of the Shaw Batholith in the Archaean east Pilbara Block, Western Australia. New whole-rock Pb isotopic geochronology confirms the extent of these rocks, but a minor plutonic phase is dated at 3338±52 Ma and represents a second plutonic event of the same age as much of the nearby Mt Edgar Batholith. The Sm----Nd isotopic systematics of the 3450Ma rocks imply their derivation from a heterogeneous source, which probably included a slightly older crustal component as well as a depleted mantle component. The 3338±52 Ma pluton includes components derived from crustal sources older than 3600 Ma. The geochemistry and Sm---Nd isotopic systematics of these rocks are consistent with crustal growth in the early Archaean from upper mantle sources as depleted as the modern upper mantle. The Shaw Batholith calc-alkaline suites exhibit very similar chemical trends on variation diagrams to modern calc-alkaline plutonic rocks which can be modelled by a combination of mixing and fractionation. A suite collected from outcrops displaying prominent igneous layering shows distinct geochemical trends which can be modelled by differentiation into a component enriched in ferromagnesian minerals, principally hornblende, and possibly sphene, magnetite and epidote, and into a leucocratic component containing quartz, plagioclase and K-feld-par. These Archaean calc-alkaline plutonic rocks, in common with rocks from many other Archaean calc-alkaline provinces, exhibit very fractionated REE patterns with depleted HREE contents, a feature considered to result from equilibrium with garnet at depth in lower crustal regions. The geochemistry of the Pilbara Archaean calc-alkaline rocks is identical to the subset of modern continental-margin calc-alkaline plutonic rocks with fractionated REE patterns, such as those from the central and eastern Peninsular Ranges Batholith, western USA. The tectonic setting in which the Archaean calc-alkaline rocks formed is still not known. This reflects both uncertainty associated with the petrogenesis and environments of modern calc-alkaline rocks, as well as the limited knowledge of the precise timing and relationships of plutonic, depositional and tectonic events in the Pilbara Archaean.     

Paragenetic relations in gedrite — cordierite — staurolite — biotite sillimanite — kyanite gneisses at Ajitpura,Rajasthan, India

Aluminous parageneses containing gedrite, cordierite, garnet, staurolite, biotite, sillimanite, kyanite, quartz or spinel plus corundum are found as dark colored lenses in the polymetamorphic, multideformed Archean complex at Ajitpura in northwest peninsular India. Staurolite, like kyanite, is a relict phase of earlier metamorphism and is excluded as a paragenetic mineral in view of its incompatibility with quartz and gedrite and its lower X _Mg values than for garnet of the assemblage. Its stability here is attributed to zinc content of up to 3 wt%. The XMg in other ferromagnesian minerals decreases in the order: cordierite, biotite, gedrite, garnet, as found elsewhere in high grade rocks.The textural criteria and systematic partitioning of Fe and Mg in the ferromagnesian phases, excluding staurolite, indicate attainment of equilibrium during the second metamorphism. From tie line configurations in the phase diagrams, X _Mg ratios in the constituent minerals, and other petrographic criteria, it is suggested that gedrite — cordierite-garnet — sillimanite — biotite assemblage has been produced by the reactions: Biotite+Sillimanite+Quartz = Cordierite+Garnet+K-feldspar+Vapor (1) and Biotite+Sillimanite+Quartz = Cordierite +Gedrite+K-feldspar+Vapor (2) which occurred during partial melting of the rocks at fixed P and T conditions.By isothermal P-X(Fe-Mg) sections it has been demonstrated that release of FeO, SiO₂ and other components modified the composition of the reactant biotite presumably by the substitution FeSi2 Al, whereby reaction 1 was replaced by reaction 2. Cordierite with higher X _Mg was produced with gedrite instead of with garnet, whose X _Mg is less than X _Mg of gedrite. Reaction 2 has been tentatively located in T-P space from the intersection of some continuous loops in the P-X(Fe-Mg) diagram at 700°C and also by other constraints. The discontinuous reaction 2 is located about 1–2 kilobars higher than reaction 1, which implies that it is difficult to distinguish between effects of pressure and those of melting on the X _Mg ratios of the reaction phases.The P-T calibrations of garnet — cordierite, garnet — biotite and garnet — plagioclase equilibria and the calibrations from other dehydration curves give temperatures near 700°C and pressure (assuming ) about 6 kilobars.     

Magnetic polarity stratigraphy of the Upper Siwalik deposits,Pabbi Hills,Pakistan

Over 1000 m of fluvial molasse, exhibiting a stable detrital remanent magnetization, is exposed in a mammal-bearing sequence in the Upper Siwalik Group of the Pabbi Hills, Pakistan. The magnetic polarity chronology reveals that the sequence records a time period of 2.6 m.y., extending from the early Gauss Normal Epoch into the Brunhes Normal Epoch. During this period, sedimentation rates increased upward in time from 0.25 m/1000 yr to 0.45 m/1000 yr. The sudden disappearance of red beds and a change in the lithoclastic composition of basal channel sands suggests that about 800,000 years ago the primary source area began shifting from the metamorphic terrane of the Himalayan Orogen to a more local sedimentary terrane on the folded margins of the Himalayan foredeep. About 500,000 years ago the anticlinal Pabbi Hills attained surface expression. Uplift continued at a minimum rate of 1 m/1000 yr.A local Pliocene/Pleistocene boundary based on the Olduvai Normal Event is clearly recognized. Local fossil finds reveal thatEquus, diagnostic element of the Pinjor faunal zone, appeared locally about 1.8 m.y. ago and thatHipparion, a faunal element of the Tatrot and earlier faunal zones, persisted locally until at least 3.0 m.y. ago.     

Strontium isotopic contamination and oxidation during ocean floor hydrothermal metamorphism of the ophiolitic rocks of the Troodos Massif,Cyprus

Twenty-six new high precision ${}^{87}\text{Sr}{}^{86}\text{Sr}$ratio determinations and existing analyses are used to discuss the strontium isotopic composition of the Upper Cretaceous ophiolitic rocks of the Troodos Massif, Cyprus. Relative to initial magmatic ${}^{87}\text{Sr}{}^{86}\text{Sr}$ ratios (0.70338 ± 0.00010 to 0.70365 ± 0.00005), the hydrothermally metamorphosed pillow lavas and dyke complex have been contaminated by isotopically heavier strontium.This observation confirms the hypothesis that hydrothermal metamorphism was a consequence of sea water-rock interaction, since sea water was the only readily accessible reservoir of isotopically heavier strontium. The fact that metagabbros and altered trondhjemites were also Sr isotopically contaminated shows that sea water penetrated approximately 2 km into the oceanic crust represented by the ophiolitic sequence.The amount of Sr isotopic contamination requires that the bulk sea water: rock ratio was at least ~15:1 and shows that water-rock interaction occurred in a flow system. The degree of oxidation decreases with increasing depth. This shows that the vertical component of fluid flow was downward. The absolute bulk water/rock ratio (for water at S.T.P.), as estimated from the oxidation profile, may have been as large as ~3 × 10³:1 —a large figure which independently confirms that rocks showing strong δ¹⁸O shifts have interacted with large volumes of water.The sites of discharge of the hot fluid, which must have come out of the system, are identified as the cupriferous pyrite ore deposits. This process of mass transfer corresponds to hydrothermal convection in a permeable medium with an open upper boundary surface.     

40Ar/39Ar age and thermal history of the Kirin chondrite

The Kirin meteorite, a large (2800kg) H5 chondrite, fell in Kirin Province, China in 1976. A sample from each of the two largest fragments (K-1, K-2) yield⁴⁰Ar/³⁹Ar total fusion ages of 3.63 ± 0.02b.y. and 2.78 ± 0.02b.y. respectively.⁴⁰Ar/³⁹Ar age spectra show typical diffusional argon loss profiles. Maximum apparent ages of 4.36 b.y. (K-1) and ～4.0 b.y. (K-2) are interpreted as possible minimum estimates for the age of crystallization of the parent body.The⁴⁰Ar/³⁹Ar ages found for gas released at low temperature are about 2.2 b.y. for K-1 and about 0.5 b.y. for K-2, suggesting that this meteorite may have suffered two discrete collisional events that caused degassing of radiogenic argon. Modelling of possible thermal events in the parent body indicates that samples K-1 and K-2 were at a depth of less than 3 m from the base of an impact melt of a thickness less than 7 m and separated by no more than ～2 m from one another at the time of the heating event about 0.5 b.y. ago. Further, the duration of heating was probably less than a few years.Calculations from³⁸Ar data yield exposure ages for samples K-1 and K-2 of about 5 m.y., similar to that found for many other H chondrites.     

Long wavelength thermal convection between non-conducting boundaries

Non-linear Rayleigh-Bénard convection in a fluid layer is considered as a model of convection in the Earth's upper mantle. Previous studies have shown that when the temperature is held fixed at one of the boundaries of the layer, convection takes place in cells of width of the order of the layer depth or less. We investigate the effects of a different thermal boundary condition, in which the flux of heat is held fixed on both layer boundaries; then if this flux is just greater than that required for the onset of convection, motion takes place on horizontal scales much greater than the layer depth. An analytical treatment of the equations, based on an expansion in the depth-to-width ratio of the cells, shows that cells of a definite horizontal scale are the fastest growing according to linearised theory, but that these cells are unstable to ones of larger wavelength than themselves. Thus the dominant wavelength lengthens with time. The results hold whether the heat flux is generated internally of comes from beneath the layer. These results produce flow patterns similar to those found when the heat flux is much greater than the critical value. The results have important consequences for the understanding of mantle convection.     

The Early Carboniferous paleomagnetic field of North America and its bearing on tectonics of the Northern Appalachians

We have obtained additional evidence for the Early Carboniferous paleomagnetic field for cratonic North America from study of the Barnett Formation of central Texas. A characteristic magnetization of this unit was isolated after thermal demagnetization at four sites (36 samples) out of eight sites (65 samples) collected. The mean direction of declination = 156.3°, inclination = 5.8° (N = 4 ,k = 905 , α₉₅ = 3.0°), corresponds to a paleomagnetic pole position at lat. = 49.1°N,long. = 119.3°E (dp = 1.5° , dm = 3.0°). Field evidence suggests that characteristic magnetization was acquired very early in the history of the rock unit whereas the rejected sites are comprised of weakly magnetized limestones dominated by secondary components near the present-day field direction. Comparison of the Barnett pole with other Early Carboniferous (Mississippian) paleopoles from North America shows that it lies close to the apparent polar wander path for stable North America and that the divergence of paleopoles from the Northern Appalachians noted previously for the Devonian persisted into the Early Carboniferous. We interpret this difference in paleopoles as further evidence for the Northern Appalachian displaced terrain which we refer to here as Acadia, and the apparent coherence of Late Carboniferous paleopoles as indicating a large (～1500 km) motion of Acadia with respect to stable North America over a rather short time interval in the Carboniferous.     

Pyrope-spinel (alkremite) xenoliths from kimberlite

Xenoliths consisting of two thirds pyrope (Py₇₃Alm₁₄Gr₁₃-Py₁₅Alm₁₈Gr₃₁) and one third hercynite-bearing spinel with minor chromium, from Bellsbank and Jagersfontein kimberlites, South Africa, are compared with similar rocks, alkremites, from the Udachnaya pipe, U.S.S.R. From published experimental data and textural relationships these formed as early dense cumulates in aluminous mantle melts under restricted pressure conditions equivalent to about 75 km depth. At greater pressures very pyrope-rich garnets (Py₈₀) are capable of being formed. The garnet spinel xenoliths are considered to have become separated from the magma prior to crystallisation of clinopyroxene, whereas complete uninterrupted fractionation and reaction would produce the more common griquaites (eclogites).     

Rare-gas-rich separates from carbonaceous chondrites

Samples studied were residual, carbonaceous /Alates—a coined word to designate colloids prepared sometimes before and sometimes after acid demineralization—from Murray, Murchison, Cold Bokkeveld (type C2s) and Allende (type CV3) meteorites. Characterization: C2 /Alates, comprising 0.5% of the bulk meteorite are fine-grained (< 100 Å), amorphous, sulfide-free, oxidizable, 95% carbonaceous materials which pyrolyze bimodally at 200–700 and 800–1200°C. Allende /Alates are similar but with traces of inferred spinel and chromite and of sulfur, Rare gas results: Elemental: Release from stepwise heated Murray is bimodal with maximum release and upper temperature peak at 1000°C, probably accompanying chemical reaction. All /Alates studied had very nearly the same elemental concentrations, distinctly planetary in pattern. Isotopic: Trapped neon compositions are unprecedentedly close to Pepin's neon-A corner but nevertheless show signs of complexity, as if accompanied by neon-E. The trapped ³He/⁴He ratio is essentially constant at (1.42 ± 0.2 × 10^?4. The isotopically anomalous heavy noble gases, easily detected in the residues of oxidized /Alates, were not conspicuous in this particular study. Comparison and Chicago results: Concentrations of heavy rare gases in our /Alates agree with concentrations measured directly (as opposed to inferred by difference) in acid resistant residues at Chicago. Alone, our results support the idea of a carbonaceous gas-carrier uniformly present in meteorites of various types, but Chicago characterizations of the samples can apply to both their samples and ours provided that the right amount of gas was lost in the Berkeley procedures to make the uniform gas contents in various samples a coincidence.