Arsenic and presumed resistate trace element geochemistry of the Lincolnshire (UK) sedimentary ironstones,as revealed by a regional geochemical survey using soil,water and stream sediment sampling

A regional geochemical survey using soils, stream sediment and stream water sampling revealed multi-element geochemical anomalies, though of low environmental mobility, associated with Mesozoic sedimentary ironstones in Lincolnshire, UK. The most prominent of these anomalies were of As and V in soils and sediments, but elevated levels of elements such as Cr, La, Ce and Th were also observed. These were initially thought to be part of a residual resistate element or heavy-mineral suite, but careful examination suggests that these too may be primarily associated with the process of Fe oxide precipitation during the initial formation of the ironstones.     

Interpreting the Ca isotope record of marine biogenic carbonates

An 18 million year record of the Ca isotopic composition (δ^44/42Ca) of planktonic foraminiferans from ODP site 925, in the Atlantic, on the Ceara Rise, provides the opportunity for critical analysis of Ca isotope-based reconstructions of the Ca cycle. δ^44/42Ca in this record averages +0.37 ± 0.05 (1σ SD) and ranges from +0.21‰ to +0.52‰. The record is a good match to previously published Neogene Ca isotope records based on foraminiferans, but is not similar to the record based on bulk carbonates, which has values that are as much as 0.25‰ lower. Bulk carbonate and planktonic foraminiferans from core tops differ slightly in their δ^44/42Ca (i.e., by 0.06 ± 0.06‰ (n = 5)), while the difference between bulk carbonate and foraminiferan values further back in time is markedly larger, leaving open the question of the cause of the difference. Modeling the global Ca cycle from downcore variations in δ^44/42Ca by assuming fixed values for the isotopic composition of weathering inputs (δ^44/42Ca_w) and for isotope fractionation associated with the production of carbonate sediments (Δ_sed) results in unrealistically large variations in the total mass of Ca²⁺ in the oceans over the Neogene. Alternatively, variations of ±0.05‰ in the Ca isotope composition of weathering inputs or in the extent of fractionation of Ca isotopes during calcareous sediment formation could entirely account for variations in the Ca isotopic composition of marine carbonates. Ca isotope fractionation during continental weathering, such as has been recently observed, could easily result in variations in δ^44/42Ca_w of a few tenths of permil. Likewise a difference in the fractionation factors associated with aragonite versus calcite formation could drive shifts in Δ_sed of tenths of permil with shifts in the relative output of calcite and aragonite from the ocean. Until better constraints on variations in δ^44/42Ca_w and Δ_sed have been established, modeling the Ca²⁺ content of seawater from Ca isotope curves should be approached cautiously.     

Dating alluvial deposits with optically stimulated luminescence, AMS C and cosmogenic techniques, western Transverse Ranges, California, USA

In an effort to better understand chronology of alluvial episodes in Cuyama Valley in the western Transverse Ranges of California, USA, we employed optically stimulated luminescence, radiocarbon and cosmogenic radionuclide surface exposure dating methods. Twenty-one optical dates ranging from 0.01 to 27 ka were obtained from exposures of late-Holocene axial-fluvial deposits, Pleistocene–Holocene alluvial-fan deposits, and axial-fluvial sands interbedded within a late Pleistocene alluvial fan. These were cross-checked with 37 AMS radiocarbon dates from charcoal and wood from within a and five ¹⁰Be surface exposure dates from boulders on alluvial-fan surfaces. The OSL results show generally good stratigraphic consistency, logical comparison with the radiocarbon and cosmogenic data, and appear to be the best method for accurate dating within deposits of this nature because suitable material is fairly easy to find in these environments. The radiocarbon data contained numerous “detrital ages”, but well-bedded lenses of apparently in situ or minimally transported charcoal provide reliable age estimates for the associated alluvium. Radiocarbon dating of detrital charcoal in the older alluvial fan deposits was problematic. Our cosmogenic surface-exposure dating was consistent stratigraphically and with our other data, but we were unable to determine its accuracy due to the limited number of samples and the possibility of inherited radionuclides and post-depositional erosion. In light of our results, we suggest that OSL dating using the latest analytical techniques combined with rigorous methods for estimation of paleodase is reliable and of increasing utility in otherwise difficult-to-date coarse alluvial environments in the southwestern United States and elsewhere.     

基于高光谱遥感数据提取森林结构参数的研究

以位于三峡库区的龙门河森林自然保护区为研究区,综合利用线性光谱混合模型和几何光学模型,基于高光谱遥感数据提取森林结构参数是本文研究的重点。在研究区地面调查数据的基础上,通过高光谱数据和混合光谱分解法,获得反演几何光学模型所需的四分量参数,根据背景光照分量与森林植被冠层各参数间的关系,反演得到森林冠层郁闭度及平均冠幅的定量分布图,并利用37个野外实测样本进行结果验证。     

An SEM study of porosity and grain boundary microstructure in quartz mylonites, Simplon Fault Zone, Central Alps

A backscattered and secondary electron SEM study of the grain boundary microstructure in quartz mylonites sampled along the length of the retrograde Simplon Fault Zone established three characteristic components. (1) Fine isolated pores (≤?1?μm diameter) are scattered across two-grain interfaces, preferentially concentrated on surfaces in extension. Pores are uncommon on three-grain junctions and there is no evidence for fluid interconnectivity along three- and four-grain junctions. The fine porosity may develop by accumulation of original, mainly intragranular fluid inclusions to the grain boundary during deformation and recrystallization and by cavitation of grain boundaries during grain boundary sliding. Dynamic cavitation implies that the “ductile” mylonitic deformation is at least locally dilatant and therefore pressure sensitive. (2) Large “vug”-like pores (up to mm-scale) extend along multi-grain boundaries. Observed in all samples, they are most common in the higher initial temperature, coarse-grained samples with a microstructure dominated by grain boundary migration recrystallization. Grains bordering this connected porosity develop perfect crystal faces, undecorated by fine pores or pits. The irregular “lobate” optical microstructure of many migrating grain boundaries actually consists of a series of straight crystal faces. The coarse porosity is probably due to accumulation during dynamic recrystallization of (CO₂-rich ?) fluid with a high wetting angle against quartz. (3) In one sample, interconnected sinuous ridges, ≤?0.2?μm high, are observed to follow three- and four-grain junctions and disjoint into more isolated worms and spheroidal globules. On two-grain interfaces, these are transitional to more branching vein-like or convoluted brain-like forms. The brain-like and globular forms have been observed, with varying frequency, through the range of samples, with the globules attaining sizes of up to 60?μm. Vein structures have also been observed on intragranular fractures. These topologies do not match across adjoining surfaces and must have developed into free space. The ridge-vein-brain-spheroid structure is distinctly different to that previously observed on experimentally healed microcracks and its origin is not unequivocally established. They could represent unstable meniscus necking of a thin grain-boundary phase of low viscosity, developed due to quasi-adiabatic shear and/or local stress-induced dilatancy during microcracking.     

A comparison of estimated and calculated effective porosity

 Effective porosity in solute-transport analyses is usually estimated rather than calculated from tracer tests in the field or laboratory. Calculated values of effective porosity in the laboratory on three different textured samples were compared to estimates derived from particle-size distributions and soil–water characteristic curves. The agreement was poor and it seems that no clear relationships exist between effective porosity calculated from laboratory tracer tests and effective porosity estimated from particle-size distributions and soil–water characteristic curves. A field tracer test in a sand-and-gravel aquifer produced a calculated effective porosity of approximately 0.17. By comparison, estimates of effective porosity from textural data, moisture retention, and published values were approximately 50–90% greater than the field calibrated value. Thus, estimation of effective porosity for chemical transport is highly dependent on the chosen transport model and is best obtained by laboratory or field tracer tests. Received, March 1997 · Revised, August 1997 · Accepted, August 1997     

The dwarf galaxy population of the Coma cluster to MR=−11: a detailed description

We present the luminosity function and measurements of the scalelengths, colours and radial distribution of dwarf galaxies in the Coma cluster down to R =24. Our survey area is 674 arcmin²; this is the deepest and most detailed survey covering such a large area.
Our measurements agree with those of most previous authors at bright and intermediate magnitudes. The new results are as follows.
(1) Galaxies in the Coma cluster have a luminosity function φ( L )∝ L ^α that is steep (α∼−1.7) for −15< M_R <−11, and is shallower brighter than this. The curvature in the luminosity function at M_R ∼−15 is statistically significant.
(2) The galaxies that contribute most strongly to the luminosity function at −14< M_R <−12 have colours and scalelengths that are consistent with those of local dwarf spheroidal galaxies placed at the distance of Coma.
(3) These galaxies with −14< M_R <−12 have a colour distribution that is very strongly peaked at B − R =1.3. This is suggestive of a substantial degree of homogeneity in their star formation histories and metallicities.
(4) These galaxies with −14< M_R <−12 also appear to be more confined to the cluster core ( r ∼200 kpc) than the brighter galaxies. Alternatively, this observation may be explained in part or whole by the presence of an anomalously high number of background galaxies behind the cluster core. Velocity measurements of these galaxies would distinguish between these two possibilities.     

The galaxy luminosity function in clusters and the field

We present the results from a CCD survey of the B -band luminosity function of nine clusters of galaxies, and compare them to published photographic luminosity functions of nearby poor clusters like Virgo and Fornax, and also to the field luminosity function. We derive a composite luminosity function by taking the weighted mean of all the individual cluster luminosity functions; this composite luminosity function is steep at bright and faint magnitudes and is shallow in-between.
All clusters have luminosity functions consistent with this single composite function. This is true both for rich clusters like Coma and for poor clusters like Virgo.
This same composite function is also individually consistent with the deep field luminosity functions found by Cowie et al. and Ellis et al., and also with the faint end of the Las Campanas Redshift Survey R -band luminosity function, shifted by 1.5 mag. A comparison with the Loveday et al. field luminosity function, which is well determined at the bright end, shows that the composite function, which fits the field data well fainter than M _B=−19, drops too steeply between M _B=−19 and −22 to fit the field data there.     

Evolution of the near-infrared in rich galaxy clusters

We present the K -band (2.2 μm) luminosity functions (LFs) of the X-ray-luminous clusters MS1054–0321 ( z  = 0.823), MS0451–0305 ( z  = 0.55), Abell 963 ( z  = 0.206), Abell 665 ( z  = 0.182) and Abell 1795 ( z  = 0.063) down to absolute magnitudes M _K  = −20. Our measurements probe fainter absolute magnitudes than do any previous studies of the near-infrared LFs of clusters. All the clusters are found to have similar LFs within the errors, when the galaxy populations are evolved to redshift z  = 0. It is known that the most massive bound systems in the Universe at all redshifts are X-ray-luminous clusters. Therefore, assuming that the clusters in our sample correspond to a single population seen at different redshifts, the results here imply that not only had the stars in present-day ellipticals in rich clusters formed by z  = 0.8, but that they existed in as luminous galaxies then as they do today.   Additionally, the clusters have K -band LFs which appear to be consistent with the K -band field LF in the range −24 <  M _K  < −22, although the uncertainties in both the field and cluster samples are large.     

Holocene alluvial stratigraphy in the upper Susquehanna River Basin, New York

Two alluvial terraces and the present flood plain were studied at two locations along the Susquehanna and Unadilla Rivers in south-central New York state. They have formed since deglaciation and incision of the stream channels into the valley train deposits. The higher terrace has noncumulative soil profiles with well-developed color B horizons predominantly of silt loam and very fine sandy loam. The terrace is weathered to a degree similar to nearby glacial outwash terraces that have caps of similarly textured sediments. Incision that produced the terrace occurred before 9705 ± 130 yr B.P. The lower terrace is characterized by relatively thick, vertical-accretion deposits of silt loam that contain sequences of thin, buried A, color B, and C horizons. They were formed between about 3240 ± 110 (¹⁴C data of soil humin) and 235 ± 80 yr B.P. Deposits above the 235 ± 80 yr B.P. stratum are unweathered. The soil stratigraphy and ¹⁴C dates of soil humin from buried A horizons are surprisingly well correlated between sites. Most sediments of the present flood plain have been deposited since 1120 ± 80 yr B.P. Incipient A horizons and oxidation of inherited organic matter in the subsoil are the only evidence of pedogenesis in the flood-plain deposits that are older than 275 ± 80 yr B.P. The most recent flood-plain fill deposited since then is unaltered. These youngest sediments of the flood plain along with the youngest veneer of vertical-accretion deposits on the lowest terrace are associated with an increased rate of deposition largely attributable to clearing of the forests by settlers, beginning in the late 1700s. Comparison of the alluvial stratigraphy with the radiocarbon-dated pollen stratigraphy of southwestern New York (Miller 1973) reveals some apparent time correlations between alluvial events and vegetation changes. This gives reason to speculate that climatic change or forest catastrophes such as disease or drought are causes of some of the alluvial events.