Photo-induced degradation of emamectin benzoate: effect of iron amendments and solvent system

Photodegradation is the major dissipation pathway for emamectin benzoate (EB) in water. Therefore, the photolysis of EB was studied in distilled water (DW) and methanol under different irradiation conditions such as natural sunlight, UV tube, and artificially stimulated light (mercury lamp 125 W). The results of the study showed that EB degrades rapidly in DW than in methanol as evidenced by a photodegradation efficiency of about 75 % achieved in DW, after 24 h of irradiation with UV light, while in methanol, it was only 59.3 %. The addition of iron to EB solution in DW further enhanced its photodegradation. The rate of photodegradation of EB was recorded to be increased from 5.5 × 10^?2 to 1.0 × 10^?1 k/h after amendment with iron. The order for the rate of photodegradation of EB was DW + Fe > DW > methanol, with their respective t _1/2 values of 6.5, 12.6, and 18.7 h. Fe amendment was also found to enhance the degradation efficiency of EB even in the absence of any light (dark).     

A bibliometric-based evaluation on environmental research in the Arab world

The Arab world’s environment is among the most vulnerable and harsh ones across the globe. This entails much efforts to mitigate the potential environmental risks. Analysing contributions of Arab scholars in environmental research in terms of quantity and quality can bring up insights on their endeavours in this regard. Bibliometric techniques are proposed to conduct such this analysis over publications originated from Arab world in a leading environmental journal “Science of the Total Environment”. Research productivity is being used as quantitative indicator, while citation rates and Hirsch index (h-index) are being used as qualitative indicators. The research outputs were compared with those obtained from non-Arab Middle Eastern countries (Iran, Turkey and Israel). Worldwide research productivity was 17,258 documents, while that from Arab countries, Iran, Turkey and Israel were 215, 34, 83 and 87 documents, respectively. The h-index of Arab world research was 31, and total citations were 3616 with an average of 16.8. The highest share of publications was recorded by Saudi Arabia (53 documents; 24.7%). Egypt and Saudi Arabia had highest h-index with 15 for each one. American University of Beirut in Lebanon was the highest productive institution (16; 7.4%). The most collaborated country with Arab world was France (29; 13.5%). In the conclusion, the study reveals a clear gap in terms of research productivity between Arab countries and other Middle Eastern countries, precisely Israel and Turkey. More research efforts through optimizing investments in environmental research, developing regional experiences and fostering international collaboration are required to eliminate these lags.     

巴基斯坦山达克矿区ASTER遥感数据、蚀变信息提取及找矿预测

巴基斯坦查盖火山岩浆岩带属于特提斯成矿域的重要组成部分之一,是巴基斯坦境内最重要的斑岩型铜矿带,但目前其相关的遥感研究还较少,制约了对该成矿带的找矿潜力分析。笔者等以山达克矿床及其周边为研究区,对先进星载热辐射与反射辐射计(Advanced Spaceborne Thermal Emission and Reflection Radiometer, ASTER)数据进行RBD (Relative absorption band depth)比值假彩色合成、主成分分析、光谱角制图等处理,获得蚀变遥感异常信息分布特征,通过对蚀变特征和主要控矿要素进行遥感研究,建立了山达克矿床遥感找矿模型并开展成矿预测,为该成矿带矿产勘查提供借鉴。根据建立的遥感找矿模型,圈定了找矿预测靶区10处。对矿区东矿体和矿区北部的2个靶区进行野外验证,证实了提取结果与实际地质事实吻合较好,对矿区岩石样品进行光谱实测,表明样品实测光谱曲线与标准矿物光谱曲线的吸收特征位置高度相似,证实了研究区绢云母化、青磐岩化等蚀变较强且分布较广。结果表明本次研究提取的矿化蚀变结果可信度较高,可为后续找矿勘查工作提供参考。     

A Study of Largest Active Region AR12192 of 24th Solar Cycle Using Fractal Dimensions and Mathematical Morphology

Solar System Research - An active region (AR) of the sun is an area of strong magnetic field. Sunspots are frequently formed in an AR. Solar activity exhibits in the form of solar flares and...     

Metabolic and physiological regulation of Chlorella sp. (Trebouxiophyceae,Chlorophyta) under nitrogen deprivation

Journal of Oceanology and Limnology - A freshwater green microalgae Chlorella sp., UMACC344 was shown to produce high lipid content and has the potential to be used as feedstock for biofuel...     

Treating Leather Tanning Wastewater with Stone Cutting Solid Waste

This paper presents a new environmental approach for reducing environmental impacts of two local Palestinian industries: It implements the principle of “treating waste by waste.” The technical feasibility of chromium removal from wastewater in leather making by its treatment with solid waste from stone cutting industry is demonstrated experimentally, and found to be an efficient approach. Nearly full removal of chromium is obtained at optimum operating conditions using sufficient mass of solid waste (limestone) and allowing enough contact time between the two wastes. This study investigated effects of various parameters on the percentage relative decrease in concentration by using ultra violet (UV)/Vis spectrophotometry. Kinetic curves showed that percentage relative decrease in concentration increased with time until approaching a plateau (adsorption capacity). The adsorption capacity increased with increasing limestone to liquid ratio (solid content), until nearly full removal of chromium was obtained when the solid content was 5 g/100 mL or higher. This was accomplished within few days when the particles were settled. The adsorption capacity was pH dependent; adsorption at pH < 5 was obtained, as a finding which was not reported by previous investigators for Cr(III) adsorption using other particles. The percentage removal was nearly doubled at higher pH values (>5). Further research work is proposed to distinguish between the contributions of the two removal mechanisms of precipitation and adsorption.     

Suitability of AuRM2 as a Reference Material for Trace Element Microanalysis of Native Gold

Microanalysis of native gold specimens has been hampered by the lack of a suitable reference material (RM) known to be sufficiently homogeneous at the scale of microanalytical sampling. The suitability of gold reference material AuRM2 for microanalysis was assessed. This RM was created for bulk analysis of refined gold and was only certified for homogeneity at the bulk scale. However, it contains trace elements in appropriate mass fraction ranges for analysis of native gold. This study was not intended to provide alternative mass fractions from the original certified values, only to assess its suitability for microanalytical methods. Micro‐scale (~ 3.4 μg sample mass) heterogeneity was calculated from measurement repeatability of LA‐ICP‐MS analyses of AuRM2 by factoring in signal (represented by counting statistics) and instrument set‐up‐specific variability (determined using measurement variability of a reference material known to be homogeneous). Elements determined to be homogeneous or to have minor heterogeneity (< 10% calculated heterogeneity RSD) are Mg, Al, Ti, Fe, Ni, Cu, Zn, Se, Rh, Sn, Sb, Pt and Pb. Elements with moderate heterogeneity (10–20% heterogeneity RSD) are: Mn, As, Pd, Te and Bi. Correlation of element mass fractions indicates that micro‐scale inclusions of chalcophile‐rich phases along grain boundaries may be responsible for some of the chemical heterogeneity. However, the level of heterogeneity is statistically negligible compared with the ranges of chemical signatures observed in sample populations of native gold. Therefore, AuRM2 is shown to be sufficiently homogenous at a micro‐scale for use as a RM for microanalysis of native gold.     

The probability distributions and fractal dimension of sunspot cycles associated with ENSO phenomena

Various methods have been used to secure the certainty of significant relations among the sunspot cycles and some of the terrestrial climate parameters such as temperature, rainfall, and ENSO. This study investigates the behavior of ENSO cycles and mean monthly sunspot cycles. Sunspot cycles range from 1755 to 2016 whereas, ENSO cycles range from 1866 to 2012. In this regard, the appropriateness of distributions is investigated with the help of Kolmogorov-Smirnov D, Anderson-Darling, and chi-square tests. It is found that most of the sunspot cycle follows generalized Pareto distribution whereas, generalized extreme value distribution was found appropriate for ENSO cycles. Probability distribution is used to analyze the behavior of each sunspot cycle and ENSO cycle separately. Probability distribution indicates the tail behavior of each cycle; tail explored correlation cycles. Furthermore, self-similar and self-affine fractal dimension methods are used to compute Hurst exponents to determine the persistency of the available data. Fractal dimension has an ability to study the complexity involved in sunspot and ENSO cycles. The fractal dimension and Hurst exponent describe persistency (smoothness) and complexity of data. Hurst exponent measures long-term behavior of time series, making it more helpful for forecasting. This is the measure of regularity or irregularity (chaos) of the time function in the form of their persistency or anti-persistency, respectively. Hurst exponents are computed using rescaled range analysis method and box counting methods. Both these methods are suitable for long-term forecasting. The results of this study confirm that during the period 1980–2000, ENSO cycles were very active. Simultaneously, ENSO was active for the periods 1982–1983, 1986–1987, 1991–1993, 1994–1995, and 1997–1998; these periods include two strongest periods of the century viz., 1982–1983 and 1997–1998. Sunspot cycles and ENSO cycles both were found to be persistent. Self-similar fractal dimensions exhibited a better persistency and a better correlation as compared to self-affine fractal dimension. This research is a part of a larger research project investigating the correlation of sunspot cycles and ENSO cycles, and the influence of ENSO cycles on variations of the local climatic parameters which in turn depends on solar activity changes.