Fluoride ion contamination in the groundwater of Mithi sub-district, the Thar Desert, Pakistan

Groundwater samples were collected from various localities of Mithi sub-district of the Thar Desert of Pakistan and analysed for fluoride ion along with other chemical parameters. The area is mainly covered by sand dunes and kaolin/granite at variable depths. Results showed that collected water samples were severely contaminated by the presence of fluoride ion and most of the samples have higher concentration than prescribed WHO standards (1.5 mg/l) for drinking water. Fluoride ion concentrations ranged between 0.09 and 11.63 mg/l with mean and median values of 3.64 and 3.44 mg/l, respectively, in this area whereas, distribution pattern showed high concentrations in the vicinity of Islamkot and Mithi towns. The content of F⁻ has also been correlated with other major ions found in the groundwater of the study area. The positive correlation of F⁻ with Na⁺ and HCO₃ ⁻ showed that the water with high Na⁺ and HCO₃ ⁻ stabilizes F⁻ ions in the groundwater of the Thar Desert. The pH versus F⁻ plots signifies high fluoride concentration at higher pH values, implying that alkaline environment favours the replacement of exchangeable OH⁻ with F⁻ in the groundwater of Mithi area. The saturation indices (SI) of fluorite (CaF₂) and calcite (CaCO₃) in the groundwater samples showed that most of the samples are oversaturated with respect to calcite whereas majority of samples have been found under saturated with respect to fluorite. The log TDS and Na/Na+Ca ratio reflected supremacy of weathering of rocks, which promotes the availability of fluoride ions in the groundwater. Piper diagram has been used to classify the hydrofacies. In the cation triangle, all samples are Na-type, while the anion triangle reflects major dominance of Cl-type with a minor influence of HCO₃ ⁻ and SO₄ ⁻.     

Exploring Placer Gold Deposits through Integrated Geophysical and Geochemical Techniques at the Confluence of the Indus and Kabul Rivers, NW Pakistan

Analysis of the anomalous magnetic mineral intensities and geochemistry for placer gold deposits are presented for those of the Attock area at the confluence of the Indus and Kabul rivers in northwestern Pakistan. Two grids covering an area of 10x18 m2 and 8x10 m2 were analyzed using a G-858 Cesium Vapor Magnetometer. The anomalous zones obtained were plotted on contour maps, 2D and 3D magnetic intensity maps. Based on the magnetic anomalies, grid-1 of the study area was sampled at three different anomalous zones for geochemical analysis. These zones contain gold concentrations, ranging from 2.11 ppm to 6.109 ppm with an average of 4.01 ppm. Increase in gold concentration in the subsurface within the anomalous zones indicates that magnetometer survey followed by a geochemical analysis can potentially narrow down the gold-bearing anomalous zones.