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11.
R.R. Reddy Y. Nazeer Ahammed K. Rama Gopal D. Baba Basha 《Astrophysics and Space Science》2003,286(3-4):419-436
The experimental potential energy curves for the different electronic states of molecules like CN, CO and CS observed in comets
are constructed by using the Rydberg-Klein-Rees method as modified by Vanderslice et al. The ground state dissociation energies
are determined by curve fitting technique using the five parameter Hulburt-Hirschfelder (H-H)function. The estimated dissociation
energies are 7.63 ± 0.187, 10.95 ±0.224 and 7.27 ± 0.152 eV for CN, CO and CS respectively. These values are in good agreement
with the literature values. Estimated dissociation energies of CN, CO and CS are used in the relation given by Gaydon and
ionization potentials are evaluated for CO and CS molecules. The estimated ionization potentials are 13.92and 12.15 eV for
CO and CS molecules respectively. The r-centroids and Franck-Condon factors (FC Factors) for the band system of a 3Πr – X1Σ+ (a – X) and A1Π – X 1Σ+ (A -X) of CN, A 2Πi – X2Σ+ (A – X) and B2Σ+-X2Σ+ (B – X) of CO and a 3Πr – X1Σ+ (a – X) of CS molecules have been calculated employing an approximate analytical methods of Jarmain and Fraser and Nicholls
and Jarmain. The absence of the bands in these systems are explained.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
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R.R. Reddy Y. Nazeer Ahammed K. Rama Gopal P. Abdul Azeem S. Anjaneyulu 《Astrophysics and Space Science》1998,262(2):223-240
The potential energy curves for the electronic ground states of astrophysically important YO, CrO, BN, ScO, SiO and AlO molecules are constructed techniques using the five-parameter Hulburt-Hirschfelder function. The estimated dissociation energies are 7.235±0.15, 4.337 ± 0.09, 3.917 ± 0.09, 6.899 ± 0.14, 8.181 ± 0.17 and 5.202 ± 0.11 eV for YO, CrO, BN, ScO, SiO and AlO, respectively. The estimated D0 values are in reasonably good agreement with literature values. The r-Centroids and Franck-Condon factors for the bands of B2 + – X2 + of YO, B5 –X5 > of CrO, A3 – X3 of BN, B2 + –X2 + of ScO, E1 + – X1 + of SiO and D2 + – X2 + and B2 + –X2 + of AlO molecules have been determined. The Franck-Condon factors are evaluated by the approximate analytical method of Jarmain and Fraser. The absence of the bands in these systems is explained. 相似文献
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