Fluorine geochemistry of quaternary volcanic rocks from Southwestern British Columbia: Some petrogenetic implications

Fluorine contents in 38 Quaternary volcanic rocks, representing calc-alkaline andesite eruptive groups from the Garibaldi Lake area, were determined by a selective ion-electrode method. A close relationship is evident between F abundance and the type of ferromagnesian phenocrysts present in the andesitic rocks. Hypersthene andesites have the lowest F contents (142–212 ppm), whereas hornblende-biotite andesites exhibit the highest F values (279–368 ppm); hornblende andesites have intermediate F contents (238–292 ppm). The hornblende-free Desolation Valley basaltic andesite has a lower F content than the hornblende-bearing Sphinx Moraine basaltic andesite (122 ppm versus 317–333 ppm).Different eruptive suites can be grouped on the basis of F differentiation patterns into (1) a hornblende-free lava series in which the F content of basaltic andesite is less than that of andesite, and (2) a hornblende-bearing lava series in which F contents remain constant or decrease slightly from basaltic andesite through dacite. Fluorine variation in the former series was controlled largely by fractionation of anhydrous minerals, whereas that in the latter was influenced by crystallization of amphibole, biotite and apatite.The distinctive F variation patterns of the two lava series appear to represent real differences in the volatile contents of Garibaldi Lake magmas. These different volatile concentrations may reflect varying degrees of magma-wallrock interaction, differences in the initial volatile contents of the primary magmas, or some combination of these factors.     

Last glacial maximum equilibrium-line altitude and paleo-temperature reconstructions for the Cordillera de Mérida, Venezuelan Andes

The pattern and magnitude of glacier equilibrium-line altitude (ELA) lowerings in the tropics during the last glacial maximum (LGM) are topics of current debate. In the northern tropics, paleo-ELA data are particularly limited, inhibiting the ability to make regional and large-scale paleoclimatic inferences. To improve these records, nine paleo-glaciers in the Venezuelan Andes were reconstructed based on field observations, aerial photographs, satellite imagery and high-resolution digital topographic data. Paleo-glacier equilibrium-line altitudes (ELAs) were estimated using the accumulation-area ratio (AAR) and the area-altitude balance ratio (AABR) methods. During the local LGM in Venezuela (∼ 22,750 to 19,960 cal yr BP), ELAs were ∼ 850 to 1420 m lower than present. Local LGM temperatures were are at least 8.8 ± 2°C cooler than today based on a combined energy and mass-balance equation to account for an ELA lowering. This is greater than estimates using an atmospheric lapse rate calculation, which yields a value of 6.4 ± 1°C cooler. The paleo-glacial data from the Venezuelan Andes support other published records that indicate the northern tropics experienced a greater ELA lowering and possibly a greater cooling than the Southern Hemisphere tropics during the LGM.     

Resource economies and neoliberal experimentation: the reform of industry and community in rural British Columbia

This paper argues that the current literature on neoliberalism in advanced capitalist societies has concentrated primarily on urban issues, and has thus failed to see resource economies and regions as theoretically significant sites of neoliberal reform. Using research from British Columbia, Canada, we argue that resource regions are often targets of intense neoliberal experimentation. The neoliberal project in British Columbia involves an extreme shift in state policy from a strong Fordist-Keynesian programme to recent efforts to 'liberate' corporate actors from non-market social and spatial obligations (to environment, labour and community). We argue that such policy shifts have exceptional consequences in resource regions due to strong and direct state influence in corporate-resource and community-level economies. We draw several theoretical lessons from this research for the mainstream literature on neoliberal reform.     

The influence of biogeochemical conditions and level of model complexity when simulating cometabolic biodegradation in sorbent-water systems

Eighteen models with different levels of complexity for representing sorption, mass transfer, and biodegradation are used to simulate the biodegradation of toluene (primary substrate) and TCE (cometabolic substrate). The simulations are conducted for hypothetical completely mixed systems of various scenarios with regard to sorbent, microbial composition, and solute concentrations. The purpose of the suite of simulations is to investigate the sensitivity of different modeling approaches in simulating the bio-attenuation of co-existing solutes in sorbent-water systems. The sensitivity of results to the modeling approach depends on the biogeochemical conditions of the system. For example, the results are insensitive to the type of sorption model in systems with low sorption strength and slow biodegradation rates, and insensitive to the biodegradation rate model if mass transfer controlled. Differences among model results are generally greater when evaluated in terms of total mass removal rather than aqueous phase concentration reduction. The fate of the cometabolite is more sensitive to the proper consideration of co-solute effects than is the fate of the primary substrate. For a given system, graphical comparison of a characteristic mass transfer rate coefficient (α_mt) versus a characteristic biodegradation rate coefficient (α_bio) provides an indication of how sensitivity to the different processes may be expected to change with time and can guide the selection of an appropriate level of model complexity.     

Morphology and surface brightness evolution of z∼1.1 radio galaxies

We use K '-band (2.1-μm) imaging to investigate the angular size and morphology of 10 6C radio galaxies, at redshifts 1≤ z ≤1.4. Two radio galaxies appear to be undergoing mergers, another contains, within a single envelope, two intensity peaks aligned with the radio jets, while the other seven appear consistent with being normal ellipticals in the K band.
Intrinsic half-light radii are estimated from the areas of each radio galaxy image above a series of thresholds. The 6C galaxy radii are found to be significantly smaller than those of the more radio-luminous 3CR galaxies at similar redshifts. This would indicate that the higher mean K -band luminosity of the 3CR galaxies reflects a difference in the size of the host galaxies, and not solely a difference in the power of the active nuclei.
The size–luminosity relation of the z ∼1.1 6C galaxies indicates a 1.0–1.6 mag enhancement of their rest frame R -band surface brightness relative to either local ellipticals of the same size or FRII radio galaxies at z <0.2. The 3CR galaxies at z ∼1.1 show a comparable enhancement in surface brightness. The mean radius of the 6C galaxies suggests that they evolve into ellipticals of L ∼ L * luminosity, and is consistent with their low-redshift counterparts being relatively small FRII galaxies ∼25 times lower in radio luminosity, or small FRI galaxies ∼1000 times lower in radio luminosity. Hence the 6C radio galaxies appear to undergo as much optical and radio evolution as the 3CR galaxies.     

The effective period and damping of a class of hysteretic structures

This paper presents the results of a numerical investigation in which the maximum response of six hysteretic systems is calculated for an ensemble of twelve earthquakes. Inelastic response spectra are constructed for a range of response ductility. An effective linear period and damping are calculated for each system and ductility by determining those parameters which minimize an RMS response spectrum error. Conclusions are presented concerning the effects of deterioration, stiffness degradation, cracking and ductility on the effective linear system parameters.     

Application of sedimentary and chronological analyses to refine the depositional context of a Late Pleistocene vertebrate deposit,Naracoorte, South Australia

Cave deposits of infill sediments and associated vertebrate fossils provide a valuable source of information on terrestrial palaeoenvironments, climatic conditions and palaeocommunities. In the deposits of the Naracoorte Caves World Heritage Area, such records span the last 500 ka and are renowned for their rich, diverse vertebrate assemblages. Previous research into the Grant Hall deposit of Victoria Fossil Cave suggested that it may preserve the only peak last interglacial (ca. 125 ka) faunal community within the World Heritage Area. The current work tested this existing model for the age of faunal remains from Grant Hall using multiple techniques. Physical and geochemical properties of the visually homogeneous sediments were analysed at regular intervals through the sequence to establish meaningful stratigraphic divisions and sediment provenance. Optically stimulated luminescence dating of individual quartz grains indicates that sediments accumulated in Grant Hall from 93 ± 8 to 70 ± 5 ka. Minimum ages provided by U/Th dating of fossil teeth (72.3 ± 2.2 to 38.2 ± 0.8 ka) are consistent with the luminescence chronology, and show that the deposit represents a more recent faunal accumulation than previously modelled for the site. U/Th ages on calcite straws within the deposit are significantly older than the sediments and fossil teeth (>500 to 186.4 ± 1 ka). As such they provide no further constraint on the chronology of the deposit but do indicate that speleothem deposition was active over much of the Middle Pleistocene. Sedimentary analyses resulted in the identification of five depositional units, contrasting with previous divisions which were based only on visual observation of the sedimentary sequence. Sediments within each unit are broadly classified as sandy silts with soil structures and may be indirectly derived from the lunettes of nearby Bool Lagoon, although their ultimate provenance is unknown. As a result of this work, palaeoenvironmental reconstruction based on fossil remains in the deposit may be more accurately related to prevailing climatic and environmental conditions at the time of accumulation. It also contributes to an understanding of the temporal occurrence of regional vertebrate faunas through the Late Pleistocene, reinforcing the value of developing stratigraphically constrained chronologies for cave deposits based on multiple techniques.