The field and microstructural signatures of deformation‐assisted melt transfer: Insights from magmatic arc lower crust,New Zealand

Melt must transfer through the lower crust, yet the field signatures and mechanisms involved in such transfer zones (excluding dykes) are still poorly understood. We report field and microstructural evidence of a deformation‐assisted melt transfer zone that developed in the lower crustal magmatic arc environment of Fiordland, New Zealand. A 30–40 m wide hornblende‐rich body comprising hornblende ± clinozoisite and/or garnet exhibits 'igneous‐like' features and is hosted within a metamorphic, two‐pyroxene–pargasite gabbroic gneiss (GG). Previous studies have interpreted the hornblende‐rich body as an igneous cumulate or a mass transfer zone. We present field and microstructural characteristics supporting the later and indicating the body has formed by deformation‐assisted, channelized, reactive porous melt flow. The host granulite facies GG contains distinctive rectilinear dykes and garnet reaction zones (GRZ) from earlier in the geological history; these form important reaction and strain markers. Field observations show that the mineral assemblages and microstructures of the GG and GRZ are progressively modified with proximity to the hornblende‐rich body. At the same time, GRZ bend systematically into the hornblende‐rich body on each side of the unit, showing apparent sinistral shearing. Within the hornblende‐rich body itself, microstructures and electron back‐scatter diffraction mapping show evidence of the former presence of melt including observations consistent with melt crystallization within pore spaces, elongate pseudomorphs of melt films along grain boundaries, minerals with low dihedral angles as small as <10° and up to <60°, and interconnected 3D melt pseudomorph networks. Reaction microstructures with highly irregular contact boundaries are observed at the field and thin‐section scale in remnant islands of original rock and replaced grains, respectively. We infer that the hornblende‐rich body was formed by modification of the host GG in situ due to reaction between an externally derived, reactive, hydrous gabbroic to intermediate melt percolating via porous melt flow through an actively deforming zone. Extensive melt–rock interaction and metasomatism occurred via coupled dissolution–precipitation, triggered by chemical disequilibrium between the host rock and the fluxing melt. As a result, the host plagioclase and pyroxene became unstable and were reacted and dissolved into the melt, while hornblende and to a lesser extent clinozoisite and garnet grew replacing the unstable phases. Our study shows that hornblendite rocks commonly observed within deep crustal sections, and attributed to cumulate fractionation processes, may instead delineate areas of deformation‐assisted, channelized reactive porous melt flow formed by melt‐mediated coupled dissolution–precipitation replacement reactions.     

Dryland Salinity on the Dundas Tableland: A historical appraisal

The groundwater recharge-discharge model, or hydro-equilibrium model, has driven Victorian dryland salinity research for the last 30 years. This paper challenges its application to the Dundas Tableland, south-western Victoria, on historical grounds. In exposing the weak historical foundation of the model for one geographical area so well represented in mainstream investigations, the critique is designed to question the validity of applying the model to other parts of Australia without corresponding historical research. More generally, it is hoped that this contribution from another discipline gives a respectful but significant nudge to the hegemony of physical science in defining and finding solutions for environmental problems.     

Interdecadal modulation of interannual atmospheric and oceanic variability over the North Pacific

The interdecadal modulation of interannual variability of the atmosphere and ocean is examined over the North Pacific by using Wavelet Transform combined with Empirical Orthogonal Function (EOF) or Singular Value Decomposition (SVD) analysis. For the period of record 1899–1997, the interannual variability of the wintertime Aleutian Low, identified by either the North Pacific Index or the leading eigenvector (EOF-1) of North Pacific sea level pressure (SLP), exhibits an interdecadal modulation. Interannual variance in the strength of the Aleutian Low was relatively large from the mid-1920s to mid-1940s and in the mid-1980s, but relatively small in the periods from 1899 to the mid-1920s and from the mid-1940s to the mid-1970s. The periods of high (low) interannual variability roughly coincide with pentadecadal regimes having a time averaged relatively intense (weak) Aleutian Low. Consistent with this SLP variability the interannual variance in the zonal wind stress is strengthened in the central North Pacific after the 1970s. The SLP EOF-2, which is related to the North Pacific Oscillation, exhibited a strengthening trend from the beginning of this century to the mid-1960s. After the 1970s, the interannual variance of SLP EOF-2 is generally smaller than that in the period from 1930 to 1970. Similar interdecadal changes in interannual variance are found in expansion coefficients for the first two EOFs of the Pacific sector 500 hPa height field for the period 1946–1993. EOF-1 of Pacific sector 500 hPa corresponds to the Pacific/North American (PNA) teleconnection pattern, while EOF-2 is related to the Western Pacific (WP) pattern. The relative influence of the atmospheric PNA and WP interannual variability on North Pacific SSTs appears to have varied at pentadecadal time scales. Results from an SVD analysis of winter season (December–February) 500 hPa and North Pacific spring season (March–May) SST fields demonstrate that the PNA-related SST anomaly exhibited larger interannual variance after the 1970s, whereas the interannual variance of the WP related SST anomaly is larger before the 1970s. Correlations between the coastal North Pacific SST records and gridded atmospheric field data also change on interdecadal time scales. Our results suggest that the SST records from both the northwest and northeast Pacific coasts were more closely coupled with the PNA teleconnection pattern during the periods of 1925–1947 and 1977–1997 than in the regime from 1948 to 1976. Teleconnections between ENSO and preferred patterns of atmospheric variability over the North Pacific also appear to vary on interdecadal time scales. However, these variations do not reflect a unique regime-dependent influence. Our results indicate that ENSO is primarily related to the PNA (WP) pattern in the first (last) half of the present century. Correlation coefficients between indices for ENSO and PNA-like atmospheric variability are remarkably weak in the period from 1948 to 1976.     

An anisotropy of magnetic susceptibility (AMS) fabric record of till kinematics within a Late Weichselian low Baltic till,southern Sweden

Herein we report on the results of an anisotropy of magnetic susceptibility (AMS) fabric case‐study of two Late Weichselian tills exposed in a bedrock quarry in Dalby, Skåne, southern Sweden. The region possesses a complex glacial history, reflecting alternating and interacting advances of the main body of the Scandinavian Ice Sheet (SIS) and its ice lobes from the Baltic basin, perhaps driven by streaming ice. AMS till fabrics are robust indicators of ice‐flow history and till kinematics, and provide a unique tool to investigate till kinematics within and amongst till units. The till section investigated here contains ~8 m of the Dalby Till – a dark grey silt‐clay rich till deposited during one or more Baltic advance – overlain by ~1.5 m of the regional surface diamicton. AMS fabrics within the lower part of the Dalby Till conform to the regional surface fluting, and reflect sustained flow from the ENE with progressive increases in basal strain. A boulder‐rich horizon approximately 3 m from the base of the till marks a restricted excursion in till fabric direction, fabric strength and style of strain. Ice flow is from the SW and W in the upper section. We interpret these fabrics to record shifting ice flow and bed conditions at the margins of the Young Baltic Advance ice lobe in southern Sweden, prior to a short‐lived re‐advance of the main body of the SIS over mainland Sweden recorded by the surface diamicton.     

Magmatic and post-magmatic evolution of post-collisional rare-metal bearing granite: The Neoproterozoic Homrit Akarem Granitic Intrusion,south Eastern Desert of Egypt,Arabian-Nubian Shield

The Homrit Akarem granitic intrusion (HAGI) outcrops near the western edge of the south Eastern Desert basement exposure in Egypt. It is a composite of two cogenetic intrusive bodies: an early albite granite phase shallowly emplaced at the apex of a magmatic cupola, and a later subjacent pink granite phase with a marginal zone of muscovite granite and better preservation of magmatic features. Mineral chemistry of primary biotite and garnet, together with whole-rock chemistry, identify the HAGI as a highly fractionated A-type peraluminous intrusion. The chemistry of F-dominant, Li-bearing, Fe³⁺-rich primary magmatic mica in the pink granite resembles that typically found in highly evolved Nb-Y-F pegmatites. The HAGI is the evolved product of a primary magma generated by partial melting of juvenile crust of the Arabian-Nubian Shield (ANS), emplaced along a regional strike-slip fault system that promoted its ascent. The main emplacement mechanism and evolutionary sequence of the HAGI was magmatic, although secondary minerals and textures resulting from hydrothermal fluid interactions are observed, especially at its margins. Primary columbite-(Mn) crystallized from melt and was partly replaced by secondary fluorcalciomicrolite. The high fluorine content of magmatic fluids exsolved from the intrusion is indicated by quartz-fluorite veins, greisenization, albitization, and F-bearing secondary oxide minerals. The magmatic derivation of this fluid is demonstrated by the F-dominant primary mica, a siderophyllite-polylithionite solid solution commonly known as zinnwaldite. The chemistry of zinnwaldite constrains the F/OH activity ratio and oxygen fugacity of its parental melt and thereby resolves the ambiguity between pressure and the effects of F in controlling the normative quartz content of rare-metal granites. The HAGI is less mineralized than the post-collisional rare-metal granites found further east in the south Eastern Desert, replicating a trend observed previously in the central Eastern Desert and suggesting that east-west zoning in rare metal enrichment is a persistent feature across latitudes at the western edge of the ANS.     

Adaptive capacity and its assessment

This paper reviews the concept of adaptive capacity and various approaches to assessing it, particularly with respect to climate variability and change. I find that adaptive capacity is a relatively under-researched topic within the sustainability science and global change communities, particularly since it is uniquely positioned to improve linkages between vulnerability and resilience research. I identify opportunities for advancing the measurement and characterization of adaptive capacity by combining insights from both vulnerability and resilience frameworks, and I suggest several assessment approaches for possible future development that draw from both frameworks and focus on analyzing the governance, institutions, and management that have helped foster adaptive capacity in light of recent climatic events.     

Geomicrobiology of selenium: Life and death by selenite

Selenite oxyanions are readily assimilated by microorganisms for the synthesis of selenoproteins. However, at elevated concentrations, selenite becomes highly toxic due to the intracellular formation of reactive oxygen species. Remarkably, some microorganisms have evolved the ability to not only survive toxic levels of selenite, but to flourish in its presence. The cultivation and genomic sequencing of dissimilatory selenite-respiring Bacteria and Archaea have begun to help elucidate the molecular mechanisms of selenite respiration.     

The development of the Space Environment Viability of Organics (SEVO) experiment aboard the Organism/Organic Exposure to Orbital Stresses (O/OREOS) satellite

The Space Environment Viability of Organics (SEVO) experiment is one of two scientific payloads aboard the triple-cube satellite Organism/ORganic Exposure to Orbital Stresses (O/OREOS). O/OREOS is the first technology demonstration mission of the NASA Astrobiology Small Payloads Program. The 1-kg, 1000-cm³ SEVO cube is investigating the chemical evolution of organic materials in interstellar space and planetary environments by exposing organic molecules under controlled conditions directly to the low-Earth orbit (LEO) particle and electromagnetic radiation environment. O/OREOS was launched on November 19, 2010 into a 650-km, 72°-inclination orbit and has a nominal operational lifetime of six months. Four classes of organic compounds, namely an amino acid, a quinone, a polycyclic aromatic hydrocarbon (PAH), and a metallo-porphyrin are being studied. Initial reaction conditions were established by hermetically sealing the thin-film organic samples in self-contained micro-environments. Chemical changes in the samples caused by direct exposure to LEO radiation and by interactions with the irradiated microenvironments are monitored in situ by ultraviolet/visible/near-infrared (UV/VIS/NIR) absorption spectroscopy using a novel compact fixed-grating CCD spectrometer with the Sun as its light source. The goals of the O/OREOS mission include: (1) demonstrating key small satellite technologies that can enable future low-cost astrobiology experiments, (2) deploying a miniature UV/VIS/NIR spectrometer suitable for in-situ astrobiology and other scientific investigations, (3) testing the capability to establish a variety of experimental reaction conditions to enable the study of astrobiological processes on small satellites, and (4) measuring the chemical evolution of organic molecules in LEO under conditions that can be extrapolated to interstellar and planetary environments. In this paper, the science and technology development of the SEVO instrument payload and its measurements are described.     

The size distributions of nanoscale Fe‐Ni‐S droplets in Stardust melted grains from comet 81P/Wild 2

Abstract– To constrain the effects of capture modification processes, the size distribution of nanoscale refractory Fe‐Ni‐S inclusions (“droplets”) was measured in five allocations extracted from throughout the depth of Stardust Track 35. The Fe/S ratio has been previously shown to increase significantly with penetration depth in this track, suggesting increasing capture‐related modification along the track. Astronomical image analysis tools were employed to measure the sizes of more than 8000 droplets from TEM images, and completeness simulations were used to correct the distribution for detection bias as a function of radius. The size distribution characteristics are found to be similar within independent regions of individual allocations, demonstrating uniformity within grains. The size distribution of the Fe‐Ni‐S droplets in each allocation is dominated by a mode near 11 nm, but is coarse‐skewed and leptokurtic with a mean of ～17 nm and a standard deviation of ～9 nm. The size distribution characteristics do not vary systematically with penetration depth, despite the strong trend in bulk Fe/S ratio. This suggests that the capture modification process is not primarily responsible for producing the morphology of these nanoscale droplets. The Stardust Track 35 droplet size distribution indicates slightly smaller sizes, but otherwise resembles those in carbonaceous chondrite Acfer 094, and chondritic porous interplanetary dust particles that escaped nebular annealing of sulfides. The size distribution of metal‐sulfide beads in Stardust’s quenched melted‐grain emulsions appears to be inherited from the size distribution of unmelted sulfide mineral grains in comet‐dust particles of chondritic character.