Metal-silicate partitioning of cesium: Implications for core formation

Here we present the first set of metal-silicate partitioning data for Cs, which we use to examine whether the primitive mantle depletion of Cs can be attributed to core segregation. Our experiments independently varied pressure from 5 to 15 GPa, temperature from 1900 to 2400 °C, metallic sulfur content from pure Fe to pure FeS, silicate melt polymerization, expressed as a ratio of non-bridging oxygens to tetrahedrally coordinated cations (nbo/t) from 1.26 to 3.1, and fO₂ from two to four log units below the iron-wüstite buffer. The most important controls on the partitioning behavior of alkalis were the metallic sulfur content, expressed as X_S, and the nbo/t of the silicate liquid. Normalization of X_S to 0.5 yielded the following expressions for D-values as a function of nbo/t: log D_Na = −2.0 + 0.44 × (nbo/t), log D_K = −2.4 + 0.67 × ( nbo/t), and log D_Cs = −3.2 + 1.17 × (nbo/t). Normalization of nbo/t to 2.7 resulted in the following equations for D-values as a function of S content: log D_Na = −4.1 + 6.4 × X_S, log D_K = −7.7 + 13.9 × X_S, and log D_Cs = −12.1 + 23.3 × X_S.There appears to be a negative pressure effect up to 15 GPa, but it should be noted that this trend was not present before normalization, and is based on only two measurements. There is a positive trend in cesium’s metal-silicate partition coefficient with increasing temperature. D_Cs exhibits the largest change and increased by a factor of three over 500 °C. The effect of oxygen fugacity has not been precisely determined but in general, lowering fO₂ by two log units resulted in a rise in all D-values of approximately an order of magnitude. In general, the sensitivity of partition coefficients to changing parameters increased with atomic number.The highest D-value for Cs observed in this study is 0.345, which was obtained at nbo/t of 2.7 and a metal phase of pure FeS. This metallic composition has far more S than has been suggested for any credible core-forming metal. We therefore conclude that the depletion of Cs in Earth’s mantle is either caused by radically different behavior of Cs at pressures higher than 15 GPa or is not related to core formation. Even so, we have shown that a planet with a sufficient S inventory may incorporate significant amounts of alkali elements into its core.     

Single-Well Injection-Drift Test to Estimate Groundwater Velocity

A simple algebraic equation is presented here to estimate the magnitude of groundwater velocity based on data from a single-well injection-drift test thereby eliminating the time-consuming and costly extraction phase. A volume of tracer-amended water was injected by forced-gradient into a single well followed by monitoring of the conservative solute tracers under natural-gradient conditions as their upgradient portions drifted back through the well. The breakthrough curve data from the single well during the drift phase was analyzed to determine the mean travel times of the tracers. The estimated mean upgradient travel distance back through the single well and the mean travel times of the tracers were used in a simple algebraic equation to estimate groundwater velocity. The groundwater velocity based on the single-well injection-drift test was estimated to be approximately 0.64 ft per day. Two transects of observation wells were used to monitor the natural-gradient tracer transport downgradient of the injection well. The one-dimensional, or dual-well, transport of the tracer from the injection well to the nearest downgradient observation well indicated that the groundwater velocity was 0.55 ft per day. The two-dimensional, or multi-well, transport of the center of mass of the tracers indicated that the groundwater velocity was 0.60 ft per day; the dual- and multi-well results were in excellent agreement with those from the single-well and validated the simple algebraic equation. The new single-well method presented here is relatively simple, rapid, and does not require an extraction phase.     

Late‐Summer Peak in Sediment Accumulation in Two Lakes with Contrasting Watersheds,Alaska

The timing of clastic sedimentation in two glacial‐fed lakes with contrasting watersheds was monitored using sequencing sediment traps for two consecutive years at Allison Lake (Chugach Range, Alaska) and four months at Shainin Lake (Brooks Range, Alaska). Shainin Lake is a weakly stratified lake fed by distant glaciers, whereas Allison Lake is more strongly stratified and fed predominantly by proximal glaciers. At Shainin Lake, sediment accumulation started in late June and reached its maximum in mid‐August, just before lake mixing and during a period of low river discharge. The grain size of the sediment reaching the sediment trap in Shainin Lake was homogenous throughout the summer. At Allison Lake, pulsed sedimentation of coarse particles during late summer and early fall storms were superimposed on the fine‐grained sedimentation pattern similar to that observed at Shainin Lake. These storms triggered underflows that were observed in the thermal structure of the lake and deposited abundant sediment. The sequencing sediment traps reveal a lag between fluvial discharge and sediment deposition at both lakes, implying limitations to interpreting intra‐annual sedimentary features in terms of inflow discharge.     

Evaluating social vulnerability indicators: criteria and their application to the Social Vulnerability Index

Natural Hazards - As a concept, social vulnerability describes combinations of social, cultural, economic, political, and institutional processes that shape socioeconomic differentials in the...     

Variations in population exposure and sensitivity to lahar hazards from Mount Rainier,Washington

Although much has been done to understand, quantify, and delineate volcanic hazards, there are fewer efforts to assess societal vulnerability to these hazards, particularly demographic differences in exposed populations or spatial variations in exposure to regional hazards. To better understand population diversity in volcanic hazard zones, we assess the number and types of people in a single type of hazard zone (lahars) for 27 communities downstream of Mount Rainier, Washington (USA). Using various socioeconomic and hazard datasets, we estimate that there are more than 78 000 residents, 59 000 employees, several dependent-population facilities (e.g., child-day-care centers, nursing homes) and numerous public venues (e.g., churches, hotels, museums) in a Mount Rainier lahar-hazard zone. We find that communities vary in the primary category of individuals in lahar-prone areas—exposed populations are dominated by residents in some communities (e.g., Auburn), employees in others (e.g., Tacoma), and tourists likely outnumber both of these groups in yet other areas (e.g., unincorporated Lewis County). Population exposure to potential lahar inundation varies considerably—some communities (e.g., Auburn) have large numbers of people but low percentages of them in hazard zones, whereas others (e.g., Orting) have fewer people but they comprise the majority of a community. A composite lahar-exposure index is developed to help emergency managers understand spatial variations in community exposure to lahars and results suggest that Puyallup has the highest combination of high numbers and percentages of people and assets in lahar-prone areas. Risk education and preparedness needs will vary based on who is threatened by future lahars, such as residents, employees, tourists at a public venue, or special-needs populations at a dependent-care facility. Emergency managers must first understand the people whom they are trying to prepare before they can expect these people to take protective measures after recognizing natural cues or receiving an official lahar warning.     

Shaking table 2‐D models of a concrete gravity dam

One of the most famous and studied cases of dams subjected to earthquake loading is the Koyna Dam in India. In this study, a two‐dimensional model of Koyna Dam at 1/50 scale was used on a shake table to simulate effects and serve as data for non‐linear computer model calibration. A new concrete mix was designed for the non‐linear similitude modelling. This new mix provided the correct kinematic failure of concrete at scale. Two models were tested to failure: one with an initial shrinkage crack and one monolith. Reservoir effects were not modelled. The results of both models are discussed and compared. The ability to model non‐linear effects is discussed. Published in 2000 by John Wiley & Sons, Ltd.     

Modeling the ice-attenuated waves in the Great Lakes

Ocean Dynamics - A partly coupled wave-ice model with the ability to resolve ice-induced attenuation on waves was developed using the Finite-Volume Community Ocean Model (FVCOM) framework and...     

Investigation of the thermal history of the Delaware Basin (West Texas,USA) using carbonate clumped isotope thermometry

We utilized carbonate clumped isotope thermometry to explore the thermal history of the Delaware Basin, West Texas, USA. Carbonate wellbore cuttings from five oil/gas wells across the basin yielded clumped isotope temperatures (T(Δ₄₇)) ranging from 27°C to 307°C, interpreted to reflect a combination of initial precipitation/recrystallization temperature and solid-state C-O bond reordering during burial. Dolomite samples generally record lower apparent T(Δ₄₇)s than calcite, reflecting greater resistance to reordering in dolomite. In all five wells, clumped isotope temperatures exceed modern downhole temperature measurements, indicating higher heat flow in the past. Using modelled burial curves based on sedimentological history, we created unique time-temperature histories by linearly applying a geothermal gradient. Applying two different thermal history reordering models, we modelled the extent of solid-state C–O bond reordering to iteratively find the time-averaged best-fit geothermal gradients for each of the five wells. Results of this modelling suggest that the shallower, southwestern portion of the study area experienced higher geothermal gradients throughout the sediment history (~45°C/km) than did the deeper, southeastern portion (~32°C/km), with the northern portion experiencing intermediate geothermal gradients (~35–38°C/km). This trend is in agreement with the observed gas/oil ratios of the Delaware Basin, increasing from east to west. Furthermore, our clumped isotope temperatures agree well with previously published vitrinite reflectance data, confirming previous observations and demonstrating the utility of carbonate clumped isotope thermometry to reconstruct basin thermal histories.