Compressibility of Ca3Al2Si3O12 perovskite up to 55 GPa

Compressibility of perovskite-structured Ca₃Al₂Si₃O₁₂ grossular (GrPv) was investigated at high pressure and high temperature by means of angle-dispersive powder X-ray diffraction using a laser-heated diamond anvil cell. We observed the Pbnm orthorhombic distortion for the pure phase above 50 GPa, whereas below this pressure, Al-bearing CaSiO₃ perovskite coexists with an excess of corundum. GrPv has a bulk modulus (K ₀ = 229 ± 5 GPa; \(K_{0}^{{\prime }}\) fixed to 4) almost similar to that reported for pure CaSiO₃ perovskite. Its unit-cell volume extrapolated to ambient conditions (V ₀ = 187.1 ± 0.4 Å³) is found to be ~2.5 % larger than for the Al-free phase. We observe an increasing unit-cell anisotropy with increasing pressure, which could have implications for the shear properties of Ca-bearing perovskite in cold slabs subducted into the Earth’s mantle.     

Earthquake imprints on a lacustrine deltaic system: The Kürk Delta along the East Anatolian Fault (Turkey)

Deltas contain sedimentary records that are not only indicative of water‐level changes, but also particularly sensitive to earthquake shaking typically resulting in soft‐sediment‐deformation structures. The Kürk lacustrine delta lies at the south‐western extremity of Lake Hazar in eastern Turkey and is adjacent to the seismogenic East Anatolian Fault, which has generated earthquakes of magnitude 7. This study re‐evaluates water‐level changes and earthquake shaking that have affected the Kürk Delta, combining geophysical data (seismic‐reflection profiles and side‐scan sonar), remote sensing images, historical data, onland outcrops and offshore coring. The history of water‐level changes provides a temporal framework for the depositional record. In addition to the common soft‐sediment deformation documented previously, onland outcrops reveal a record of deformation (fracturing, tilt and clastic dykes) linked to large earthquake‐induced liquefactions and lateral spreading. The recurrent liquefaction structures can be used to obtain a palaeoseismological record. Five event horizons were identified that could be linked to historical earthquakes occurring in the last 1000 years along the East Anatolian Fault. Sedimentary cores sampling the most recent subaqueous sedimentation revealed the occurrence of another type of earthquake indicator. Based on radionuclide dating (¹³⁷Cs and ²¹⁰Pb), two major sedimentary events were attributed to the ad 1874 to 1875 East Anatolian Fault earthquake sequence. Their sedimentological characteristics were determined by X‐ray imagery, X‐ray diffraction, loss‐on‐ignition, grain‐size distribution and geophysical measurements. The events are interpreted to be hyperpycnal deposits linked to post‐seismic sediment reworking of earthquake‐triggered landslides.     

Characterization of Mediterranean magnetotactic bacteria

Magnetotactic bacteria are a diverse group of motile prokaryotes that are ubiquitous in aquatic habitats and cosmopolitan in distribution. In this study, we collected magnetotactic bacteria from the Mediterranean Sea. A remarkable diversity of morphotypes was observed, including multicellular types that seemed to differ from those previously found in North and South America. Another interesting organism was one with magnetosomes arranged in a six-stranded bundle which occupied one third of the cell width. The magnetosome bundle was evident even under optic microscopy. These cells were connected together and swam as a linear entire unit. Magnetosomes did not always align up to form a straight linear chain. A chain composed of rectangle magnetosomes bent at a posi- tion with an oval crystal. High resolution transmission electron microscopy analysis of the crystal at the pivotal position suggested uncompleted formation of the crystal. This is the first report of Mediterranean magnetotactic bacteria, which should be useful for studies of biogeochemical cycling and geohistory of the Mediterranean Sea.     

Enigmatic diamonds in Archean calc-alkaline lamprophyres of Wawa, southern Ontario, Canada

A suite of 80 macrodiamonds recovered from volcaniclastic breccia of Wawa (southern Ontario) was characterized on the basis of morphology, nitrogen content and aggregation, cathodoluminescence (CL), and mineral inclusions. The host calc-alkaline lamprophyric breccias were emplaced at 2.68–2.74 Ga, contemporaneously with voluminous bimodal volcanism of the Michipicoten greenstone belt. The studied suite of diamonds differs from the vast majority of diamond suites found worldwide. First, the suite is hosted by calc-alkaline lamprophyric volcanics rather than by kimberlite or lamproite. Second, the host volcanic rock is amongst the oldest known diamondiferous rocks on Earth, and has experienced regional metamorphism and deformation. Finally, most diamonds show yellow-orange-red CL and contain mineral inclusions not in equilibrium with each other or their host diamond. The majority of the diamonds in the Wawa suite are colorless, weakly resorbed, octahedral single crystals and aggregates. The diamonds contain 0–740 ppm N and show two modes of N aggregation at 0–30 and 60–95% B-centers suggesting mantle storage at 1,100–1,170°C. Cathodoluminescence and FTIR spectroscopy shows that emission peaks present in orange CL stones do not likely result from irradiation or single substitutional N, in contrast to other diamonds with red CL. The diamonds contain primary inclusions of olivine (Fo₉₂ and Fo₈₉), omphacite, orthopyroxene (En₉₃), pentlandite, albite, and An-rich plagioclase. These peridotitic and eclogitic minerals are commonly found within single diamonds in a mixed paragenesis which also combines shallow and deep phases. This apparent disequilibrium can be explained by effective small-scale mixing of subducted oceanic crust and mantle rocks in fast “cold” plumes ascending from the top of the slabs in convergent margins. Alternatively, the diamonds could have formed in the pre-2.7–2.9 Ga cratonic mantle and experienced subsequent alteration of syngenetic inclusions related to host magmatism and ensuing metamorphism. Neither orogenic nor cratonic model of the diamond origin fully explains all of the observed characteristics of the diamonds and their host rocks. Electronic Supplementary Material Supplementary material is available for this article at and is accessible for authorized users.