The initiation of the southern central Great Barrier Reef: New multiproxy data from Pleistocene distal sediments from the Marion Plateau (NE Australia)

Significant synchronous shifts in the chemistry, mineralogy, grain sizes and color of the sediments at 6 m below sea floor (mbsf) at ODP Site 1195 on the Marion Plateau (NE Australia) are interpreted to reflect a major regional paleoceanographic change: the initiation of the southern province of the Great Barrier Reef (GBR). The onset of this massive carbonate production centre nearby resulted primarily in increased deposition of carbonate-rich sediments of neritic origin. Both sedimentation rate and terrigenous input record a coincident decline attributed to inshore trapping of materials behind the reefs. Our best estimate places the development of reef framework in the southern part of the GBR between 560 and 670 kyr B.P., based on an age model combining magnetostratigraphic and biostratigraphic data. The proposed estimation agrees with previous studies reporting an age between 500 and 930 kyr B.P., constraining more tightly their results. However, it does not support research placing the birth of the GBR in Marine Isotope Stage (MIS) 11 ( 400 kyr), nor the theory of a worldwide modern barrier reef development at that time.     

MAritime RISk Assessment (MARISA), a fuzzy approach to define an individual ship risk factor

This paper presents a fuzzy approach for the MAritime RISk Assessment (MARISA) applied to safety at sea. The aim of this work is to define automatically an individual ship risk factor which could be used in a decision making system. To achieve this purpose, a modular and hierarchical structure using fuzzy logic has been developed. It allows us to obtain a fuzzy risk factor (FRF) composed of a static risk factor (SRF) and a dynamic risk factor (DRF). The static risk factor assessment takes into account several static data relative to the ship (age, flag, gross tonnage, number of companies, duration of detention and type). The dynamic risk factor is evaluated by considering the meteorological conditions (sea state, wind speed and visibility) and the moment of the day. Moreover, the MARISA graphic interface developed with the Labview software is presented. This interface allows several simulations to be carried out to validate the fuzzy method proposed. Simulation results are presented.     

Lithium Isotope Composition of Marine Biogenic Carbonates and Related Reference Materials

In this study, the accuracy and the precision corresponding to Li isotopic measurements of low level samples such as marine and coastal carbonates are estimated. To this end, a total of fifty‐four analyses of a Li‐pure reference material (Li7‐N) at concentrations ranging from 1 to 6 ng ml^?1 were first performed. The average δ⁷Li values obtained for solutions with and without chemical purification were 30.3 ± 0.4‰ (2s, n = 19) and 30.2 ± 0.4‰ (2s, n = 36), respectively. These results show that the chosen Li chemical extraction and purification procedure did not induce any significant isotope bias. Two available carbonate reference materials (JCt‐1 and JCp‐1) were analysed, yielding mean δ⁷Li values of 18.0 ± 0.27‰ (2s, n = 6) and 18.8 ± 1.8‰ (2s, n = 9), respectively. Small powder aliquots (< 15 mg) of JCp‐1 displayed significant isotope heterogeneity and we therefore advise favouring JCt‐1 for interlaboratory comparisons. The second part of this study concerns the determination of δ⁷Li value for biogenic carbonate samples. We performed a total of twenty‐nine analyses of seven different tropical coral species grown under controlled and similar conditions (24.0 ± 0.1 °C). Our sample treatment prior to Li extraction involved removal of organic matter before complete dissolution in diluted HCl. Our results show (a) a constant δ⁷Li within each skeleton and between the different species (δ⁷Li = 17.3 ± 0.7‰), and (b) a Li isotope fractionation of ?2‰ compared with inorganic aragonite grown under similar conditions. Comparison with literature data suggests a significant difference between samples living in aquaria and those grown in natural conditions. Finally, we investigate ancient (fossil) carbonate material and foraminifera extracted from marine sedimentary records. Different leaching procedures were tested using various HCl molarities. Results indicate that carbonate preferential dissolution must be carried out at an acid molarity < 0.18 mol l^?1. Possible contamination from silicate minerals can be verified using the Al/Ca ratio, but the threshold value strongly depends on the carbonate δ⁷Li value. When the silicate/carbonate ratio is high in the sediment sample (typically > 2), contamination from silicates cannot be avoided, even at low HCl molarity (? 0.1 mol l^?1). Finally, bulk carbonate and foraminifera extracted from the same core sample exhibited significant discrepancies: δ⁷Li values of foraminifera were more reproducible but were significantly lower. They were also associated with lower Sr/Ca and higher Mn/Ca ratios, suggesting a higher sensitivity to diagenesis, although specific vital effects cannot be fully ruled out.     

Spatial variability of floodplain sedimentation at the event scale in the Rhine–Meuse delta,The Netherlands

This article addresses spatial variability of comtemporary floodplain sedimentation at the event scale. Measurements of overbank deposition were carried out using sediment traps on 11 floodplain sections along the rivers Waal and Meuse in The Netherlands during the high-magnitude flood of December 1993. During the flood, sand sheets were locally deposited behind a natural levee. At distances greater than 50 to 100 m from the river channel the deposits consisted mainly of silt- and clay-sized material. Observed patterns of deposition were related to floodplain topography and sediment transporting mechanisms. Though at several sites patterns were observed that suggest transport by turbulent diffusion, convection seems the dominant transporting mechanism, in particular in sections that are bordered by minor embankments. The average deposition of overbank fines ranged between 1·2 and 4·0 kg m⁻² along the river Waal, and between 1·0 and 2·0 kg m⁻² along the river Meuse. The estimated total accumulation of overbank fines (not including sand sheets) on the entire river Waal floodplain was 0·24 Mton, which is 19 per cent of the total suspended sediment load transported through the river Waal during the flood. © 1998 John Wiley & Sons, Ltd.     

The Manila clam population in Arcachon Bay (SW France): Can it be kept sustainable?

The venerid clam Ruditapes philippinarum is the most prominent suspension-feeding bivalve inhabiting muddy intertidal seagrass beds in Arcachon Bay (SW France). It is exploited by fishermen, and Arcachon Bay ranks number one in France in terms of production and total biomass of this species. Previous studies revealed a decrease in the standing stock of R. philippinarum since 2003 and unbalanced length–frequency distributions with a lack of juveniles and of adults > 40 mm. Consequently, the population dynamics of this bivalve were studied at four intertidal sites and one oceanic site in Arcachon Bay. As clam size structure did not allow classical dynamics computations, field monitoring was coupled with field experiments (tagging–recapture) over two years. Monitoring of condition index and gonadal maturation stages highlighted a high variability in spawning number and intensity between sites. Recruitment events in the exploited area varied spatially but with uniformly low values. Von Bertalanffy Growth Function (VBGF) parameters (K, L_∞) were determined using Appeldoorn and ELEFAN methods. In the exploited sites in the inner lagoon, K was relatively high (mean = 0.72 yr^? 1) but L_∞ was low (mean = 41.1 mm) resulting in a moderate growth performance index (Φ′ = 2.99). Growth parameters were not correlated with immersion time and L_∞ was different between sites. Comparison of mortality coefficients (Z) between cage experiments and field monitoring suggested that fishing accounts for 65–75% of total adult mortality. Low recruitment, a low growth rate and a normal mortality rate led to low somatic production (4.1 and 8.7 g Shell-Free Dry Weight (SFDW) m^? 2 yr^? 1) and an annual P/B ratio from 0.44 to 0.92 yr^? 1. Under current conditions, the possibility of a sustainable population in Arcachon Bay will strongly depend on recruitment success and fishing management.     

Which objective function to calibrate rainfall–runoff models for low-flow index simulations?

Much has been written on the subject of objective functions to calibrate rainfall–runoff models. Many studies focus on the best choice for low-flow simulations or different multi-objective purposes. Only a few studies, however, investigate objective functions to optimize the simulations of low-flow indices that are important for water management. Here, we test different objective functions, from single objective functions with different discharge transformations or using low-flow indices, to combinations of single objective functions, and we evaluate their robustness and sensitivity to the rainfall–runoff model. We find that the Kling and Gupta efficiency (KGE) applied to a transformation of discharge is inadequate to fulfil all assessment criteria, whereas the mean of the KGE applied to the discharge and the KGE applied to the inverse of the discharge is sufficient. The robustness depends on the climate variability rather than the objective function and the results are insensitive to the model.

EDITOR A. Castellarin; ASSOCIATE EDITOR C. Perrin     

Toothed whales in the northwestern Mediterranean: insight into their feeding ecology using chemical tracers

Risso’s dolphins, pilot whales and sperm whales rarely strand in the northwestern Mediterranean. Thus, their feeding ecology, through the analysis of stomach contents, is poorly known. The aim of this study was to gain further insight into the segregation/superposition of the diet and habitat of Risso’s dolphins, pilot whales and sperm whales using chemical tracers, namely, stable isotopes (δ¹³C, δ¹⁵N) and organochlorines. Significantly different δ¹⁵N values were obtained in Risso’s dolphins (11.7 ± 0.7‰), sperm whales (10.8 ± 0.3‰) and pilot whales (9.8 ± 0.3‰), revealing different trophic levels. These differences are presumably due to various proportions of Histioteuthidae cephalopods in each toothed whale’s diet. Similar δ¹³C contents between species indicated long-term habitat superposition or corroborated important seasonal migrations. Lower congener 180 concentrations (8.20 vs. 21.73 μg.g⁻¹ lw) and higher tDDT/tPCB ratios (0.93 vs. 0.42) were observed in sperm whales compared with Risso’s dolphins and may indicate wider migrations for the former. Therefore, competition between these species seems to depend on different trophic levels and migration patterns.     

Temporal distributions of anthropogenic Al, Zn and Pb in Hong Kong Porites coral during the last two centuries

A 182-year long record of trace metal concentrations of aluminum, zinc and lead was reconstructed from a massive Porites coral skeleton from southeastern Hong Kong to evaluate the impacts of anthropogenic activity on the marine environment. Zn/Ca and Pb/Ca ratios fluctuate synchronously from the early 19th century to the present, indicating that the marine environment has been anthropogenically influenced since industrialization. Additionally, land reclamation, mining, and ship building activities are recorded by elevated Al/Ca ratios from 1900 to 1950. The coral record indicates that high levels of Zn, Pb and Al occur coincidentally with local wars, and may have contributed to partial colony mortality. Pb/Ca does not correlate well with hemispheric proxy records after 1950, indicating that coastal corals may be recording local rather than hemispheric contamination. Pb/Ca levels in Hong Kong, Guangdong and Hainan corals imply a continuous supply of Pb-based contamination to southern China not reflected in hemispheric signals.