Rainfall interception by tree crown and leaf litter: An interactive process

Rainfall interception research in forest ecosystems usually focuses on interception by either tree crown or leaf litter, although the 2 components interact when rainfall occurs. A process‐based study was conducted to jointly measure rainfall interception by crown and litter and the interaction between the 2 interception processes for 4 tree species (Platycladus orientalis and Pinus tabulaeformis represented needle‐leaf species, and Quercus variabilis and Acer truncatum represented broadleaf species) at 3 simulated rainfall intensities (10, 50, and 100 mm hr^?1). Results indicated that (a) crown and litter interception processes incorporated 3 phases: the dampening phase, the steady saturation phase, and the postrainfall drainage phase, but the dampening phase for litter interception usually lasted 30 min longer than for crown interception; (b) the maximum and minimum interception storage (C _max and C _min ) for the crown were 0.63 and 0.36 mm on average, and litter C _max and C _min were 5.38 and 2.36 mm, respectively; (c) generally, crown and litter C _max and C _min increased when gross precipitation increased significantly (p  < .05) from 10 to 100 mm; and (4) crown C _max and C _min for needle‐species were 1.8 and 1.2 times larger than broadleaf species, whereas broadleaf litter showed the opposite, its C _max and C _min were 2.0 and 1.6 times larger than needle‐leaf litter on average; however, no significant differences were observed in crown and litter C _max and C _min between species on per leaf area and litter thickness basis. Results were normalized by total leaf area and litter thickness to provide a way to scale up from young trees to mature forests. Overall, rainfall interception was affected by biotic and abiotic factors together and could be quantified via multiple linear regression functions.     

Tetrachloroethene Release and Degradation During Combined ERH and Sodium Persulfate Oxidation

Electrical resistance heating (ERH) is a thermal treatment technology that involves passing electrical current through soil to increase subsurface temperatures. In addition to volatizing and recovering contaminant mass in the gas phase, heating the subsurface has the potential to decompose contaminants by increasing the rate of degradation reactions. Prior laboratory studies using convective heating demonstrated that the rate of tetrachloroethene (PCE) degradation was not sufficient to cause substantial in situ PCE mass destruction. However, similar experiments have not been performed using ERH, which has the potential to degrade PCE in reaction with the heating electrodes and electrochemically. Thus, the objective of this study was to determine the extent of PCE degradation during thermal treatment of PCE‐contaminated soil using a bench‐scale ERH system. The contaminated soil, a silty clay loam, was collected from a single borehole at a former dry cleaning facility prior to undergoing ERH treatment. After 30 days of ERH, 52% of the initial PCE mass was recovered, potentially indicating that 48% of the PCE was degraded during ERH. Although potential degradation products such as carbon dioxide were observed, their presence was attributed to the degradation of soil organic carbon and carbonates rather than PCE destruction. A second ERH experiment was conducted to assess the potential benefit of adding the heat‐activated oxidant, sodium‐persulfate, during treatment. After 19 days of ERH and three persulfate injections, 93% of the initial PCE was recovered, with 3% PCE destruction based on chloride evolution. However, the difference in mass recovery between the first and second experiments could have been due to differences in the initial mass of PCE, even though soil from the same core was used in both experiments. The results of this work suggest that the majority of mass recovered during ERH of the PCE‐contaminated soil at the former dry cleaning facility will be due to volatilization and gas phase extraction rather than abiotic degradation, even with the addition of sodium persulfate.     

Stakeholder objective preferences in Australian Commonwealth managed fisheries

Fisheries management is increasingly involving a wide range of stakeholders in the decision making process. However, in most fisheries, the set of management objectives are poorly defined, and the implicit importance placed on these objectives may vary considerably both between and within different stakeholder groups. This may lead to conflicts within management advisory groups where members from different stakeholder groups view potential management outcomes substantially differently, and inconsistencies in decision making when changes in stakeholder representation take place. In this paper, the institutional structure of fisheries management in Australia and the roles the different organisations play in shaping fisheries management plans are detailed. An explicit hierarchy of management objectives is developed in collaboration with key managers and policy makers. A large survey of stakeholders involved in Australian Commonwealth fisheries management was undertaken to determine stakeholder preferences relating to these objectives. The results highlight the differences in perspectives regarding the relative importance of the multiple objectives of fisheries management. While on average stakeholder preferences generally correspond with their expected preference set, the results also indicate that there is generally low coherence within stakeholder groups.     

Comparing modeled and observed changes in mineral dust transport and deposition to Antarctica between the Last Glacial Maximum and current climates

Mineral dust aerosols represent an active component of the Earth’s climate system, by interacting with radiation directly, and by modifying clouds and biogeochemistry. Mineral dust from polar ice cores over the last million years can be used as paleoclimate proxy, and provide unique information about climate variability, as changes in dust deposition at the core sites can be due to changes in sources, transport and/or deposition locally. Here we present results from a study based on climate model simulations using the Community Climate System Model. The focus of this work is to analyze simulated differences in the dust concentration, size distribution and sources in current climate conditions and during the Last Glacial Maximum at specific ice core locations in Antarctica, and compare with available paleodata. Model results suggest that South America is the most important source for dust deposited in Antarctica in current climate, but Australia is also a major contributor and there is spatial variability in the relative importance of the major dust sources. During the Last Glacial Maximum the dominant source in the model was South America, because of the increased activity of glaciogenic dust sources in Southern Patagonia-Tierra del Fuego and the Southernmost Pampas regions, as well as an increase in transport efficiency southward. Dust emitted from the Southern Hemisphere dust source areas usually follow zonal patterns, but southward flow towards Antarctica is located in specific areas characterized by southward displacement of air masses. Observations and model results consistently suggest a spatially variable shift in dust particle sizes. This is due to a combination of relatively reduced en route wet removal favouring a generalized shift towards smaller particles, and on the other hand to an enhanced relative contribution of dry coarse particle deposition in the Last Glacial Maximum.     

Geochemistry and petrology of howardite Miller Range 11100: A lithologically diverse piece of the Vestan regolith

The howardite‐eucrite‐diogenite (HED) clan of meteorites, which most likely originate from the asteroid Vesta, provide an opportunity to combine in‐depth sample analysis with the comprehensive remote‐sensing data set from NASA's recent Dawn mission. Miller Range (MIL) 11100, an Antarctic howardite, contains diverse rock and mineral fragments from common HED lithologies (diogenites, cumulate eucrites, and basaltic eucrites). It also contains a rare pyroxferroite‐bearing lithology—not recognized in HED until recently—and rare Mg‐rich (Fo_86‐91) olivine crystals that possibly represent material excavated from the Vestan mantle. Clast components underwent different histories of thermal and impact metamorphism before being incorporated into this sample, reflecting the diversity in geological histories experienced by different parts of Vesta. The bulk chemical composition and petrography of MIL 11100 suggest that it is akin to the fragmental howardite meteorites. The strong lithological heterogeneity across this sample suggests that at least some parts of the Vestan regolith show heterogeneity on the mm‐scale. We combine the outcomes of this study with data from NASA's Dawn mission and hypothesize on possible source regions for this meteorite on the surface of Vesta.     

Spatial distribution of micrometre‐scale porosity and permeability across the damage zone of a reverse‐reactivated normal fault in a tight sandstone: Insights from the Otway Basin,SE Australia

Knowledge of the permeability structure of fault‐bearing reservoir rocks is fundamental for developing robust hydrocarbon exploration and fluid monitoring strategies. Studies often describe the permeability structure of low porosity host rocks that have experienced simple tectonic histories, while investigations of the influence of faults with multiple‐slip histories on the permeability structure of porous clastic rocks are limited. We present results from an integrated petrophysical, microstructural, and mineralogical investigation of the Eumeralla Formation (a tight volcanogenic sandstone) within the hanging wall of the Castle Cove Fault which strikes 30 km NE–SW in the Otway Basin, southeast Australia. This late Jurassic to Cenozoic‐age basin has experienced multiple phases of extension and compression. Core plugs and thin sections oriented relative to the fault plane were sampled from the hanging wall at distances of up to 225 m from the Castle Cove Fault plane. As the fault plane is approached, connected porosities increase by ca. 10% (17% at 225 m to 24% at 0.5 m) and permeabilities increase by two orders of magnitude (from 0.04 mD at 225 m to 1.26 mD at 0.5 m). Backscattered Scanning Electron Microscope analysis shows that microstructural changes due to faulting have enhanced the micrometre‐scale permeability structure of the Eumeralla Formation. These microstructural changes have been attributed to the formation of microfractures and destruction of original pore‐lining chlorite morphology as a result of fault deformation. Complex deformation, that is, formation of macrofractures, variably oriented microfractures, and a hanging wall anticline, associated with normal faulting and subsequent reverse faulting, has significantly influenced the off‐fault fluid flow properties of the protolith. However, despite enhancement of the host rock permeability structure, the Eumeralla Formation at Castle Cove is still considered a tight sandstone. Our study shows that high‐resolution integrated analyses of the host rock are critical for describing the micrometre‐scale permeability structure of reservoir rocks with high porosities, low permeabilities, and abundant clays that have experienced complex deformation.     

Multidecadal biological monitoring and abatement program\ assessing human impacts on aquatic ecosystems within the Oak Ridge Reservation in eastern Tennessee,USA

Human activities can be powerful drivers of ecosystem change within catchments. While most long-term catchment studies have been conducted at pristine sites, such studies are less common from sites more impacted by human activity. The Oak Ridge National Laboratory's Biological Monitoring and Abatement Program (BMAP) was developed in the mid-1980s to (1) assess compliance with environmental regulations, (2) identify causes of adverse ecological impacts, (3) provide data for human and ecological risk assessments, and (4) evaluate the effectiveness of remedial actions taken to mitigate the impacts of contaminants in soils, groundwater, and surface water by documenting ecological recovery on the Oak Ridge Reservation (ORR), a federally owned 33 476-acre site in eastern Tennessee, managed by the US Department of Energy. The ORR is composed of multiple watersheds containing many small to mid-size streams. BMAP uses an integrated approach for determining stream health; its databases include long-term seasonal records of contaminant concentrations in water and biota, data from aquatic toxicity testing, and surveys of macroinvertebrate and fish assemblages from impacted and reference streams. These long-term data provide valuable records of degradation and recovery in catchment ecosystems. Our objective here is to describe our study system and data series in order to increase awareness of the availability of these long-term data to the catchment science community.     

Correction: Geostatistical Rock Physics Inversion for Predicting the Spatial Distribution of Porosity and Saturation in the Critical Zone

Mathematical Geosciences -     

A universal field equation for dispersive processes in heterogeneous media

When formulated properly, most geophysical transport-type process involving passive scalars or motile particles may be described by the same space–time nonlocal field equation which consists of a classical mass balance coupled with a space–time nonlocal convective/dispersive flux. Specific examples employed here include stretched and compressed Brownian motion, diffusion in slit-nanopores, subdiffusive continuous-time random walks (CTRW), super diffusion in the turbulent atmosphere and dispersion of motile and passive particles in fractal porous media. Stretched and compressed Brownian motion, which may be thought of as Brownian motions run with nonlinear clocks, are defined as the limit processes of a special class of random walks possessing nonstationary increments. The limit process has a mean square displacement that increases as t^α+1 where α > −1 is a constant. If α = 0 the process is classical Brownian, if α < 0 we say the process is compressed Brownian while if α > 0 it is stretched. The Fokker–Planck equations for these processes are classical ade’s with dispersion coefficient proportional to t^α. The Brownian-type walks have fixed time step, but nonstationary spatial increments that are Gaussian with power law variance. With the CTRW, both the time increment and the spatial increment are random. The subdiffusive Fokker–Planck equation is fractional in time for the CTRW’s considered in this article. The second moments for a Levy spatial trajectory are infinite while the Fokker–Planck equation is an advective–dispersive equation, ade, with constant diffusion coefficient and fractional spatial derivatives. If the Lagrangian velocity is assumed Levy rather than the position, then a similar Fokker–Planck equation is obtained, but the diffusion coefficient is a power law in time. All these Fokker–Planck equations are special cases of the general non-local balance law.     

Paleoecology of mangroves along the Sibun River, Belize

This study examines a sediment core (SR-63) from a mangrove ecosystem along the Sibun River in Belize, which is subject to both changes in sea-level and in the characteristics of the river's drainage basin. Radiocarbon dates from the core show a decreased sedimentation rate from ~ 6 ka to 1 cal ka BP and a marked change in lithology from primarily mangrove peat to fluvial-derived material at ~ 2.5 cal ka BP. Changes in the sedimentation rates observed in mangrove ecosystems offshore have previously been attributed to changes in relative sea-level and the rate of sea-level rise. Pollen analyses show a decreased abundance of Rhizophora (red mangrove) pollen and an increased abundance of Avicennia (black mangrove) pollen and non-mangrove pollen coeval with the decreased sedimentation rates. Elemental ratios ([N:C]_a) and stable isotope analyses (δ¹⁵N and δ¹³C) show that changes in the composition of the organic material are also coeval with the change in lithology. The decrease in sedimentation rate at the site of core SR-63 and at offshore sites supports the idea that regional changes in hydrology occurred during the Holocene in Belize, influencing both mainland and offshore mangrove ecosystems.