The geochemistry of aliphatic and polar organic tracers in sediments from Lake Bera, Malaysia

The molecular distributions of homologous aliphatic lipid compounds (n-alkanes, n-alkanoic acids, n-alkanols, n-alkanals and n-alkan-2-ones) were investigated in sediments of Lake Bera, Malaysia as well as in plant waxes from the vicinity using gas chromatography-mass spectrometry. In addition, triterpenoids of the oleanane, ursane, lupane and friedelane series, and their diagenetic products were also identified. Using the aquatic proxy P_aq, it was found that the n-alkanes present in surface sediments S1, S5 and S6 correspond to an input from emergent macrophytes, whereas in sediments collected from open water (S2, S3 and S4) they correspond to input from submerged/floating macrophytes. The presence of n-alkan-2-ols, a commonly found homologous series in the sediments as well as in the plant wax, is novel here. In addition, the presence of 24-methylcycloart-22-enol and 24-ethylcycloart-22-enol in sediments as well as the plant wax of Pandanus helicopus, a dominant reed around the lake, also supports the input of plant biomarkers to the sediments. The occurrence of 5-membered ring triterpenoid derivatives as major diagenetic products of the triterpenoids identified (e.g. friedelan-2,3-dione) shows that the degradation of the organic matter in the sediments occurs mainly under oxic conditions. Also, the presence of ring-A degraded triterpenoids (dihydroputranjivic acid, 3-nor-2,4-seco-friedelane, 4α- and 4β-3-norfriedelanes, A-norfriedel-10-one, and A-norfriedel-8-en-10-one) and the aromatized triterpenoid hydrocarbons (mono- and triaromatic derivatives) as minor diagenetic products indicates photochemical and microorganism-mediated alteration reactions of natural products in the sediments. Additional novel polyfunctional friedelane derivatives, namely friedelane-2,3-dione, friedelane-1,3-diol-2-one and friedel-1(10)-ene-1,3-diol-2-one were identified for the first time in this study. These novel polyfunctional triterpenoids were inferred to derive from the oxidation of the triterpenoids from higher plants in this oxic tropical environment. For future reference purposes, the mass spectra of the identified polar triterpenoids are also presented here. This study provides important data on the biogeochemistry of organic matter in a tropical lake of SE Asia.     

Construction of Deep Thermal Models Based on Integrated Thermal Properties Used for Geothermal Risk Management

Mathematical Geosciences - The development of deep geothermal energy may be at risk from the economic point of view if the estimated deep thermal field is far from its real state. The strong...     

Structural Setting of Northern Tunisia Insights from Gravity Data Analysis Jendouba Case Study

Detailed gravity data in conjunction with available surface geology are analyzed to infer the organization of the underlying structures in Jendouba area. Gravity data analysis benefits from the gravity Bouguer anomaly, upward continuations, residual distribution, derivatives and Euler deconvolved maps. The main results display a positive amplitude gravity anomaly as the response of Triassic evaporitic bodies and important NE trending features at the boundaries between the Triassic outcrops and their enveloping strata. Integration of gravity, geological and structural maps let to the identification of major structural directions and trends of the study area. It confirms some structural elements gathered from outcrops. It defines also new ones.     

Geochemical constraints and uranium potential of the younger granitic rocks in El Maghrbia area,Central Eastern Desert,Egypt

Acta Geochimica - The present work deals with the mineralogy, geochemical behavior and uranium potentiality of the monzogranites of El Maghrbia area, which comprise G. El Maghrbia and G. El Eredyia...     

A hybrid approach to compute seismic travel times in three-dimensional tetrahedral meshes

We propose an optimized method to compute travel times for seismic inversion problems. It is a hybrid method combining several approaches to deal with travel time computation accuracy in unstructured meshes based on tetrahedral elementary cells. As in the linear travel time interpolation method, the proposed approach computes travel times using seismic ray paths. The method operates in two sequential steps: At a first stage, travel times are computed for all nodes of the mesh using a modified version of the shortest path method. The difference with the standard version is that additional secondary nodes (called tertiary nodes) are added temporarily around seismic sources in order to improve accuracy with a reasonable increase in computational cost. During the second step, the steepest travel time gradient method is used to trace back ray paths for each source–receiver pair. Travel times at each receiver are then recomputed using slowness values at the intersection points between the ray path and the traversed cells. A number of numerical tests with an array of different velocity models, mesh resolutions and mesh topologies have been carried out. These tests showed that an average relative error in the order of 0.1% can be achieved at a computational cost that is suitable for travel time inversion.     

A stable flat universe with variable cosmological constant in f(R,T) gravity

In this paper, a general FRW cosmological model has been constructed in f(R,T) gravity reconstruction with variable cosmological constant. A number of solutions to the field equations has been generated by utilizing a form for the Hubble parameter that leads to Berman's law of constant deceleration parameter q = m-1. The possible decelerating and accelerating solutions have been investigated. For(q 0) we get a stable flat decelerating radiation-dominated universe at q = 1. For(q 0) we get a stable accelerating solution describing a flat universe with positive energy density and negative cosmological constant. Nonconventional mechanisms that are expected to address the late-time acceleration with negative cosmological constant have been discussed.     

Physical and Chemical Beneficiation of the Egyptian Beach Monazite

The Egyptian black sands contain several economic minerals, especially ilmenite. Monazite can reach concentrations up to 0.6 wt.%. The majority of monazite grains have light to deep canary and lemon yellow colors, whereas enigmatic monazite grains have brown, red, resinous, yellow and colorless to pinkish colors. The behavior of monazite with the electrostatic field setting of the roll-type electrostatic separator was studied for the different variables of the separator. Most of the monazite grains are reversible negative and are attracted towards the positively charged static electrode. Using wet gravity concentration, both low and high intensity magnetic separation, and electrostatic separation techniques, a high grade concentrate assaying 97 wt. % monazite with a recovery of 76.8% can be obtained. The Egyptian beach monazite contains high concentrations of Ce, La and Nd in addition to minor amounts of Y, Pr, Sm, Gd, Dy and Eu. It is particularly rich in the lighter rare earth elements (cerium subgroup). By a new method of ion exchange technique after chemically dissolving the mineral with sulfuric acid, both of REEs, Th and U, could be individually separated. The efficiency of the separation has been tested with sulfuric acid concentration at 2M H₂SO₄ where the thorium and uranium could be obtained with a cation exchange synthetic resin column, while rare earth metal ions are adsorbed and then individually separated. A highly pure thorium product could be obtained by oxalate precipitation followed by uranium precipitation as diuranate using NaOH.     

Chemical Fractionation of Aluminium in the Sediments of El-Burullus Lagoon of Nile Delta,Egypt

A five step sequential extraction technique, following Tessier’s protocol has been applied to determine the chemical association of aluminium with major sedimentary phases (exchangeable, carbonate, manganese and iron oxides, organic and residual fraction) in four short sediment cores collected from El-Burullus lagoon of the Nile delta, Egypt. This study is a first approach of chemical fractionation of aluminium in one of the protective areas of the Mediterranean Sea of Egypt. The total metal content was also determined. The results of the fractionation study indicated that aluminium was mainly associated with the residual fraction (>95%). The organic and Fe–Mn oxide fractions were the next important phases. The exchangeable and carbonate fractions were less than 1%, limiting its potential toxicity as a pollutant. The geochemical analysis of aluminium forms reflected the lithogenic origin of this metal in the study area.     

Effect of Soil Improvement Techniques on Increasing the Lateral Resistance of Single Piles in Soft Clay (Numerical Investigation)

Geotechnical and Geological Engineering - Soft clay soil extends in many areas all over the world. The construction on soft clay is one of the most important problems in engineering practice. When...