Io's surface composition based on reflectance spectra of sulfur/salt mixtures and proton-irradiation experiments

The available full-disk reflectance spectra of Io in the range 0.3 to 2.5 μm have been interpreted by comparison with new laboratory spectra of a wide variety of natural and synthetic mineral phases in order to determine a surface compositional model for Io that is consistent with Io's other known chemical and physical properties. Our results indicate that the dominant mineral phases are sulfates and free sulfur derived from them, which points toward a low temperature and initially water-rich surface assemblage. Our current preferred mineral phase mixture that best matches the Io data and is simultaneously most consistent with other constraints, consists of a fine-grained particulate mixture of free sulfur (55 vol%), dehydrated bloedite [Na₂Mg(SO₄)₂·xH₂O] (30 vol%) ferric sulfate [Fe₂(SO₄)₃·xH₂O] (15 vol%), and trace amounts of hematite [Fe₂O₃]. Other salts may be present, such as halite and sodium nitrate, as well as clay minerals. Such a model is consistent with a probable pre- and post-accretion thermal history of Io-forming material and Io's observed Na emission and other properties. These results further support the evaporite surface hypothesis of Fanale et al'; while not precluding the presence of certain silicate phases such as montmorillonite.The average surface of Io's leading hemisphere appears to contain less free sulfur and more salts and to be finer grained than that of the trailing hemisphere. Since Io is immersed in Jupiter's magnetosphere, irradiation damage effects from low-energy proton bombardment were studied. Irradiation damage of lattices is estimated to be a relatively minor but operative process on the surface of Io; irradiation darkening by sulfate reduction to free sulfur and by F-center production in salts may be partly responsible for the differences in albedo of leading and trailing hemispheres and equatorial and polar regions of Io, but slight regional differences in relative intrinsic phase concentration on the surface may likewise account for these global variations in albedo.Possible unusual surface properties predicted by this model include: posteclipse darkening in certain wavelenghts, limb brightening in certain wavelengths, and unusual surface electrical properties. Further refinement of Io's surface composition model and better understanding of surface irradiation effects will be possible when observational data in the range 0.20 to 0.30 μm are obtained and when improved spectra in the range 0.30 to 5.0 μm are obtained having increased spectral, spatial, and temporal resolution.     

'A good site for health': Missionaries and the pathological geography of central southern Africa

Throughout much of the late eighteenth and early nineteenth centuries, the tropics and subtropics were constructed as a relatively homogenous realm. The supposed 'pathological potency' of these regions was assumed to render them particularly hazardous for European constitutions relative to 'temperate' locations. The interior of Africa represented one such apparently pestilential place. This paper examines how the experiences of nineteenth-century missionaries based at various stations in central southern Africa might have been influenced by popular and scientific debates focusing on environment, climate and health in Africa. We also illustrate how their perspectives may have challenged popular homogenized conceptualizations of interior Africa as a uniformly dangerous place for Europeans and helped to identify a spatially varied pathological geography of the region.     

Forms of bluffs degraded for different lengths of time in emmet county,Michigan, U.S.A.

Distinct differences in morphology are found among bluffs cut and abandoned by Glacial Lake Algonquin and by the Nipissing Great Lakes in Emmet County, Michigan and modern, active bluffs presently being eroded by Lake Michigan in Mason and Manistee Counties, Michigan. The Algonquin, Nipissing, and modern bluffs are all composed of a sandy, morainic material. Because the composition and mode of formation of the three sets of bluffs are similar, it is assumed that the abandoned bluffs had the same initial configuration as the modern bluff. The morphologic differences are likely a function of the different periods of time each bluff has degraded. With time, the angle of the bluff midsection decreased, the extent of the convex crest and the concave base increased, and the angle of the crest increased. This course of hillslope degradation is believed similar to that occurring elsewhere on heavily vegetated hillslopes underlain by cohesionless material and situated in temperate, humid climates. The morphologic changes may be understood in terms of an analytical model which assumes that the rate of change in elevation at a point on a hillslope profile is proportional to the profile curvature at that point.     

Late Quaternary fluvial activity in the dry valleys (mekgacha) of the Middle and Southern Kalahari,southern Africa

Kalahari dry ‘fossil’ valleys (mekgacha) have been little used in palaeoenvironmental reconstruction, partly because the origins and functions of the valleys are a subject of debate, and partly because they contain few datable sediments. In the Middle Kalahari the valleys are endoreic, and, following a decline in ground-water tables owing to human interference over the past 150 years, rarely contain water. Evidence from three sites suggests that the valleys contained standing water between 15000 and 12000 yr BP, and that the main Okwa-Mmone system flowed into palaeolake Makgadikgadi at 920 m a.s.l. during this period. The Southern Kalahari contains the exoreic Molopo network which is hydrologically more active, being prone to surface flows in response to extreme rainfall events. The spring—fed Kuruman valley has two terraces, the lower composed of a series of flood deposits of late Holocene age. The flood of February 1988 provides a useful analogue for the conditions under which these deposits were formed, and of the temporal regime of the Kuruman River. Comparison with adjacent sites suggests that evidence put forward to indicate cycles of climatic amelioration in the last 4000 yr may, in part, represents the effect of extreme precipitation events. Historical floods show a strong correlation to Southern Oscillation high-phase (cold event) episodes, suggesting possibilities for extension of the Southern Oscillation record through palaeoflood studies.     

Seasonal fluctuations and compositions of two populations of small demersal fishes on the west coast of Scotland

The soft sediment fish communities below 20 m depth were studied at two sites on the west coast of Scotland (Irvine Bay, Firth of Clyde and the Lynn of Lorne) using small meshed beam trawls. In both cases the emphasis was on the small demersal fish (<15 cm) within these communities. The Irvine Bay community was studied between May 1978 and December 1979 and the Lynn of Lorne community between February 1975 and October 1976.Twenty-seven fish species were recorded in Irvine Bay and 32 in the Lynn of Lorne. In both communities four species constituted more than 78% of the total annual abundance, two gobies (Lesueurigobius friesii and Pomatoschistus norvegicus) were high in the dominance ranking for both sites. The species abundance lists were similar for both sites (0·62 level of similarity) but the species lists for each site were different (0·36 level of similarity). The overall mean density of small demersal fish was similar for both sites (Irvine Bay = 0·045 individuals m^?2 and the Lynn of Lorne = 0·047 individuals m^?2). There were two periods of high abundance for both communities (late autumn to winter and late spring). There was, however, a low repeatability between successive years. The species richness (D) was relatively high (Irvine Bay = 1·5-3·08, Lynn of Lorne = 1·4-3·34) as was the species diversity (H′) (Irvine Bay = 1·17-1·97, Lynn of Lorne = 1·23-1·95). The proportional representation ($\text{J′}$) of each species within the community was greater in Irvine Bay ($\text{J′}$ = 0·57-0·77) than in the Lynn of Lorne ($\text{J′}$ = 0·50-0·72). Therefore these two communities of small demersal fish appeared to be similar at the community level but the way in which this was achieved was different.