Anomalous absorption in thioformaldehyde

Absorption against the Cosmic Microwave Background (CMB), called the anomalous absorption, is an unusual phenomenon. The transition 1₁₁–1₁₀ at 4.829 GHz of formaldehyde (H₂CO) was the first one showing the anomalous absorption. The c-C₃H₂ is the second molecule showing anomalous absorption through its transition 2₂₀–2₁₁ at 21.590 GHz. Structure of thioformaldehyde (H₂CS) is very similar to that of the H₂CO. Therefore, we have investigated about the physical conditions under which the transition 1₁₁– 1₁₀ at 1.0465 GHz of H₂CS would be found in anomalous absorption in cool cosmic objects. As in case of H₂CO, the anomalous absorption of 1₁₁–1₁₀ of H₂CS is found sensitive to the relative collisional rates and it requires that the collisional rate for the transition 1₁₁–2₁₁ must be smaller than that for the transition 1₁₀–2₁₂.     

Equatorial electrojet in east Brazil longitudes

This paper describes the morphology of the equatorial electrojet (EEJ) along 45°W longitude in east Brazil, where the ground magnetic (dip) equator is associated with the largest declination in the world. Daily range of the horizontal field (ΔH), as expected, was largest at the station in the chain closest to the dip equator, Sao Luiz (inclination −0.25°S). ΔZ was largest positive at Eusebio (inclination 9.34°S) and largest negative at Belem (inclination 7.06°N); both near the fringe of EEJ belt. ΔZ at Sao Luiz during the daytime was unexpectedly large negative in-spite of a small dip and also located south of the dip equator where ΔZ should be positive. Center of EEJ was found to be shifted southward of the dip equator by about 1° in latitude. During southern summer, ΔY started decreasing from 00 h and reached a minimum value in the afternoon, an abnormal feature not discussed for any station so far. The mid-day value of the direction of ΔH vector was 22°–24°W compared to the declination of 19°–21°W in the region.     

Distribution of dissolved carbohydrates and uronic acids in a tropical estuary,India

Carbohydrates including uronic acids are among the active components of dissolved organic carbon, and play an important role in biogeochemical cycling of organic carbon in marine environments. In order to understand their distribution, concentrations of total dissolved carbohydrate (TCHO), dissolved polysaccharide (PCHO), dissolved monosaccharide (MCHO), and dissolved uronic acid (URA) were measured in the Mandovi estuary, west coast of India during the monsoon and premonsoon seasons. The estuary experienced nearly fresh water condition during the monsoon season and marine condition during the pre-monsoon season. Concentrations of TCHO, MCHO and URA ranged from 17.7 to 67.3 μM C, 4.1 to 15.5 μM C and 2.3 to 10.8 μM C, and their contribution to dissolved organic carbon (DOC) varied from ∼11 to 60%, 2.5 to 9.7%, and 1.8 to 5.3%, respectively. PCHO accounted for ∼52 to 92% of the TCHO. Generally, concentrations and yields of TCHO species were greater during the monsoon season. Phytoplankton abundance and bacterial cell numbers influenced the distribution of TCHO in the pre-monsoon season but not during the monsoon season. Transport of TCHO rich (11 to 60%) dissolved organic matter from the Mandovi estuary to the coastal waters during the monsoon season may affect ecosystem function by fueling biological activity of heterotrophic micro-organisms.     

The COVID-19 pandemic and global environmental change: Emerging research needs

The outbreak of COVID-19 raised numerous questions on the interactions between the occurrence of new infections, the environment, climate and health. The European Union requested the H2020 HERA project which aims at setting priorities in research on environment, climate and health, to identify relevant research needs regarding Covid-19. The emergence and spread of SARS-CoV-2 appears to be related to urbanization, habitat destruction, live animal trade, intensive livestock farming and global travel. The contribution of climate and air pollution requires additional studies. Importantly, the severity of COVID-19 depends on the interactions between the viral infection, ageing and chronic diseases such as metabolic, respiratory and cardiovascular diseases and obesity which are themselves influenced by environmental stressors. The mechanisms of these interactions deserve additional scrutiny. Both the pandemic and the social response to the disease have elicited an array of behavioural and societal changes that may remain long after the pandemic and that may have long term health effects including on mental health. Recovery plans are currently being discussed or implemented and the environmental and health impacts of those plans are not clearly foreseen. Clearly, COVID-19 will have a long-lasting impact on the environmental health field and will open new research perspectives and policy needs.     

Preparation and characterization of antibacterial silver/vermiculites and silver/montmorillonites

The reason for the preparation and characterization of the novel antibacterial silver/vermiculites (Ag/V) together with the silver/montmorillonites (Ag/M) was that the information on the vermiculite structure change and stability of Ag/V in water as well as its effect on bacteria are sporadic. The vermiculite (V), (Si_3.02Al_0.98)^IV (Mg_2.27Al_0.12Ti_0.07)^VI O₁₀(OH)₂ Ca_0.09Na_0.21K_0.50 from West China and montmorillonite (M), (Si_3.96Al_0.04)^IV (Al_1.20Mg_0.42Ti_0.02)^VI O₁₀ (OH)₂Ca_0.15Na_0.14K_0.08 from Ivan?ice (Czech Republic), fraction <0.4 μm were the starting clay materials for sample preparation. The samples V1 and M1 were prepared via reaction of the V and M with the 0.01 mol L⁻¹ AgNO₃ aqueous solution. The samples V2 and M2 were treated with the aqueous solution of AgNO₃ for two times. The cation exchange and reduced metallic silver on M1 and V1 evoked the specific surface area (SSA) diminution, the mean particle-size diameter extension and appearance of micropores with radius (<0.4 nm). Repeated silver cation exchange in M2 and V2 reduced particle size, increased slightly SSA and micropores with radius of 0.4-0.5 nm. Samples Ag/V and Ag/M showed higher content of pores with radius 0.5-1.0 nm than original V and M. The Ag concentration was found higher in Ag/V than in Ag/M and higher in repeatedly treated samples: 0.9 wt.% Ag in V1, 1.4 wt.% Ag in V2, 0.6 wt.% Ag in M1 and 1.0 wt.% Ag in M2. Vermiculite structure consisting of the hydrated interstratified phases and the mica-like phase changed to the cation-one-zero layer hydrate interstratification structure in V1 and to the random of two-one layer hydrate interstratifications in V2. Infrared and Mössbauer spectroscopy revealed no changes in the structure of the clay minerals that could be related directly to the sorption and crystallization of silver. Transmission electron microscopy showed that the silver nanoparticles size distribution was much narrower for the samples Ag/M than for Ag/V. The mean size of the Ag particles was between 40 and 50 nm. Although the Ag nanoparticles did not adhere sufficiently at the clay minerals surface and migrated moderately into water, all samples under study were approved to be effective inhibitors of the bacterial growth persisting for the whole testing period of 6 days. Silver/vermiculite was antimicrobial more efficient against Klebsiella pneumoniae and Pseudomonas aeruginosa than silver/montmorillonite.     

Nonplanar ion-acoustic Gardner solitons in a pair-ion plasma with nonextensive electrons and positrons

The properties of nonplanar (cylindrical and spherical) ion-acoustic solitary waves (IA SWs) in an unmagnetized, collisionless electron-positron-ion (e-p-i) plasma, whose constituents are q-distributed electrons and positrons and inertial ions, are investigated by deriving the modified Gardner (MG) equation. The well known reductive perturbation method is employed to derive the MG equation. The basic features of nonplanar IA Gardner solitons (GSs) are discussed. It is found that the properties of nonplanar IA GSs (rarefactive and compressive) are significantly affected by the particle nonextensivity.     

Fe‐Mn systematics of type IIA chondrules in unequilibrated CO,CR, and ordinary chondrites

Abstract– We have examined Fe/Mn systematics of 34 type IIA chondrules in eight highly unequilibrated CO, CR, and ordinary chondrites using new data from this study and prior studies from our laboratory. Olivine grains from type IIA chondrules in CO chondrites and unequilibrated ordinary chondrites (UOC) have significantly different Fe/Mn ratios, with mean molar Fe/Mn = 99 and 44, respectively. Olivine analyses from both these chondrite groups show well‐defined trends in Mn versus Fe (afu) and molar Fe/Mn versus Fe/Mg diagrams. In general, type IIA chondrules in CR chondrites have properties intermediate between those in UOC and CO chondrites. In most UOC and CR type IIA chondrules, the Fe/Mn ratio of olivine decreases during crystallization, whereas in CO chondrites the Fe/Mn ratio does not appear to change. It is difficult to interpret the observed Fe/Mn trends in terms of differing moderately volatile element depletions inherited from precursor materials. Instead, we suggest that significant differences in the abundances of silicates and sulfides ± metals in the precursor material, as well as open‐system behavior during chondrule formation, were responsible for establishing the different Fe/Mn trends. Using Fe‐Mn‐Mg systematics, we are able to identify relict grains in type IIA chondrules, which could be derived from previous generations of chondrules, including chondrules from other chondrite groups, and possibly chondritic reservoirs that have not been sampled previously.     

Relationship between interplanetary field/plasma parameters with geomagnetic indices and their behavior during intense geomagnetic storms

This paper presents a correlative study between the peak values of geomagnetic activity indices (Dst, Kp, ap and AE) and the peak values of various interplanetary field (Bt, Bz, E and σ_B) and plasma (T, D, V, P and β) parameters along with their various products (BV, BzV and B²V) during intense geomagnetic storms (GMSs) for rising, maximum and decay phases as well as for complete solar cycle 23. The study leads to the conclusion that the peak values of different geomagnetic activity indices are in good correlation with Bt, Bz, σ_B, V, E, BV, BzV and B²V, therefore these parameters are most useful for predicting GMSs and substorms. These parameters are also reliable indicators of the strength of GMSs. We have also presented the lag/lead time analysis between the maximum of Dst and peak values of geomagnetic activity indices, various interplanetary field/plasma parameters for all GMSs. We have found that the average of peak values of geomagnetic activity indices and various field/plasma parameters are larger in decay phase compare to rising and maximum phases of cycle 23. Our analyses show that average values of lag/lead time lie in the ≈?4.00 h interval for Kp, ap and AE indices as well as for Bt, Bz, σ_B, E, D and P. For a more meaningful analysis we have also presented the above study for two different groups G1 (CME-driven GMSs) and G2 (CIR-driven GMSs) separately. Correlation coefficients between various interplanetary field/plasma parameters, their various products and geomagnetic activity indices for G1 and G2 groups show different nature. Three GMSs and associated solar sources observed during three different phases of this solar cycle have also been studied and it is found that GMSs are associated with large flares, halo CMEs and their active regions are close to the solar equator.     

Chemical composition of rain water and influence of airmass trajectories at a rural site in an ecological sensitive area of Western Ghats (India)

Samples of rain water were collected during monsoon season (June to September) of 2006 and 2007 at Hudegadde, a rural site located in an ecological sensitive area of Western Ghats. The collected samples were analyzed for pH, conductivity and major ions. At this site, rainwater pH varied from 4.20 to 7.39 with 5.65 as volume weighed mean. The observed mean was slightly lower than the average pH reported at most of the Indian continental sites. Monthly variation showed that average pH of rain water was the lowest during September (end of monsoon) and the highest during July (peak of monsoon). Overall, marine sources had dominating influence at this site. However, significant influence of anthropogenic and crustal sources from local as well as inter-continental regions was also noticed. As compared to NO₃⁻, higher concentration of SO₄²⁻ was noticed which might be due to contribution from industrial activities responsible for SO₂ emission. At this site, influence of five types of airmass trajectories was noticed i.e. i) C.I.O. (Central part of Indian Ocean)-when air masses blown from Maldives and nearby region of central Indian ocean. These airmasses had higher concentrations of nss Ca²⁺ which did not show any adverse impact on the pH; ii) N.W.I.O.(North-West Indian Ocean)-when airmasses travelled from oceanic region close to north-east Africa. These airmassses had higher concentrations of nss sulphate and nitrate and gave rise to acid rain; iii) S.W.I.O. (South -West Indian Ocean)- when airmasses came from southern part of Indian ocean (close to Mauritius). During these airmasses, rain water samples had almost equal ratio of nss SO₄²⁻ and nss Ca²⁺ similar to N.W.I.O but very low NO₃⁻ ; iv) Gulf-when airmasses were observed coming from Gulf region. Although these airmasses contributed only 2% of the total number of samples but carried high amount of nss SO₄²⁻ which gave rise to acid rain. The second lowest pH was observed during these airmasses which might be due to very high nssSO₄²⁻/nssCa²⁺ ratios; v) N.W.I.O. + S.W.I.C. (North-West Indian Ocean+South-West Indian Continental)- when airmasses originated from north-west Indian Ocean travelling towards south continental part of India and then arriving to the site. During these airmasses, samples showed typical influence of urban activities having high concentrations of nss SO₄²⁻ and NO₃⁻ leading to the lowest pH of rain water.     

KLENOT Project 2002–2008 contribution to NEO astrometric follow‐up

Abstract— Near‐Earth object (NEO) research plays an increasingly important role not only in solar system science but also in protecting our planetary environment as well as human society from the asteroid and comet hazard. Consequently, interest in detecting, tracking, cataloguing, and the physical characterizing of these bodies has steadily grown. The discovery rate of current NEO surveys reflects progressive improvement in a number of technical areas. An integral part of NEO discovery is astrometric follow‐up crucial for precise orbit computation and for the reasonable judging of future close encounters with the Earth, including possible impact solutions. The KLENOT Project of the Klet Observatory (South Bohemia, Czech Republic) is aimed especially at the confirmation, early follow‐up, long‐arc follow‐up, and recovery of near‐Earth objects. It ranks among the world's most prolific professional NEO follow‐up programs. The 1.06 m KLENOT telescope, put into regular operation in 2002, is the largest telescope in Europe used exclusively for observations of minor planets and comets, and full observing time is dedicated to the KLENOT team. In this paper, we present the equipment, technology, software, observing strategy, and results of the KLENOT Project obtained during its first phase from March 2002 to September 2008. The results consist of thousands of precise astrometric measurements of NEOs and also three newly discovered near‐Earth asteroids. Finally, we also discuss future plans reflecting also the role of astrometric follow‐up in connection with the modus operandi of the next generation surveys.