Contribution of stable isotopes to the understanding of the unsaturated zone of a carbonate aquifer (Nerja Cave, southern Spain)

We analysed the stable isotopes (¹⁸O and ²H) of rainwater and drip water within a cave (Nerja Cave) located in the unsaturated zone of a carbonate aquifer. Rainfall is more abundant and presents lower isotopic content in winter, while the volume of drip water is greater and its isotopic content is lower in summer. The flow analysis of ¹⁸O through the unsaturated zone confirms the seasonal lag between rainfall and the appearance of drip water in the cave and reveals that the unsaturated zone of the aquifer, in the sector of the cave, behaves like an inertial system with a strong capability to modulate the input signal. To cite this article: F. Carrasco et al., C. R. Geoscience 338 (2006).     

Condensation water in heritage touristic caves: Isotopic and hydrochemical data and a new approach for its quantification through image analysis

Condensation water is a major factor in the conservation of heritage caves. It can cause dissolution of the rock substrate (and the pigments of rock art drawn on it) or covering thereof with mineral components, depending on the chemical saturation degree of the condensation water. In show caves, visitors act as a source of CO₂ and thus modify the microclimate, favouring negative processes that affect the conservation of the caves. In spite of their interest, studies of the chemical composition of this type of water are scarce and not very detailed. In this work we present research on the condensation water in the Nerja Cave, one of the main heritage and tourist caves in Europe. The joint analysis of isotopic, hydrochemical, mineralogical and microbiological data and the use of image analysis have allowed us to advance in the knowledge of this risk factor for the conservation of heritage caves, and to demonstrate the usefulness of image analysis to quantify the scope of the possible corrosion condensation process that the condensation water could be producing on the bedrock, speleothem and rock art. To our knowledge, this application of image analysis (relative to the condensation water in caves) is the first one of this type that has been documented.     

Supraglacial Debris Supply in the Cuerpo de Hombre paleoglacier (Spanish Central System): Reconstruction and Interpretation of a Rock Avalanche Event

During the deglaciation stages of the last glacial period a rock avalanche took place on the glacier that occupied the upper sector of the Cuerpo de Hombre Valley (Sierra de Béjar). The material displaced during the avalanche fell onto the ice, was transported by the glacier and later deposited as supraglacial ablation till. The cause of the avalanche was the decompression of the valley slopes after they were freed from the glacier ice (stress relaxation). Reconstruction of the ice masses has been carried out to quantify the stress relaxation that produced the collapse. The rock avalanche took place on a lithologically homogeneous slope with a dense fracture network. The avalanche left a 0.4 ha scar on the slope with a volume of displaced material of 623 ± 15 × 10³ m³. The deposit is an accumulation of large, angular, heterometric boulders (1–100 m³ in volume) with a coarse pebble‐size matrix. The avalanche can be explained as a relaxation process. This implies rock decompression once the glacier retreat left the wall ice free (debuttressing). Calculations show that the avalanche took place where the decompression stresses were highest (130–170 kPa). In the Spanish Central System paleoglaciers the largest accumulation of morainic deposits occurred after the glacial maximum and the earliest stages of the ice retreat. The process described here is used as an example to formulate a hypothesis that the largest accumulations of tills were formed in relation to enhanced slope dynamics once some glacier retreat had occurred.     

Weathering phases recorded by gnammas developed since last glaciation at Serra da Estrela, Portugal

The morphometrical analysis of gnammas (weathering pits) in granite landscapes has been used to establish the relative chronology of recent erosive surfaces and to provide the weathering history in a region. To test the validity of gnammas as relative chronometer indicators, and the reliability of the obtained weathering record, two sites have been studied in Serra da Estrela, Portugal. The first site is within the limits of the glacier that existed in these mountains during the last glaciation, whereas the second site is located in an unglaciated sector of the mountains, which preserves a longer record of weathering in the bedrock surface. The number of gnamma weathering phases recorded in the latter site (8) is larger than those from the former (6). Correlation between both measurement stations based on morphometrical criteria is excellent for the younger six weathering phases (1 to 6). Consequently, the parameter used for relative chronology (δ-value) has been verified to be age dependent, although absolute values are modulated by microclimate due to altitude variations. The weathering record was essentially duplicated once the surfaces at both sites were exposed, demonstrating the reliability of gnamma evolution as a post-glacial environmental indicator for the region.     

Epistemic bimodality and kinetic hypersensitivity in photochemical models of Titan's atmosphere

We show that photochemical models of Titan's atmosphere can give rise to bimodal distributions in the abundances of some major compounds, like C₂H₂ and C₂H₄. Sensitivity analysis enabled us to identify the causes and conditions of this bimodality. We propose several methods to control this behavior in photochemical models. In particular, we point out the importance of two key reactions and the needs for a critical evaluation of the kinetic data. We also show that the abundances of some compounds are hypersensitive to the ratio [CH₄]/[H], suggesting that a time-dependent variation of this ratio might lead to a real bistability in the high atmosphere of Titan.     

Structure of Saturn's Mesosphere from the 28 Sgr Occultations

We analyze an extensive data set of immersion and emersion lightcurves of the occultation of 28 Sgr by Saturn's atmosphere on 3 July 1989. The data give profiles of number density as a function of altitude at a variety of latitudes, at pressures ranging from about 0.5 to about 20 μbar. The atmosphere is essentially isothermal in this range, with a temperature close to 140 K for an assumed mean molecular weight of 2.135. Owing to favorable ring geometry, an accurate radial scale is available for all observations, and we confirm the substantial equatorial bulge produced by zonal winds of ∼450 m/s first observed in the Voyager radio-occultation experiments. The fact that the bulge is still present at microbar pressures suggests that the equatorial winds persist to high altitudes. According to our radial scale, the 2.4-μbar level, which corresponds to half-flux in the stellar occultations, is at an equatorial radius of 60,960 km. This radial scale is in good agreement with the Voyager radio-occultation data at mbar pressures and allows smooth interpolation of the isothermal structure between the stellar-occultation and radio-occultation regions. We do not have such a smooth interpolation between our data and Voyager ultraviolet occultation data, unless we discard the lowest 200 km of Voyager ultraviolet data. When this is done, we obtain a complete atmospheric model from an equatorial radius of 61,500 km down to an equatorial radius of 60,500 km. This model gives excellent agreement between all 28 Sgr, Voyager, and Pioneer 11 data.