Synthesis of highly dense and fine-grained aggregates of mantle composites by vacuum sintering of nano-sized mineral powders

Synthesized mineral powders with particle size of <100 nm are vacuum sintered to obtain highly dense and fine-grained polycrystalline mantle composites: single phase aggregates of forsterite (iron-free), olivine (iron containing), enstatite and diopside; two-phase composites of forsterite + spinel and forsterite + periclase; and, three-phase composites of forsterite + enstatite + diopside. Nano-sized powders of colloidal SiO₂ and highly dispersed Mg(OH)₂ with particle size of ≤50 nm are used as chemical sources for MgO and SiO₂, which are common components for all of the aggregates. These powders are mixed with powders of CaCO₃, MgAl₂O_4, and Fe(CO₂CH₃)₂ to introduce mineral phases of diopside, spinel, and olivine to the aggregates, respectively. To synthesize highly dense composites through pressureless sintering, we find that calcined powders should be composed of particles that have: (1) fully or partially reacted to the desired minerals, (2) a size of <100 nm and (3) less propensity to coalesce. Such calcined powders are cold isostatically pressed and then vacuum sintered. The temperature and duration of the sintering process are tuned to achieve a balance between high density and fine grain size. Highly dense (i.e., porosity ≤1 vol%) polycrystalline mantle mineral composites with grain size of 0.3–1.1 μm are successfully synthesized with this method.     

Ecologic and taxonomic diversification in the Mesozoic brackish-water bivalve faunas in Japan, with emphasis on infaunalization of heterodonts

Mesozoic brackish-water bivalve faunas in Japan diversified in three steps: at the beginning of the Early Jurassic, Early and Late Cretaceous. The Hettangian Niranohama Fauna in northeastern Honshu represents the establishment of a heterodont-dominated brackish-water fauna that persisted until the early Late Cretaceous. No similar composition is known from the Triassic. The infauna consists mostly of non-siphonate and some short-siphonate heterodonts, while the epifauna is represented by diverse pteriomorphian families. In the Early Cretaceous Tetori Group in central Honshu, the long-siphonate heterodonts Tetoria (Corbiculidae) and the semi-infaunal soft-bottom oyster Crassostrea appeared. The evolutionary diversification of the latter, known as the most important element of modern brackish-water faunas, may thus originate at that time. In the early Late Cretaceous (Cenomanian) of the Goshoura and Mifune Groups in west Kyushu, several euryhaline deep-burrowing heterodont families, such as Veneridae and Tellinidae, further diversified in the brackish and marine environments. The Late Cretaceous is characterized by massive shell biolithic beds in which large Crassostrea species are common, a feature common for Cenozoic brackish-water faunas. The long-term changes in the composition of the brackish-water faunas in Japan represents thus an evolutionary record, irrespective of the severe physiological and environmental conditions imposed on the highly conservative nature of the fauna.     

Comment on ‘Poisson Equations of Rotational Motion for a Rigid Triaxial Body with Application to a Tumbling Artificial Satellite’ by Liu and Fitzpatrick

Liu and Fitzpatrick (1975) discussed the secular and long-periodic behavior of a dynamical system by using improper time-averaged equations. The correct time-averaged equations are given in this note.     

Chemical characteristics of the lherzolitic shergottite Yamato 000097: magmatism on Mars inferred from the chemical compositions of shergottites

As a part of a consortium study, we analyzed the Martian meteorite Yamato (Y) 000097 by prompt gamma-ray analysis, instrumental neutron activation analysis, and instrumental photon activation analysis. For comparison, we also analyzed Allan Hills (ALH) 77005 using the same methods. The data confirm that Y000097 belongs to lherzolitic shergottites in terms of chemical composition. Although there exist slight differences in elemental abundances among lherzolitic shergottites due to differences in the modal abundances of constituent minerals, they have essentially the same chemical compositions, suggesting they are genetically related and experienced similar formation histories.Zr/Hf ratios obtained for Y000097 and ALH 77005 are subchondritic, consistent with values reported for other lherzolitic shergottites and olivine-phyric shergottites. Such fractionation can be explained by invoking clinopyroxene, ilmenite, or majorite in the petrogenesis of the shergottites' source material. CI-normalized Hf/Sm ratios obtained for Y000097 and ALH 77005 are 1.52 and 1.37, respectively, consistent with superchondritic Hf/Sm ratios reported for shergottites. Based on experimentally derived partition coefficients, majorite is the best candidate mineral for the fractionation of Hf and Sm in shergottites.     

Possibility of recent changes in vertical distribution and size composition of chlorophyll-a in the western North Pacific region

Our analysis of the last three decades of retrospective data of vertical distributions and size composition of chlorophyll-a (Chl-a) over the western North Pacific has revealed significant changes of three indices related to Chl-a during summer season, as follows: (1) decreasing linear trend of the proportion of Chl-a in surface layer to that of the whole water column by 0.4 and 2.3% year⁻¹ in the subtropical area along 137°E (STA₁₃₇) during 1972 to 1997 and in the Kuroshio Extension area along 175°E (KEA₁₇₅) during 1990 to 2001; (2) increasing linear trend of the depth of subsurface Chl-a maximum (DCM) by 0.4 and 2.6 m year⁻¹ in STA₁₃₇ and KEA₁₇₅; and (3) decreasing linear trend of larger-size Chl-a (>3 μm) by 0.1 and 2.5% year⁻¹ in STA₁₃₇ and KEA₁₇₅, respectively. Water density (σ _θ ) at 75 m depth had also decreased by 0.006 and 0.05 year⁻¹ in STA₁₃₇ and KEA₁₇₅, respectively. The ratio of biogenic opal to biogenic CaCO₃ in the sinking flux decreased by 0.015 year⁻¹ in the subtropical region from 1997 to 2005. These findings may indicate that the subsurface chlorophyll maximum is deepening and larger phytoplankton such as diatoms has been decreasing during the past decade, associated with the decreasing density of surface water caused by warming in the western North Pacific, especially in the summer.     

Passive seismic response controlled high-rise building with high damping device

This paper describes a feasibility study on a high-damping device (HiDAM) installed in a building structure by way of a bracing mechanism. A seismic response analysis with respect to a high-rise building approximately 100 m high is reported. Proper adjustment of the damping coefficient of the HiDAM (oil damper) provided an over all damping factor of about 10–20 per cent to the building structure, and reductions in the response, deformation and shear forces were verified analytically. This paper reports also the performance confirmation tests conducted on a model device of the HiDAM which satisfied the specifications determined from the analytical results. The test results demonstrate the feasibility of the HiDAM and the possibility of utilizing it in high-rise buildings.     

Long-term precipitation and stream discharge records at seven forested experimental watersheds along a latitudinal transect in Japan: Jozankei,Kamabuchi, Takaragawa,Tsukuba, Tatsunokuchi-yama,Kahoku and Sarukawa

This data note introduces a database of long-term daily total precipitation and stream discharge data for seven forested watersheds in Japan that have been continuously monitored by the Forestry and Forest Products Research Institute. Three of the watersheds started data collection in the 1930s. Forest cover across the sites ranges from cool to warm temperate regions with the latitude spanning from 31 to 44° N and annual precipitation ranging from 1200 to 3000 mm yr⁻¹. The effects of vegetation change via clearcutting, thinning and forest fire (among other stressors) on stream discharge can be analysed from the long-term observation sites. Moreover, this multi-site dataset allows for inter- and intra-site comparisons of annual water loss (difference of annual precipitation and stream discharge). These long-term datasets can provide comprehensive insights into the effects of climate change and other stressors on forested ecosystems, not only in Japan but across a spectrum of forest types, if combined with other long-term records from other forested watersheds across the world.     

Effects of salinity downshock on dimethylsulfide production

During time-series observations in Sagami Bay, Japan, the concentration of dissolved dimethylsulfoniopropionate (DMSP_d), a precursor of dimethylsulfide (DMS), was negatively correlated with salinity. In the laboratory, low-salinity shock reduced DMS production rates of the natural bacterial community and induced rapid DMSP release from a dinophyte, Heterocapsa triquetra, suggesting that low-salinity shock reduced DMSP_d consumption but enhanced DMSP_d production, which agrees with the negative correlation between DMSP_d and salinity observed in Sagami bay. In addition, low-salinity shock did not affect DMSP lyase activity of H. triquetra. Low-salinity shock would increase the contribution from algae in DMS production, leading to an increase in potential DMS productivity in the environment.     

High heat flow anomalies on an old oceanic plate observed seaward of the Japan Trench

Thirty-three new measurements on the seaward slope and outer rise of the Japan Trench along a parallel of 38°45′N revealed the existence of high heat flow anomalies on the subducting Pacific plate, where the seafloor age is about 135 m.y.. The most prominent anomaly with the highest value of 114 mW/m² is associated with a small mound on the outer rise, which was reported to be a kind of mud volcano. On the seaward slope of the trench, heat flow is variable: high (70–90 mW/m²) at some locations and normal for the seafloor age (about 50 mW/m²) at others. The spatial variation of heat flow may be related to development of normal faults and horst/graben structures due to bending of the Pacific plate before subduction, with fluid flow along the fault zones enhancing the vertical heat transfer. Possible heat sources of the high heat flow anomalies are intra-plate volcanism in the last several million years like that discovered recently on the Pacific plate east of the Japan Trench.     

Projected impact of deep ocean carbon dioxide discharge on atmospheric CO2 concentrations

An evaluation of oceanic containment strategies for anthropogenic carbon dioxide is presented. Energy conservation is also addressed through an input hydrocarbon-fuel consumption function. The effectiveness of the proposed countermeasures is determined from atmospheric CO₂ concentration predictions. A previous box model with a diffusive deep ocean is adapted and applied to the concept of fractional CO₂ injection in 500 m deep waters. Next, the contributions of oceanic calcium carbonate sediment dissolution, and of deep seawater renewal, are included. Numerical results show that for CO₂ direct removal measures to be effective, large fractions of anthropogenic carbon dioxide have to be processed. This point favors fuel pre-processing concepts. The global model also indicates that energy conservation, i.e. a hydrocarbon-fuel consumption slowdown, remains the most effective way to mitigate the greenhouse effect, because it offers mankind a substantial time delay to implement new energy production alternatives.