Temporal alteration of fracture permeability in granite under hydrothermal conditions and its interpretation by coupled chemo-mechanical model

Examining the evolution of fracture permeability under stressed and temperature-elevated conditions, a series of flow-through experiments on a single rock fracture in granite has been conducted under confining pressures of 5 and 10 MPa, under differential water pressures ranging from 0.04 to 0.5 MPa, and at temperatures of 20–90 °C, for several hundred hours in each experiment. Measurements of fluid and dissolved mass fluxes, and post-experimental microscopy, were conducted to constrain the progress of mineral dissolution and/or precipitation and to examine its effect on transport properties. Generally, the fracture aperture monotonically decreased with time at room temperature, and reached a steady state in relatively short periods (i.e., <400 h). However, once the temperature was elevated to 90 °C, the aperture resumed decreasing and kept decreasing throughout the rest of the experimental periods. This reduction may result from the removal of the mineral mass from the bridging asperities within the fracture. Post-experimental observations by scanning electron microscopy, coupled with energy dispersive X-ray spectroscopy (SEM-EDX), revealed the formation of several kinds of secondary minerals such as silica and calcite. However, the precipitated minerals seemed to have had little influence on the flow characteristics within the fracture, because the precipitation was limited to quite local and small areas. The evolving rates and ultimate magnitudes of the fracture aperture are likely to be controlled by the stress exerted over the contacting asperities and temperatures, and by the prescribed flow conditions. Thus, this complex behavior should be attributed to the coupled chemically- and mechanically-induced effect. A coupled chemo–mechano conceptual model, accounting for pressure and free-face dissolutions, is presented in this paper to follow the evolution of the fracture permeability observed in the flow-through experiments. This model addresses the two dissolution processes at the contacting asperities and the free walls within the fractures, and is also capable of describing multi-mineral dissolution behavior. The model shows that the evolution of a fracture aperture (or related permeability) and of element concentrations may be followed with time under arbitrary temperature and pressure conditions. The model predictions for the evolving fracture aperture and elements concentrations show a relatively good agreement with the experimental measurements, although it is not possible to replicate the abrupt reduction observed in the early periods of the experiments, which is likely to be due to an unaccounted mechanism of more stress-mediated fracture compaction driven by the fracturing of the propping asperities.     

Geotechnical properties of submarine sediments in the Seto Inland Sea

Abstract

Sampling of submarine sediments by an improved piston corer and a bucket dredger has been carried out since 1973. The length of the core samples ranged from 0.9 m to 5.4 m. The recovery ratio ranged from 39.1 percent to 98.9 percent. The physical and engineering properties of 16 sediment cores and the physical properties of 125 dredged samples were determined, and variation of these properties was analyzed.

Clayey silts and silty clays cover the floor of relatively wide bays and sea areas. Sands and sandy silts blanket the floor of channels that have swift currents, and are also found in the vicinity of estuaries.

The piston core samples showed considerable sample disturbance, which should be estimated quantitatively in the future.     

Distribution of fossil seawater and its role in Neogene sedimentary rock landslides in Niigata,eastern marginal region of the Japan Sea

The Neogene marine sedimentary rock area in the eastern marginal region of the Japan Sea is an area with some of the highest landslide densities in Japan. Some of the landslides in this area have been known to involve saline groundwater, which can be the cause of these landslides. In order to demonstrate the relationships between landslides and saline water, topographic, geological, groundwater, and electromagnetic surveys were performed in the eastern marginal region of the Japan Sea. Many landslides and gravitational slope deformations with linear depressions and small scarps were recognized in the study area. The resistivity profile obtained by an electromagnetic survey suggests that there is a wide zonal distribution of saline water with salt concentrations equivalent to seawater at depths of 50–100 m or more and that the groundwater shallower than 50 m has an electrical conductivity of less than 100 mS/m. The shallow resistive groundwater is inferred to be meteoric water that replaced the saline groundwater, which likely weakened the bedrock, resulting in landslides. A ridge of competent tuff overlying mudstone has many linear depressions from gravitational slope deformation and low‐resistivity water to a depth of 600 m, which suggests that the mudstone was weakened by water replacement and deformed under the tuff caprock. The saline groundwater is inferred to be fossil seawater trapped in pores during sediment deposition, which is brought near the ground surface along with rocks by tectonic movement in the hills. Thus, the saline water and its fresh water replacement are among the important basic causes of the landslides. The oil well data obtained in the eastern marginal region of the Japan Sea suggest that such saline water replacement has occurred widely and that replacement is likely one of the predispositions for the frequent landslides there.     

Identification of soil–structure interaction effect in base-isolated bridges from earthquake records

Identification of system parameters with the help of records made on base-isolated bridge during earthquakes provides an excellent opportunity to study the performance of the various components of such bridge systems. Using a two-stage system identification methodology for non-classically damped systems, modal and structural parameters of four base-isolated bridges are reliably identified using acceleration data recorded during 18 earthquakes. Physical stiffness of reinforced concrete columns, dynamic properties of soil and foundation impedance are found by available theoretical models in conjunction with pertinent information from the recorded accelerographs. Soil–structure interaction (SSI) effect in these bridges is examined by comparing the identified and physical stiffness of the sub-structure components. It is found that SSI is relatively pronounced in bridges founded in weaker soils and is more strongly related to the ratio of pier flexural stiffness and horizontal foundation stiffness than soil shear modulus, G_s, alone. However, substantial reduction in G_s is observed for moderate seismic excitation and this effect should be taken into account while computing foundation impedance.     

Spatiotemporal Decreases of Nutrients and Chlorophyll-a in the Surface Mixed Layer of the Western North Pacific from 1971 to 2000

Using time series of hydrographic data in the wintertime and summertime obtained along 137°E from 1971 to 2000, we found that the average contents of nutrients in the surface mixed layer showed linear decreasing trends of 0.001∼0.004 μmol-PO₄ l⁻¹ yr⁻¹ and 0.01∼0.04 μmol-NO₃ l⁻¹ yr⁻¹ with the decrease of density. The water column Chl-a (CHL) and the net community production (NCP) had also declined by 0.27∼0.48 mg-Chl m⁻² yr⁻¹ and 0.08∼0.47 g-C-NCP m⁻² yr⁻¹ with a clear oscillation of 20.8±0.8 years. These changes showed a strong negative correlation with the Pacific Decadal Oscillation Index (PDO) with a time lag of 2 years (R = 0.89 ± 0.02). Considering the recent significant decrease of O₂ over the North Pacific subsurface water, these findings suggest that the long-term decreasing trend of surface-deep water mixing has caused the decrease of marine biological activity in the surface mixed layer with a bidecadal oscillation over the western North Pacific.     

Modeling of the branches of the Tsushima Warm Current in the Eastern Japan Sea

The branches of the Tsushima Warm Current (TWC) are realistically reproduced using a three-dimensional ocean general circulation model (OGCM). Simulated structures of the First Branch and the Second Branch of the TWC (FBTWC and SBTWC) in the eastern Japan Sea are mainly addressed in this study, being compared with measurement in the period September–October 2000. This is the first numerical experiment so far in which the OGCM is laterally exerted by real volume transports measured by acoustic Doppler current profiler (ADCP) through the Tsushima Straits and the Tsugaru Strait. In addition, sea level variation measured by tide-stations along the Japanese coast as well as satellite altimeters is assimilated into the OGCM through a sequential data assimilation method. It is demonstrated that the assimilation of sea level variation at the coastal tide-stations is useful in reproducing oceanic conditions in the nearshore region. We also examine the seasonal variation of the branches of the TWC in the eastern Japan Sea in 2000. It is suggested as a consequence that the FBTWC is continuous along northwestern Honshu Island in summertime, while it degenerates along the coast between the Sado Strait and the Oga Peninsula in other seasons. On the other hand, a mainstream of the SBTWC exists with meanders and eddies in the offshore region deeper than 1000 m to the north of the Sado Island throughout the year.     

Dietary shift and feeding intensity of <Emphasis Type="Italic">Stenobrachius leucopsarus</Emphasis> in the Bering Sea

The food habits of the dominant myctophid Stenobrachius leucopsarus were examined in the central basin of the Bering Sea in relation to oceanographic conditions, in summer 2002 and 2003 and spring 2006. S. leucopsarus exhibited an ontogenetic and seasonal dietary shift. In spring, small fish (≤40 mm) preyed mainly on Neocalanus flemingeri/plumchrus whereas large fish fed mainly on Neocalanus cristatus. In summer, small fish preyed mainly on Metridia pacifica whereas large fish fed mainly on euphausiids (Thysanoessa spp.). In the summer of 2003, when water temperature in the epipelagic layer (≤100 m) was warmer, reflecting the prevalence of the Alaskan Stream, small-sized S. leucopsarus showed a higher stomach content index, perhaps reflecting the greater abundance of M. pacifica. Thus, the present study shows that the physical variability in the epipelagic layer affects not only diets but also feeding performance of micronekton.     

Properties of sea ice and overlying snow in the Southern Sea of Okhotsk

The general properties of sea ice and overlying snow in the southern Sea of Okhotsk were examined during early February of 2003 to 2005 with the P/V “Soya”. Thin section analysis of crystal structure revealed that frazil ice (48% of total core length) was more prevalent than columnar ice (39%) and that stratigraphic layering was prominent with a mean layer thickness of 12 cm, indicating that dynamic processes are essential to ice growth. The mean thickness of ice blocks and visual observations suggest that ridging dominates the deformation process above thicknesses of 30 to 40 cm. As for snow, it was found that faceted crystals and depth hoar are dominant (78%), as which is also common in the Antarctic sea ice, and is indicative of the strong vertical temperature gradients within the snow. Stable isotope measurements (δ¹⁸O) indicate that snow ice occupies 9% of total core length and that the mass fraction of meteoric ice accounts for 1 to 2% of total ice volume, which is lower than the Antarctic sea ice. Associated with this, the effective fractionation coefficient during the freezing of seawater was also derived. Snow ice was characterized by lower density, higher salinity, and nearly twice the gas content of ice of seawater origin. In addition, it is shown that the surface brine volume fraction and freeboard are well correlated with ice thickness, indicating some promise for remote sensing approaches to the estimation of ice thickness.     

Measurements of Rare Earth Element and Other Element Mass Fractions in Environmental Reference Materials (NIST SRM 1646a,NIST SRM 1400, IAEA‐395 and IAEA‐450) by INAA,ICP‐AES and ICP‐MS

INAA, ICP‐AES and ICP‐MS were used to elementally characterise four environmental reference materials – NIST SRM 1646a (Estuarine Sediment), NIST SRM 1400 (Bone Ash), IAEA‐395 (Urban Dust) and IAEA‐450 (Algae). An analytical scheme consisting of the three methods was first applied to NIST SRM 1646a to validate the methodology because it has been extensively analysed and has certified values for many elements. With repeated analyses of NIST SRM 1646a, the accuracy and measurement repeatability of the data obtained were evaluated based on two statistical calculations (zeta‐score and Horwitz ratio) and were observed to be good enough for the analytical scheme to be applied to similar sorts of environmental/geochemical samples. Applying the same approach to NIST SRM 1400, IAEA‐395 and IAEA‐450, enabled mass fractions of 29, 38 and 28 elements to be determined, respectively. Among these results, the data for rare earth elements are of particular interest, not only for IAEA‐450 but also for the other three reference samples. The data for Pr, Gd, Dy, Ho, Er and Tm in NIST SRM 1646a are newly reported in this study. By using small test portions (< 100 mg) for NIST SRM 1646a and IAEA‐395, and recommended minimum amounts for NIST SRM 1400 and IAEA‐450, sample homogeneity was evaluated.     

High-resolution terrestrial carbon isotope and planktic foraminiferal records of the Upper Cenomanian to the Lower Campanian in the Northwest Pacific

Making Upper Cretaceous biostratigraphic correlations between the Northwest Pacific and Tethyan–Atlantic sections have been difficult because of rare frequencies of age-diagnostic macro- and microfossils in the sequences in the Northwest Pacific region. In order to correlate these sections precisely, an integrated planktic foraminiferal and bulk wood carbon-isotope stratigraphy from the upper Cenomanian to the lower Campanian succession (the middle–upper part of the Yezo Group) of Hokkaido, northern Japan is established with an average resolution of 50 k.y. The δ¹³C curves from bulk wood of the Yezo Group and from bulk carbonate of English Chalk show remarkably similar patterns of isotopic fluctuation, allowing the correlation of 22 carbon isotopic events between these sections. This high-resolution correlation greatly improves the previous micro- and macrofossil biostratigraphic schemes in the Northwest Pacific region, and reveals that global events, such as the oxygen depletion at the OAE 2 horizon, the constant decrease in pCO₂ during the Late Cretaceous, and the eustatic sea-level falls in the late middle Turonian, Santonian/Campanian Boundary and early Campanian, are recorded in the Upper Cretaceous sequence of the Northwest Pacific.