Regional investigations of vertical crustal movements in the U.S., using precise relevelings and mareograph data

In the past two years, the National Geodetic Survey has been creating a data base of vertical crustal movement information. The data elements are relative elevation changes along lines of releveling which are used to produce graphic displays on microfilm. In separate studies, the releveling data, together with information extracted from mareograph records, have been used to create two networks of velocity differences. The two networks, one in the vicinity of Chesapeake Bay and the other covering the Gulf Coast states, have been adjusted in order to prepare maps showing the velocities of elevation change. In the adjustments, the velocities derived from mareograph records were treated as observations. The results indicate annual subsidence ranging between −1.2 mm and −4.0 mm in the Chesapeake Bay area, with significant local variation. In the Gulf Coast region there is generally slight subsi'dence along the coast, ranging between 0.0 and −1.5 mm/year. Stability and slight uplift is indicated to the north where bedrock reaches the terrain surface. Anomalous subsidence of −7.0 mm/year occurs at New Orleans, La., and at Houston, Texas, there has been several decimeters change in the last ten years.     

Municipal initiatives for managing dunes in coastal residential areas: a case study of Avalon, New Jersey, USA

The characteristics of foredunes created in a municipal management program on a developed barrier island are evaluated to identify how landforms used as protection structures can be natural in appearance and function yet compatible with human values. Shoreline management zones include a naturally evolving, undeveloped segment; a noneroding, developed segment; eroding and noneroding segments of an “improved beach” where dunes have been built by artificial nourishment; and a privately built, artificially nourished dune on the shoreline of an inlet.A disastrous storm in 1962 resulted in an aggressive program for building dunes using sand fences, vegetation plantings, purchase of undeveloped lots, and sediment backpassing to maintain beach widths and dune elevations. The present nourished and shaped foredune in the improved beach is higher, wider, and closer to the berm crest than the natural dune. Restricted inputs of aeolian sand keep the surface flat and poorly vegetated. A stable section of this engineered shore has a wider beach, and sand fences have created a higher foredune with greater topographic diversity. The cross shore zonation of vegetation here is more typical of natural dunes, but the environmental gradient is much narrower. The privately built dune is low, narrow, and located where it could not be created naturally. Foreshore and aeolian sediments in the undeveloped segment and the improved beach are similar in mean grain size (0.16–0.21 mm) and sorting (0.31–0.39φ), but sediment on the surface of the nourished dune is coarser (28.1% gravel) with a more poorly sorted sand fraction (1.30φ) representing lag elements on the deflation surface.Willingness to enhance beaches and dunes for protection has reduced insurance premiums and allowed the municipality to qualify for funds from the Federal Emergency Management Agency (FEMA) to replace lost sediment, thus placing an economic value on dunes. Success of the management program is attributed to: (i) timing property-purchase and dune-building programs to periods immediately after storms (causing residents to accept high dunes that restrict access or views); (ii) instituting a vigorous education program (reminding residents of hazards during nonstorm periods); (iii) maintaining control over local sediment supplies (to keep pace with erosion and create new shoreline environments); (iv) investing private and municipal economic resources in landforms (qualifying them for external funds for replacement); and (v) maintaining, augmenting, or simply tolerating biodiversity and natural processes (retaining a natural heritage).     

Crystallization of magmatic iron meteorites: The effects of phosphorus and liquid immiscibility

Abstract— Magmatic iron meteorites are commonly thought to have formed by fractional crystallization of the metallic cores of asteroid‐sized bodies. As fractional crystallization proceeds, light elements such as P and S become enriched in the molten portion of the core. The light element content of the metallic liquid influences the partitioning behavior of trace elements and may cause liquid immiscibility to occur. The elemental trends observed in magmatic iron meteorites may have been affected by both of these processes. We have examined experimentally the effect of P on the solid‐metal‐liquid‐metal partitioning behavior of Ag and Pd, Re and Os, two element pairs used to date iron meteorite processes. Phosphorus has no effect on the partition coefficient of either Ag or Pd, which are incompatible and identical within experimental error. Compatible Re and Os also have identical partitioning behavior, within experimental error, and show increasing compatibility in the solid metal with increasing P content of the metallic liquid. Including the effects of both S and P on the partitioning behavior of Re and Os, simple fractional crystallization calculations can reproduce the large variation of Re and Os concentrations observed in four magmatic iron meteorite groups but have difficulty matching the later crystallizing portions of the trends. We have also conducted experiments with three phases—solid metal and two immiscible metallic liquids—to determine the location of the liquid immiscibility field near conditions thought to be relevant to magmatic iron meteorites. Our results show a significantly smaller liquid immiscibility field as compared to the previously published Fe‐P‐S phase diagram. Our revised phase diagram suggests that liquid immiscibility was encountered during the crystallization of asteroidal cores, but much later during the crystallization process than predicted by the previously published diagram.     

Effectiveness of Conservation Reserve Programs and Land ‘Slippage’ in Southwestern Kansas

Historically land reserve programs have been used to reduce soil erosion. Slippage, which occurs when the number of acres enrolled in a reserve program is not met by an equivalent reduction of acreage in production, has limited reserve success, however. This study addresses the effect of slippage on conservation reserves in southwestern Kansas from 1988–1994. Slippage has varied considerably on both spatial and temporal bases. At one extreme the programs were 100% successful in removing land from production, but at the other extreme, slippage rendered reserve programs nearly useless. Overall, slippage in the study area has greatly reduced conservation reserve effectiveness.     

Holocene climate change and carbon cycling in a groundwater-fed, boreal forest lake: Dune Lake, Alaska

We compared cladoceran assemblages in modern and pre-industrial sediments from cores taken in 48 softwater lakes located in four main regions of Nova Scotia (Canada) to evaluate the impacts of acidification and other recent environmental stressors. Lakes in Kejimkujik National Park showed significant increases in Holopedium relative abundances and significant decreases in Alona and other chydorids since pre-industrial times, which appear to be related to declines in pH and calcium (Ca) concentrations caused by acidic deposition. Lakes in Bridgewater also showed a significant decrease in Alona, as well as a significant increase in macrothricid (Acantholeberis and Ophryoxus) taxa that cannot be explained by declines in pH, although declines in [Ca] have been recorded. Lakes in Yarmouth did not show any significant regional changes in major cladoceran species groups. Still, pre-industrial assemblages in these lakes significantly differed from modern assemblages, with assemblage changes being lake-specific and likely related to interactions between local and regional stressors acting on individual lakes. Finally, lakes in Cape Breton Highlands National Park, located on the taiga plateau, have received historically lower levels of sulphate deposition relative to other regions in the province, and recorded a significant decrease in Alona similar to Bridgewater lakes. The province-wide decrease in Alona across different acid deposition rates suggests that limnological changes related to climate warming may be responsible. Overall, this study shows that acidification history is an important predictor of cladoceran assemblage changes since pre-industrial times in Nova Scotia lakes, although multiple stressors result in complex Cladocera responses in some regions.     

A preliminary methods comparison for measurement of dissolved organic nitrogen in seawater

Routine determination of dissolved organic nitrogen (DON) is performed in numerous laboratories around the world using one of three families of methods: UV oxidation (UV), persulfate oxidation (PO), or high temperature combustion (HTC). Essentially all routine methods measure total dissolved nitrogen (TDN) and calculate DON by subtracting the dissolved inorganic nitrogen (DIN). While there is currently no strong suggestion that any of these methods is inadequate, there are continuing suspicions of slight inaccuracy by UV methods.This is a report of a broad community methods comparison where 29 sets (7 UV, 13 PO, and 9 HTC) of TDN analyses were performed on five samples with varying TDN and DIN concentrations. Analyses were done in a “blind” procedure with results sent to the first author. With editing out one set of extreme outliers (representing 5 out of 145 ampoules analyzed), the community comparability for analyzing the TDN samples was in the 8–28% range (coefficient of variation representing one standard deviation for the five individual samples by 28 analyses). When DIN concentrations were subtracted uniformly (single DIN value for each sample), the comparability was obviously worse (19–46% cv). This comparison represents a larger and more diverse set of analyses, but the overall comparability is only marginally better than that of the Seattle workshop of a decade ago. Grouping methods, little difference was seen other than inconclusive evidence that the UV methods gave TDN values for several of the samples higher than HTC methods. Since there was much scatter for each of the groups of methods and for all analyses when grouped, it is thought that more uniformity in procedures is probably needed. An important unplanned observation is that variability in DIN analyses (used in determining the final analyte in most UV and PO methods) is essentially as large as the variability in the TDN analyses.This exercise should not be viewed as a qualification exercise for the analysts, but should instead be considered a broad preliminary test of the comparison of the families of methods being used in various laboratories around the world. Based on many independent analyses here, none of the routinely used methods appears to be grossly inaccurate, thus, most routine TDN analyses being reported in the literature are apparently accurate. However, it is not reassuring that the ability of the international community to determine DON in deep oceanic waters continues to be poor. It is suggested that as an outgrowth of this paper, analysts using UV and PO methods experiment and look more carefully at the completeness of DIN conversion to the final analyte and also at the accuracy of their analysis of the final analyte. HTC methods appear to be relatively easy and convenient and have potential for routine adoption. Several of the authors of this paper are currently working together on an interlaboratory comparison on HTC methodology.     

Airborne LiDAR and Terrestrial Laser Scanning Derived Vegetation Obstruction Factors for Visibility Models

Research presented here explores the feasibility of leveraging vegetation data derived from airborne light detection and ranging (LiDAR) and terrestrial laser scanning (TLS) for visibility modeling. Using LiDAR and TLS datasets of a lodgepole pine (Pinus contorta) dominant ecosystem, tree canopy and trunk obstructions were isolated relevant to a discrete visibility beam in a short‐range line‐of‐sight model. Cumulative obstruction factors from vegetation were compared with reference visibility values from digital photographs along sightline paths. LiDAR‐derived tree factors were augmented with single‐scan TLS data for obstruction prediction. Good correlation between datasets was found up to 10 m from the terrestrial scanner, but fine scale visibility modeling was problematic at longer distances. Analysis of correlation and regression results reveal the influence of obstruction shadowing inherent to discrete LiDAR and TLS, potentially limiting the feasibility of modeling visibility over large areas with similar technology. However, the results support the potential for TLS‐derived subcanopy metrics for augmenting large amounts of aerial LiDAR data to significantly improve models of forest structure. Subtle LiDAR processing improvements, including more accurate tree delineation through higher point density aerial data, combined with better vegetation quantification processes for TLS data, will advance the feasibility and accuracy of data integration.     

Chemical equilibrium model of solution behavior and solubility in the H-Na-K-OH-Cl-HSO4-SO4-H2O system to high concentration and temperature

This paper describes a chemical model that calculates solute and solvent activities and solid-liquid equilibria in the H-Na-K-OH-Cl-HSO₄-SO₄-H₂O system from dilute to high solution concentration within the 0° to 250°C temperature range. All binary and ternary subsystems are included in the model parameterization. The model is validated by comparing predictions with experimental data, primarily in higher order systems, not used in the parameterization process. Limitations of the model due to data insufficiencies are discussed.The Harvie and Weare (GCA44, 981, 1980) solubility modeling approach, incorporating their implementation of the concentration-dependent specific interaction equations of Pitzer (J. Phys. Chem.77, 268, 1973), is employed. This model expands the variable temperature Na-K-Cl-SO₄-H₂O model of Greenberg and Moller (GCA53, 2503, 1989) by including acid (H₂SO₄, HCl) and base (NaOH, KOH) species. Temperature functions for the chemical potentials of 5 acidic (sodium bisulfate, sodium sesquisulfate, mercallite, potassium sesquisulfate and misenite) and 6 basic (4 sodium hydroxide hydrates and 2 potassium hydroxide hydrates) solid phases are determined.